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Two reviewers of this manuscript expressed some concern that the PEGMA-AIBA-PS latex had slightly higher positive zeta potentials than the AIBA-PS latex at low pH. We were also surprised by this unexpected observation. However, 1H NMR analysis of the dissolved latex in CD 2Cl2 confirmed that the PEGMA stabilizer is indeed grafted to the PEGMA-AIBA-PS latex (see Figure 3S in the Supporting Information, Moreover, the latent-grafting approach that we adopted in this synthesis should ensure that this PEGMA stabilizer is located on the outside of the latex particles. This is confirmed by our XPS studies, which revealed a C-O feature at approximately 286.5 eV that is not present in the AIBA-PS latex prepared in the absence of the PEGMA stabilizer see Figure 4S in the Supporting Information, However, we calculate from the 1H NMR data that the PEGMA grafting density is only around 1.6 mg m-2. Also, additional cationic AIBA initiator was
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-2. Also, additional cationic AIBA initiator was added to promote effective PEGMA grafting. Thus, we believe that the higher positive zeta potentials observed for the PEGMA-AIBA-PS latex are due to two factors: (i) the presence of additional cationic initiator fragments at the latex surface and (ii) the relatively low PEGMA grafting density (and hence reduced shielding efficiency).
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