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Volumn 10, Issue 12, 2007, Pages 1510-1514

Switching on the photochemical reactivity in heterodimetallic OsII-RuII bipyridyl complexes containing a bis(bidentate) phosphine

Author keywords

Antenna effect; Bis(bidentate) phosphine; Dinuclear Os and Ru complexes; Energy transfer; Luminescence

Indexed keywords


EID: 36249021436     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2007.09.028     Document Type: Article
Times cited : (10)

References (19)
  • 7
    • 36248995135 scopus 로고    scopus 로고
    • In this context the expression "steric pressure" is appropriate, since intramolecular forces are applied to certain areas like phenyl rings.
  • 12
    • 36248938199 scopus 로고    scopus 로고
    • note
    • Though the diastereoisomers 1/2 or 3/4 can be separated by partial crystallization, this is not necessary, since in both cases the diastereoisomers show the same absorption and emission properties. Furthermore, the luminescence lifetimes of 1/2 or 3/4 can be fitted by single exponential decay functions in the whole temperature range 77-298 K.
  • 14
    • 36248949538 scopus 로고    scopus 로고
    • note
    • P,Ptrans = 7.4 Hz, -143.2
  • 15
    • 36249005390 scopus 로고    scopus 로고
    • note
    • 2) = 0.0978.
  • 18
    • 36248994587 scopus 로고    scopus 로고
    • note
    • A full description of this photoproduct will be given elsewhere.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.