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Volumn 48, Issue 50, 2007, Pages 8909-8913

Photolabile arylsilyl group: application to the oxidation of C-Si bonds

Author keywords

[No Author keywords available]

Indexed keywords

(2,6 DIMETHOXYPHENYL)DIMETHYLSILYL DERIVATIVE; 2 PROPANOL; CARBON; HEXAFLUORO 2 PROPANOL; HYDROXYL GROUP; ORGANOSILICON DERIVATIVE; SILICON; UNCLASSIFIED DRUG;

EID: 36048945435     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.10.057     Document Type: Article
Times cited : (5)

References (41)
  • 14
    • 3743056920 scopus 로고
    • For a review on organosilane photochemistry, see:
    • For a review on organosilane photochemistry, see:. Steinmetz M.G. Chem. Rev. 95 (1995) 1527-1588
    • (1995) Chem. Rev. , vol.95 , pp. 1527-1588
    • Steinmetz, M.G.1
  • 24
    • 36049014557 scopus 로고    scopus 로고
    • note
    • Stirring of the organosilanes in HFIP in the absence of irradiation led to no reaction, indicating that the conjunction of alcohol and the irradiation was necessary for the protodesilylation to occur.
  • 25
    • 36049035162 scopus 로고    scopus 로고
    • note
    • 6 which are not really suitable for preparative chemistry.
  • 26
    • 36049027657 scopus 로고    scopus 로고
    • note
    • +, 100%).
  • 32
    • 36049011478 scopus 로고    scopus 로고
    • note
    • 3): δ 157.6, 68.8, 61.1, 49.6, 24.9, 14.7, 1.6, 1.2 ppm.
  • 33
    • 36048996785 scopus 로고    scopus 로고
    • note
    • 3): δ 158.1, 71.4, 63.9, 61.4, 43.3, 14.7 ppm.
  • 34
    • 0034827901 scopus 로고    scopus 로고
    • The 2,6-dimethoxyphenylsilyl group is also stable to thermal radical conditions as illustrated by the carboazidation of allylsilane 5a: {A figure is presented}
    • The 2,6-dimethoxyphenylsilyl group is also stable to thermal radical conditions as illustrated by the carboazidation of allylsilane 5a: {A figure is presented}. Ollivier C., and Renaud P. J. Am. Chem. Soc. 123 (2001) 4717-4727
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 4717-4727
    • Ollivier, C.1    Renaud, P.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.