Formation of N,N,N′,N′-tetramethylformamidinium disulphide from the chemical and electrochemical oxidation of tetramethylthiourea: Vibrational spectra and crystal structure of the chloride dihydrate salt

Journal of Molecular Structure

Volumn 871, Issue 1-3, 2007, Pages 131-139

  Bolzan A E ^a   Guida J A ^b   Piatti, R C V ^a   Arvia, A J ^a   Piro, O E ^c   Sabino, J R ^d,e   Castellano, E E ^d  

^a INSTITUTO DE INVESTIGACIONES FISICOQUÍMICAS TEÓRICAS Y APLICADAS INIFTA   (Argentina)

^b UNIVERSIDAD NACIONAL DE LA PLATA   (Argentina)

^c FACULTAD DE CIENCIAS EXACTAS   (Argentina)

^d UNIVERSITY OF SÃO PAULO   (Brazil)

^e FEDERAL UNIVERSITY OF GOIÁS   (Brazil)

Author keywords

Crystal structure; DFT; Electrochemistry; Formamidinium disulphide; Oxidation; Tetramethylthiourea; Vibrational spectra

Indexed keywords

CRYSTAL STRUCTURE; ELECTROCHEMICAL OXIDATION; FREE ENERGY; HYDROGEN PEROXIDE; RAMAN SCATTERING; VIBRATIONAL SPECTRA;

ANODIC FORMATION; CHLORIDE DIHYDRATE; HETEROGENEOUS PROCESSES; NORMAL MODE FREQUENCIES; TETRAMETHYLTHIOUREA;

ORGANIC COMPOUNDS;

EID: 36048975332     PISSN: 00222860     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molstruc.2007.02.004     Document Type: Article

References (41)

1. Reid E.E. Organic Chemistry of Bivalent Sulfur vol. 5 (1963), Chemical Publishing Co., New York
2. Smith P.A.S. Open-Chain Nitrogen Compounds (1965), W.A. Benjamin, New York
3. Pletcher D., and Walsh F. Industrial Electrochemistry (1990), Chapman and Hall Ltd., London
4. Szymaszek A., Biernat J., and Pajdowski L. Electrochim. Acta 22 (1977) 359
5. Suarez D.F., and Olson F.A. J. App. Electrochem. 22 (1992) 1002
6. Farndon E.E., Walsh F.C., and Campbell S.A. J. App. Electrochem. 25 (1995) 574
7. Marti{dotless}́n V.S., Sanllorente S., and Palmiero S. Electrochim. Acta 44 (1998) 579
8. Upadhayay D.N., and Yegnaraman V. Mat. Chem. Phys. 62 (2000) 247
9. Agrawal R., and Namboodhiri T.K.G. Corrosion science 30 (1990) 37
10. Dey G.R., Naik D.B., Kishore K., and Moorthy P.N. Radiat. Phys. Chem. 43 (1994) 365
11. Dey G.R., Naik D.B., Kishore K., and Moorthy P.N. J. Chem. Soc. Perkin Trans. 2 (1994) 1625
12. Pesic B., and Seal T. Metall. Trans. 21B (1990) 419
13. Kai T., Hagiwara T., Haseba H., and Takahashi T. Ind. Eng. Chem. Res. 36 (1997) 2757
14. Aguayo Salinas S., Encinas Romero M.A., and González I. J. Appl. Electrochem. 28 (1998) 417
15. Li J., and Miller J.D. Hydrometallurgy 63 (2002) 215
16. Bunge E., Port S.N., Roelfs B., Meyer H., Baumgärtel H., Schiffrin D.J., and Nichols R.J. Langmuir 13 (1997) 85
17. Piro O.E., Castellano E.E., Piatti R.C.V., Bolzán A.E., and Arvia A.J. Acta Cryst. C58 (2002) 252
18. Hoffmann M., and Edwards J.O. Inorg. Chem. 16 (1977) 3333
19. Bierbach U., Barklage W., Saak W., and Pohl S. Z. Naturforsch. 47b (1992) 1593
20. Bolzán A.E., Schilardi P., Piatti R.C.V., Iwasita T., Cuesta A., Gutiérrez C., and Arvia A.J. J. Electroanal. Chem. 571 (2004) 59
21. Senda H., Kitoh S., Suganami T., and Kunimoto K. Anal. Sciences 16 (2000) 1003
22. Enraf-Nonius (1997-2000). COLLECT. Nonius BV, Delft, The Netherlands.
23. Otwinowski Z., and Minor W. In: Carter J.C.W., and Sweet R. (Eds). Methods in Enzymology (1997), Academic Press, New York 307-326
24. Sheldrick G.M. SHELXS-97. Program for Crystal Structure Resolution (1997), University of Göttingen, Göttingen, Germany
25. Sheldrick G.M. SHELXL-97. Program for Crystal Structures Analysis (1997), University of Göttingen, Göttingen, Germany
26. C.K. Johnson, ORTEP-II. A Fortran Thermal-Ellipsoid Plot Program, Report ORNL-5318, Oak Ridge National Laboratory, Tennessee, USA, 1976.
27. Bolzán A.E., Wakenge I.B., Salvarezza R.C., and Arvia A.J. J. Electroanal. Chem. 475 (1999) 181
28. Anthoni U., Nielsen P.H., Borch G., Gustavsen J., and Klaboe P. Spectrochim. Acta Part A 33 (1977) 403
29. Stephens P.J., Devlin J.F., Chabalowski C.F., and Frisch M.J. J. Phys. Chem. 98 (1994) 11623
30. Scott A.P., and Radom L. J. Phys. Chem. 100 (1996) 16502
31. R.B.M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, J.A. Montgomery, Jr., T. Vreven, K.N. Kudin, J.C. Burant, J.M. Millam, S.S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J.E. Knox, H.P. Hratchian, J.B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann, O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V.G. Zakrzewski, S. Dapprich, A.D. Daniels, M.C. Strain, O. Farkas, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J. Cioslowski, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R.L. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C. Gonzalez, J.A. Pople, Gaussian Inc., Pittsburgh PA.
32. Günzler H., and Gremlich H.-U. IR Spectroscopy (2002), Wiley-VCH Verlag GmbH, Weinheim
33. Bard A.J., and Faulkner L.R. Electrochemical Methods (1980), J. Wiley and Sons, New York
34. Bolzán A.E., Piatti R.C.V., Salvarezza R.C., and Arvia A.J. J. Appl. Electrochem. 32 (2002) 611
35. Mayrhofer K.J.J., Blizanne B.B., Arenz M., Stamenkovic V.R., Ross P.N., and Markovic N.N. J. Phys. Chem. B 109 (2005) 14433
36. S. Trasatti, E. Lust, vol. 33, Plenum Press, New York, 1999.
37. Srinivasan S., and Gileadi E. Electrochim. Acta 11 (1966) 321
38. Bolzán A.E., Iwasita T., and Arvia A.J. Electrochim. Acta 51 (2005) 1044
39. Magnussen O.M. Chem. Rev. 102 (2002) 679
40. In: Bard A., Parsons R., and Jordan R. (Eds). Standard Potentials in Aqueous Solutons (1985), IUPAC/M. Dekker, New York and Basel
41. Glasstone S., Leidler K.J., and Eyring H. The Theory of Rate Processes (1941), McGraw-Hill, New York