Insights into oxidation mechanisms in gamma-irradiated polypropylene, utilizing selective isotopic labeling with analysis by GC/MS, NMR and FTIR

Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

Volumn 265, Issue 1, 2007, Pages 8-17

  Bernstein, Robert ^a   Thornberg, Steven M ^a   Assink, Roger A ^a   Mowery, Daniel M ^a   Kathleen Alam, M ^a   Irwin, Adriane N ^a   Hochrein, James M ^a   Derzon, Dora K ^a   Klamo, Sara B ^b   Clough, Roger L ^a  

^a SANDIA NATIONAL LABORATORIES   (United States)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

C 13 labeling; C 13 NMR; Isotopic labeling; Polymer degradation; Polymer irradiation; Polymer oxidation; Polypropylene; Volatile degradation products

Indexed keywords

DEGRADATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; ISOTOPES; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE;

ISOTOPIC LABELING; POLYMER IRRADIATION; POLYMER OXIDATION;

POLYPROPYLENES;

EID: 36049021818     PISSN: 0168583X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.nimb.2007.08.100     Document Type: Article

References (42)

1. In: Clough R.L., and Shalaby S.W. (Eds). Radiation Effects on Polymers; (1990), American Chemical Society, Washington, DC
2. Clough R.L., Gillen K.T., and Dole M. Radiation Resistance of Polymers and Composites. In: Clegg D.W., and Collyer A.A. (Eds). Irradiation Effects on Polymers (1991), Elsevier, London 79
3. Clough R.L. Review of the 5th IRaP Conference. Nucl. Instr. and Meth. B 208 (2003) 1
4. Clough R.L. Enhancing Polymers with Radiation. Nucl. News. April (2000) 32
5. Clough R.L. Radiation Resistant Polymers. second ed. Encyclopedia of Polymer Science and Engineering Vol. 13 (1988), Whiley and Sons, New York
6. Clough R.L., and Gillen K.T. J. Polym. Sci. Pol. Chem. Part A-1. 27 (1989) 2313
7. Clough R.L. J. Am. Chem. Soc. 102 (1980) 5242
8. Clough R.L. Nucl. Instr. and Meth. B 185 (2001) 8
9. Burillo G., Clough R.L., Czvikovszky T., Guven O., Le-Moel A., Liu W., Singh A., Yang J., and Zaharescu T. Radiat. Phys. Chem. 64 (2002) 41
10. Clough R.L., and Gillen K.T. Polym. Degrad. Stabil. 30 (1990) 309
11. Clough R.L., and Gillen K.T. Radiat. Phys. Chem. 18 (1981) 661
12. Dunn T.S., Williams E.E., and Williams J.L. Radiat. Phys. Chem. 19 (1982) 287
13. Clough R.L., Malone G.M., Gillen K.T., Wallace J.S., and Sinclair M.B. Polym. Degrad. Stabil. 49 (1995) 305
14. Clough R.L., and Gillen K.T. Nucl. Technol. 59 (1982) 344
15. Celina M., Gillen K.T., Malone G.M., Clough R.L., and Nelson W.H. Radiat. Phys. Chem. 62 (2001) 153
16. Assink R.A., Celina M., Dunbar T.D., Alam T.M., Clough R.L., and Gillen K.T. Macromolecules 33 (2000) 4023
17. Alam T.M., Celina M., Assink R.A., Clough R.L., and Gillen K.T. Radiat. Phys. Chem. 60 (2001) 121
18. Chien J.C.W., and Boss C.R. J. Polym. Sci. Pol. Chem. 5 (1967) 3091
19. Chien J.C.W., Vandenberg E.J., and Jabloner H. J. Polym. Sci. Pol. Chem. 6 (1968) 381
20. Carlsson D.J., and Wiles D.M. Macromolecules. 2 (1969) 587
21. Carlsson D.J., and Wiles D.M. Macromolecules. 2 (1969) 597
22. Adams J.H. J. Polym. Sci. Polym. Chem. 8 (1970) 1279
23. Decker C., and Mayo F.R. J. Polym. Sci. Polym. Chem. 11 (1973) 2847
24. Carlsson D.J., and Wiles D.M. J. Macromol. Sci-Polym. R. C14 (1976) 65
25. Geuskens G., and Kabamba M.S. Photo-Oxidation of Polymers -- Part V: A New Chain Scission Mechanism in Polyolefins. Polym. Degrad. Stabil. 4 (1982) 69
26. Iring M., and Tüdös F. Thermal Oxidation of Polyethylene and Polypropylene: Effects of Chemical Structure and Reaction Conditions on the Oxidation Process. Prog. Polym. Sci. 15 (1990) 217
27. Lacoste J., Vaillant D., and Carlsson D.J. Gamma-photo-, and thermally-initiated oxidation of isotactic polypropylene. J. Polym. Sci. Pol. Chem. 31 (1993) 715
28. Celina M., George G.A., and Billingham N.C. Physical spreading of oxidation in solid polypropylene as studied by chemiluminescence. Polym. Degrad. Stabil. 42 (1993) 335
29. Gijsman P., Kroon M., and Oorschot M.V. Polym. Degrad. Stabil. 51 (1996) 3
30. Gugumus F. Polym. Degrad. Stabil. 62 (1998) 235
31. George G.A., and Celina M. Homogeneous and Heterogeneous Oxidation of Polypropylene. In: Hamid S.H. (Ed). Handbook of Polymer Degradation. second ed. (2000), Marcel Dekker Inc., New York 277
32. Barabás K., Iring M., Lazlo-Hedvig S., Kellen T., and Tudos F. Eur. Polym. J. 14 (1978) 405
33. Hoff A., and Jacobsson S. J. Appl. Polym. Sci. 29 (1984) 465
34. Philippart J.L., Posada F., and Gardette J.L. Polym. Degrad. Stabil. 49 (1995) 285
35. Commereuc S., Vaillant D., Philippart J.L., Lacoste J., Lemaire J., and Carlsson D.J. Polym. Degrad. Stabil. 57 (1997) 175
36. Mowery D.M., Assink R.A., Derzon D.K., Klamo S.B., Clough R.L., and Bernstein R. Macromolecules 38 (2005) 5035
37. Mowery D.M., Assink R.A., Derzon D.K., Klamo S.B., Bernstein R., and Clough R.L. Radiat. Phys. Chem. 76 (2007) 864
38. R. Breslow, Organic Reaction Mechanisms an Introduction; W. A. Benjamin: Menlo Park, 1969.
39. Pryor W.A. Free Radicals (1966), McGraw-Hill, New York
40. Walling C. Free Radicals in Solution (1957), John Wiley & Sons, New York
41. Clough R.L. J. Chem. Phys. 87 (1987) 1588
42. Thornberg S.M., Bernstein R., Derzon D.K., Irwin A.N., Klamo S.B., and Clough R.L. Polym. Degrad. Stabil. 92 (2007) 94