메뉴 건너뛰기




Volumn 349, Issue 14-15, 2007, Pages 2235-2240

Highly efficient ethylene/cyclopentene copolymerization with exclusive 1,2-cyclopentene incorporation by (cyclopentadienyl)(ketimide)titanium(IY) complex-MAO catalysts

Author keywords

Copolymerization; Cyclopentadienyl ligands; Cyclopentene; Ethylene; Titanium

Indexed keywords


EID: 36049004926     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200700247     Document Type: Article
Times cited : (45)

References (45)
  • 4
    • 36048965195 scopus 로고    scopus 로고
    • for example: V. Dragutan, R. Streck, Catalytic Polymerization of Cycloolefins, Studies in Surface Science and Catalysis, l3l, Elsevier, Amsterdam, 2000.
    • d) for example: V. Dragutan, R. Streck, Catalytic Polymerization of Cycloolefins, Studies in Surface Science and Catalysis, Vol. l3l, Elsevier, Amsterdam, 2000.
  • 6
    • 36048996903 scopus 로고    scopus 로고
    • 1998, 31, 4674-4680;
    • (1998) , Issue.31 , pp. 4674-4680
  • 7
    • 36048953367 scopus 로고    scopus 로고
    • 1998, 31, 4681-4683;
    • (1998) , vol.4681-4683 , Issue.31
  • 8
    • 36049001180 scopus 로고    scopus 로고
    • 1998, 31, 4684-4686;
    • (1998) , vol.4684-4686 , Issue.31
  • 29
    • 0037045461 scopus 로고    scopus 로고
    • N. Naga, Y. Imanishi, Y. Macromol. Chem. Phys. 2002, 203, 159-165;
    • c) N. Naga, Y. Imanishi, Y. Macromol. Chem. Phys. 2002, 203, 159-165;
  • 38
    • 36048956390 scopus 로고    scopus 로고
    • For reported examples, the catalytic activities by [Me 2Si(C5Me4)(N-t-Bu)]TiCl2, Me 2Si(indenyl)(N-tBu)]TiCl2 or the related complexes (modified by Cp, indenyl fragment)-MMAO catalysts were 10469 kg mol-1 Ti-h (ethylene ca. 1 atm, toluene 5 mL, cyclopentene 15 mL, 7] the activities by bis(phenoxyimine)titanium complex-MAO catalysts were < 49 kg mol-1 Ti-h (ex. ethylene <1 atm, toluene total 10-15 mL, cyclopentene 13.2 mL, 8] The activities by, Ph)NC(R 2)CHC(R1)O]2TiCl (R1 ;R2, CF3 ;CH3, Ph;CF3, t-Bu;CF3)-MMAO catalysts were 38-310 kgpolymer/mol Ti-h (ex. ethylene 1 atm, cyclopentene 5.0mmolmL-1 in toluene, 9] The activities by Ti[3-tBu-2-(O)C6H3CH, N(C6F 5, 2-(C6H5NCH)C
    • n = 3.6-4.5).
  • 40
    • 0037008020 scopus 로고    scopus 로고
    • For the effect of the cyclopentadienyl ligand in ethylene/styrene copolymerization using a series of CpTiCl2(0-2,6-t-Pr 2C6H3)-MAO catalyst systems, see: K. Nomura, H. Okumura, T. Komatsu, N. Naga, Macromolecules 2002, 35, 5388-5395
    • 3)-MAO catalyst systems, see: K. Nomura, H. Okumura, T. Komatsu, N. Naga, Macromolecules 2002, 35, 5388-5395.
  • 41
    • 36048992417 scopus 로고    scopus 로고
    • We did not choose the Cp'-aryloxo analogues, CpTiCl2(0-2,6-i- Pr2C6H3, because these complexes-MAO catalyst systems afforded low molecular weight copolymers. Other ketimide analogues, CpTiCl2[N=C(R1)R2, R1,R2 t, Bu,Ph, Ph,Ph etc, were not chosen, because these complexes showed low activities to afford polymers with broad molecular weight distributions, 4d
    • [4d]
  • 42
    • 36049031174 scopus 로고    scopus 로고
    • 13CNMR spectra for poly(ethylene-co-norbornene)s, poly(ethylene-co-cyclopentene)s are shown in the Supporting Information.
    • 13CNMR spectra for poly(ethylene-co-norbornene)s, poly(ethylene-co-cyclopentene)s are shown in the Supporting Information.
  • 43
    • 36049036874 scopus 로고    scopus 로고
    • [4c] no notable decreases in the activities were seen even after 30 min.
    • [4c] no notable decreases in the activities were seen even after 30 min.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.