The importance of atmospheric ozone and hydrogen peroxide in oxidising sulphur dioxide in cloud and rainwater

Atmospheric Environment

Volumn 41, Issue SUPPL., 2007, Pages 154-168

  Penkett, S A ^a   Jones, B M R ^a   Brice, K A ^a   Eggleton, A E J ^a  

^a CULHAM SCIENCE CENTRE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERICS; CLOUDS; DROPS; FREE RADICALS; HYDROGEN PEROXIDE; REACTION RATES; SULFUR DIOXIDE;

FREE RADICAL MECHANISM; HYDROGEN ION CONCENTRATION; HYDROXYL RADICALS; PHASE CONCENTRATIONS;

OZONE;

FREE RADICAL; HYDROGEN PEROXIDE; HYDROXYL RADICAL; OXIDIZING AGENT; OXYGEN; OZONE; PROTON; RAIN; SODIUM SULFITE; SULFATE; SULFUR DIOXIDE;

ATMOSPHERIC CHEMISTRY; CATALYSIS; HYDROGEN PEROXIDE; HYDROXYL RADICAL; LABORATORY METHOD; OXIDATION; OZONE; PH; RAINWATER; SULFUR DIOXIDE;

ACIDITY; ARTICLE; ATMOSPHERIC DEPOSITION; CALCULATION; CATALYSIS; CLOUD; GAS; LABORATORY; MATHEMATICAL ANALYSIS; OXIDATION; PRIORITY JOURNAL; REACTION ANALYSIS; REACTION TIME;

EID: 36248955580     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2007.10.065     Document Type: Article

References (34)

1. Alder M.G., and Hill A.R. The kinetics and mechanisms of hydroxide ion catalysed ozone decomposition in aqueous solution. Am. chem. Soc. J. 72 (1950) 1884-1886
2. Bäckstrom H.L.J. Z. phys. Chem. B25 (1934) 122-128
3. 2 by oxygen in aqueous systems. Atmospheric Environment 9 (1975) 1083-1090
4. Brimblecombe P., and Spedding D.J. The catalytic oxidation of micromolar aqueous sulphur dioxide, I. Atmospheric Environment 8 (1974) 937-945
5. Chamberlain A.C., and Eggieton A.E.J. Washout of tritiated water vapour by rain. Int. J. Air Wat. Pollut. 8 (1964) 135-149
6. Cox R.A., and Penkett S.A. The photooxidation of sulphur dioxide in sunlight. Atmospheric Environment 4 (1970) 425-433
7. Cox R.A., and Penkett S.A. Aerosol formation from sulphur dioxide in the presence of ozone and olefinic hydrocarbons. J. Chem. Soc. Faraday Trans. 68 (1972) 1735-1753
8. Crank J. The mathematics of diffusion (1956), Oxford University Press, Oxford
9. Crutzen P.J. (1973). Photochemical reactions initiated by and influencing ozone in the troposphere. Report A.P. 13 Inst. Meteorology, University of Stockholm.
10. Derwent R.G. (1976). Private communication.
11. Eggleton A.E.J., and Cox R.A. Homogeneous oxidation of sulphur compounds in the atmosphere. Atmospheric Environment 12 (1978) 227-230
12. Esphenson J.E., and Taube H. Tracer experiments with ozone as oxidising agent in aqueous solution. Inorg. Chem. 4 (1965) 704-709
13. Frank J. Haber F. (1931). Sber. preuss. Akad. Wiss. 1931, 250.
14. Fuller E.C., and Crist R.H. The rate of oxidation of sulphite ions by oxygen. Am. chem. J. 63 (1941) 1644-1650
15. Garland J.A. Some fog droplet size distributions obtained with an impaction method. Q. JI. R. met. Soc. 97 (1971) 483-494
16. Goiding R.M. Ultraviolet absorption studies of the bisulphite pyrosulphite equilibrium. J. C. S. 1960 (1960) 3711-3716
17. Gorham E. Paper presented at the 1st Int. symp. on acid precipitation and the forest ecosystem (1975), Columbus, Ohio
18. Hoffman M.R., and Edwards J.O. Kinetics of the oxidation of sulphite by hydrogen peroxide in acidic solution J. Phys. Chem. 79 (1975) 2096-2098
19. Hoigne J., and Bader H. Ozonation of water: Role of hydroxyl radicals as oxidising intermediates. Science 190 (1975) 782-784
20. Junge C.E., and Werby R.T. The concentration of chloride, sodium, potassium, calcium and sulphate in rainwater over the United States. J. Met. 15 (1958) 417-425
21. Levy H. Photochemistry of minor constituents in the troposphere. Planet. Space Sci. 21 (1973) 575-591
22. Mader P.M. Kinetics of the hydrogen peroxide-sulphite reaction in alkaline solution. Am. chem. Soc. J. 80 (1958) 2634-2639
23. Mason B. The Physics of Clouds (1971), Clarendon Press, Oxford
24. Mellor J.W. Comprehensive Treatise on Inorganic and Theoretical Chemistry (1946), Longmans Green, London
25. 2 and other atmospheric gases by ozone in aqueous solution. Nature 240 (1972) 105-106
26. Penkett S.A., and Garland J.A. Oxidation of sulphur dioxide in artificial fogs by ozone. Tellus 26 (1974) 284-290
27. 2 oxidation in stored rainwater samples. Atmospheric Environment 13 (1979) 139-147
28. Schroeter A.C. Kinetics of air oxidation of sulphurous acid salts. J. Pharm. Sci. 52 (1963) 559-563
29. Schumb W.C., Sutterfieid C.N., and Wentworth R.C. Hydrogen Peroxide. A.C.S. Monograph series (1955), Reinhold, NY
30. Sillen L. A. (1964). Stability constants of metal ion complexes, Section I Chem. Soc. Special publication No. 17.
31. Taube H., and Bray W.C. Chain reactions in aqueous solutions containing ozone, hydrogen peroxide and acid. Am. chem. J. 62 (1940) 3357-3373
32. 2 in the atmosphere, a wealth of monitoring data, but few reaction rate studies. Envir. Sci. Tech. 3 (1969) 436-445
33. Visser S. Chemical composition of rainwater in Kampala, Uganda and its relation to meteorological and topographical conditions. J. geophys. Res. 66 (1961) 3759-3765
34. Yeatts L.R.B., and Taube H. The kinetics of the reaction of ozone and chloride ion in acid aqueous solution. Am. chem. J. 71 (1949) 4100-4105