Amphiboles: Crystal chemistry

Reviews in Mineralogy and Geochemistry

Volumn 67, Issue , 2007, Pages 1-54

  Hawthorne, Frank C ^a   Oberti, Roberta ^b  

^a UNIVERSITY OF MANITOBA   (Canada)

^b CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 35948987481     PISSN: 15296466     EISSN: None     Source Type: Book Series    
DOI: 10.2138/rmg.2007.67.1     Document Type: Article

References (143)

1. Appleyard EC (1975) Silica-poor hastingsitic amphiboles from the metasomatic alkaline gneisses at Wolfe, eastern Ontario. Can Mineral 13:342-351
2. Bancroft GM (1973) Mössbauer Spectroscopy. An Introduction for Inorganic Chemists and Geochemists. McGraw-Hill, New York
3. 2+ ratios. Am Mineral 60:265-272
4. Banno Y, Miyawaki R, Matsubara S, Makino K, Bunno M, Yamada S, Kamiya T (2004) Magnesiosadanagaite, a new member of the amphibole group from Kasuga-mura, Gifu Prefecture, central Japan. Eur I Mineral 16:177-183
5. Bocchio R, Ungaretti L, Rossi G (1978) Crystal chemical study of eclogitic amphiboles from Alpe Arami, Lepontine Alps, Southern Switzerland. Rend Soc Ital Mineral Petrol 34:453-470
6. Brese NE, O'Keeffe M (1991) Bond-valence parameters for solids. Acta Crystallogr B47:192-197
7. Brown ID (1981) The bond valence method. An empirical approach to chemical structure and bonding. In: Structure and Bonding in Crystals II. O'Keeffe M, Navrotsky A (eds) Academic Press, New York, p 1-30
8. Brown ID (2002) The Chemical Bond in Inorganic Chemistry. The Bond Valence Model. Oxford University Press
9. Brown ID, Alterman D (1985) Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database. Acta Crystallogr B41:244-247
10. Bunch TE, Okrusch M (1973) Al-rich pargasite. Am Mineral 58:721-726
11. BLi clinoamphibole from the Pedriz Massif, Sierra de Guadarrama, Spanish Central System. Am Mineral 83:167-171
12. BLi amphibole end-member from the Eastern Pedriza Massif, Sierra de Guadarrama, Spain, and a restatement of the nomenclature of Mg-Fe-Mn-Li amphiboles. Am Mineral 87:976-982
13. 2: thermodynamic and crystal-chemical evaluation. Phys Chem Mineral 30:570-581
14. 3, a triclinic C1̄ amphibole with a triple-cell and excess hydrogen. Am Mineral 89:1464-1473
15. BLi amphiboles. Am Mineral 90:1167-1176
16. Cameron M, Gibbs GV (1973) The crystal structure and bonding of fluor-tremolite: a comparison with hydroxyl tremolite. Am Mineral 58:879-888
17. Cameron M, Sueno S, Papike JJ, Prewitt CT (1983) High temperature crystal chemistry of K and Na fluorrichterites. Am Mineral 68:924-943
18. Castelli D (1988) Chlorpotassium ferro-pargasite from Sesia-Lanzo marbles (Western Italian Alps): A record of highly saline fluids. Rend Soc Ital Mineral Petrol 43:129-138
19. Colville PA, Ernst WG, Gilbert MC (1966) Relationships between cell parameters and chemical compositions of monoclinic atnphiboles. Am Mineral 51:1727-1754
20. Cosca MA, Essene EJ, Bowman JR (1991) Complete chemical analyses of metamorphic homblendes: implications for normalizations, calculated H20 activities, and thermobarometry. Contrib Mineral Petrol 108:472-484
21. 3+/∑Fe in amphibole by X-ray absorption near edge structure (XANES) spectroscopy. In: Mineral Spectroscopy: A Tribute to Roger G. Bums. Dyar MD, McCammon C, Schaefer MW (eds). Geochernical Society Special Publication 5:165-171
22. Della Ventura G, Hawthorne FC, Robert J-L, Delbove F, Welch MF, Raudsepp M (1999) Short-range order of cations in synthetic amphiboles along the richterite-pargasite join. Eur J Mineral 11:79-94
23. Dick LA, Robinson GW (1979) Chlorine-bearing potassian hastingsite from a sphalerite skarn in southern Yukon. Can Mineral 17:25-26
24. + and D/H in kaersutites: Misleading indicators of mantle source fugacities. Geol 20:565-568
25. + in mantle kaersutite: Implications for mantle metasornatism. Am Mineral 78:968-979
26. Dyar MD, Gunter ME, Delaney JS, Lanzarotti A, Sutton SR (2002) Systematics in the structure and XANES spectra of pyroxenes, amphiboles, and micas as derived from oriented single crystals. Can Mineral 40:1375-1393
27. Dyar MD, Agresti DG, Schaefer MW, Grant CA, Sklute EC (2006) Mössbauer Spectroscopy of Earth and Planetary Materials. Ann Rev Earth Planet Sci 34:83-125
28. Eeckhout SG, De Grave E (2003) Evaluation of ferrous and ferric Mössbauer fractions. Part II. Phys Chem Mineral 30:142-146
29. Enarmi M, Liou JG, Bird DK (1992) Cl-bearing amphibole in the Salton Sea geothermal system, California. Can Mineral 30:1077-1092
30. Enders M, Speer D, Maresch WV, McCammon CA (2000) Ferric/ferrous iron ratios in sodic amphiboles: Mössbauer analysis, stoichiometry-based model calculations and the high-resolution microanalytical flank method. Contrib Mineral Petrol 140:135-147
31. Evans BW, Yang H (1998) Fe-Mg order-disorder in tremolite-actinolite-ferro-actinolite at ambient and high temperature. Am Mineral 83:458-475
32. Evans BW, Ghiorso MS, Yang H, Medenbach O (2001) Thermodynamics of the amphiboles: Anthophyllite- ferroanthophyllite and the ortho-clino phase loop. Am Mineral 86:640-651
33. Garvie LAJ, Buseck PR (1998) Ratios of ferrous to ferric iron from nanometer-sized areas in minerals. Nature 396:667-670
34. 3+/∑Fe by electron energyloss spectroscopy: A cautionary note. Am Mineral 89:1610-1616
35. Ghose S (1961) The crystal structure of cummingtonite. Acta Crystallogr 14:622-627
36. Gibbs GV (1966) Untitled article. In: AGI Short Course Lecture Notes on Chain Silicates. p 1-23
37. Gibbs GV (1969) The crystal structure of protoamphibole. Mineral Soc Am Spec Pap 2: 101-110
38. Gibbs GV, Bloss FD, Shell HR (1960) Protoamphibole, a new polytype. Am Mineral 45:974-989
39. Gottschalk M, Andrut M, Melzer S (1999) The determination of the cummingtonite content of synthetic tremolite. Eur J Mineral 11:967-982
40. 3+/∑Fe, and crystal structure of non-asbestiform and asbestiform amphiboles from Libby, Montana, U.S.A. Am Mineral 88:1970-1979
41. Hanisch K (1966) Messung des Ultrarot-Pleochroismus von Mineralen. VI. Der Pleochroismus des OH- Streckfrequenz in Riebeckit. N Jahhrb Mineral Monatsh 109-112
42. Hawthorne FC (1976) The crystal chemistry of the amphiboles. V. The structure and chemistry of arfvedsonite. Can Mineral 14:346-356
43. Hawthorne FC (1978) The crystal chemistry of the amphiboles. VIII. The crystal structure and site-chemistry of fluor-riebeckite: Can Mineral 16:187-194
44. Hawthorne FC (1979) The crystal chemistry of the amphiboles. X. Refinement of the crystal structure of ferroglaucophane and an ideal polyhedral model for clinoamphiboles. Can Mineral 17:1-10
45. Hawthorne FC (1981) Crystal chemistry of the amphiboles. Rev Mineral 9A:1-102
46. Hawthorne FC (1983a) The crystal chemistry of the amphiboles. Can Mineral 21:173-480
47. Hawthorne FC (1983b) Quantitative characterization of site occupancies in minerals. Am Mineral 68:287-306
48. Hawthorne FC (1983c) Characterization of the average structure of natural and synthetic amphiboles. Per Mineral Roma 52:543-581
49. Hawthorne FC (1988) Mössbauer spectroscopy. Rev Mineral 18:255-340
50. 2O in oxide and oxysalt minerals. Z Kristallogr 201:183-206
51. Hawthorne FC (1994) Structural aspects of oxides and oxysalt crystals. Acta Crystallogf B50:481-510
52. Hawthorne FC (1997) Short-range order in amphiboles: a bond-valence approach. Can Mineral 35:201-216
53. Hawthorne FC (2006) Landmark Papers: Structure Topology. Mineralogical Society of Great Britain and Ireland, London
54. Hawthorne FC, Della Ventura G (2007) Short-range order in amphiboles. Rev Mineral 67:xxx-yyy
55. Hawthorne FC, Grandy HD (1972) Positional disorder in the A-site of clino-amphiboles. Nature 235:72
56. Hawthorne FC, Grundy HD (1973a) The crystal chemistry of the amphiboles. I. Refinement of the crystal structure of ferrotschermakite. Mineral Mag 39:36-48
57. Hawthorne FC, Grandy HD (1973b) The crystal chemistry of the amphiboles. 11. Refinement of the crystal structure of oxykaersutite. Mineral Mag 39:390-400
58. Hawthorne FC, Grundy HD (1976) The crystal chemistry of the amphiboles. IV X-ray and neutron refinements of the crystal structure of tremolite. Can Mineral 14:334-345
59. Hawthorne FC, Grundy, HD (1977) The crystal chemistry of the amphiboles. 111. Refinement of the crystal structure of a sub-silicic hastingsite. Mineral Mag 41:43-50
60. Hawthorne FC, Grundy HD (1978) The crystal chemistry of the amphiboles. VII. The crystal structure and site chemistry of potassian ferri-taramite. Can Mineral 16:53-62
61. Hawthorne FC, Harlow GE (2007) The crystal chemistry of Al-rich amphiboles: sadanagaite and potassic- ferrisadanagaite. Can Mineral (submitted)
62. Hawthorne FC, Oberti R (2007) The crystal chemistry of the amphiboles. Rev Mineral 67:xxx-yyy
63. 2, a new alkali amphibole from the Kajlidongri manganese mine, Jhabua district, Madhya Pradesh, India. Am Mineral 77:1112-1115
64. Hawthorne FC, Ungaretti L, Oberti R, Bottazzi P, Czamanske GK (1993) Li: An important component in igneous alkali amphiboles. Am Mineral 78:733-745
65. [6]Li incorporation in amphiboles. Am Mineral 79:443-451
66. 22 O2. Am Mineral 80:165-172
67. Hawthorne FC, Oberti R, Sardone N (1996a) Sodium at the A site in clinoamphiboles: the effects of composition on patterns of order. Can Mineral 34:577-593
68. Hawthorne FC, Oberti R, Ottolini L, Foord EE (1996b) Lithium-bearing fluor-arfvedsonite from Hurricane Mountain, New Hampshire: a crystal-chemical study. Can Mineral 34:1015-1019
69. 2, a new alkali ampbibole from the Cañada Pinabete pluton, Questa, New Mexico, U.S.A. Am Mineral 81:226-228
70. Hawthorne FC, Oberti R, Zanetti A, Czamanske GK (1998) The role of Ti in hydrogen-deficient amphiboles: Sodic-calcic and sodic amphiboles from Coyote Peak, California. Can Mineral 36:1253-1265
71. 22 02. Am Mineral 85:236-241
72. Hawthorne FC, Oberti R, Cannillo E, Ottolini L, Roelofsen J, Martin RM (2001) Li-bearing arfvedsonitic amphiboles from the Strange Lake peralkaline granite, Quebec. Can Mineral 39:1161-1170
73. Hawthorne FC, Schindler M, Sokolova E, Abdu J, Evans BW, Ishida K (2007) The crystal chemistry of the gedrite-group amphiboles: II: Stereochernistry and chemical relations. Can Mineral (submitted)
74. Höfer HE, Brey GP, Schulz-Dobrick B, Oberhdnsli R (1994) The determination of the iron oxidation state by the electron microprobe. Eur J Mineral 6:407-418
75. King PL, Hervig RL, Holloway JR, Vermemarm TW, Righter K (1999) Oxy-substitution and dehydrogenation in mantle-derived amphibole megacrysts. Geochim Cosmochim Acta 62:3635-3651
76. total between amphibole and basanitic melt as a function of oxygen fugacity. Earth Planet Sci Lett 178:97-112
77. Krutov GA (1936) Dashkesanite, a new chlorine-bearing amphibole of the hastingsite group. Izv Akad Nauk Ser Geol 341-373 (in Russian)
78. Kullerud K (1996) Chlorine-rich amphiboles: interplay between amphibole compositions and an evolving fluid. Eur J Mineral 8:355-370
79. Leake BE (1968) A catalog of analyzed calciferous and subcalciferous amphiboles together with their nomenclature and associated minerals. Geol Soc Am Spec Pap 98
80. Léger A, Rebbert C, Webster J (1996) Cl-rich biotite and amphibole from Black Rock Forest, Comwall, New York. Am Mineral 81:495-504
81. Maresch WV, Miehe G, Czank M, Fuess H, Schreyer W (1991) Trichnic amphibole. Eur J Mineral 3:899-903
82. McCammon CA (1994) A Mössbauer milliprobe: Practical considerations. Hyperfine Interactions 92:1235-1239
83. McCormick KA, McDonald AM (1999) Chlorine-bearing amphiboles from the Fraser mine, Sudbury, Otario, Canada: Description and crystal chemistry. Can Mineral 37:1385-1403
84. 3+ content of megacrysts from alkali basalts. Geol 17:687-690
85. McGuire AV, Dyar MD, Nielson JE (1991) Metasomatic oxidation of upper mantle peridotite. Contrib Mineral Petrol 107:252-264
86. Mogessie A, Purtscheller F, Tessadri R (1986) High alumina calcic amphiboles (alumino pargasite-magnesio sadanagaite) from metabasites and metacarbonates of Central Oetztal, Eastern Alps (Northern Tyrol, Austria). N Jahrb Mineral Abh 154:21-39
87. Moore PB (1969) Joesmithite: a novel amphibole crystal chemistry. Mineral Soc Am Spec Pap 2:111-115
88. Moore PB, Davis AM, Van Derveer DG, Sen Gupta PK (1993) Joesmithite, a plumbous amphibole revisited and comments on bond valences. Mineral Petrol 48:97-113
89. Morrison J (1991) Compositional constraints on the incorporation of CI into amphiboles. Am Mineral 76:1920-1930
90. Murad E, Cashion J (2004) Mössbauer Spectroscopy of Environmental Materials and Their Industrial Utilization. Kluwer, Dordrecht
91. Nasir S, Al-Rawas AD (2006) Mössbauer characterization of upper mantle ferrikaersutite. Am Mineral 91:1163-1169
92. Oberti R, Ghose S (1993) Crystal-chemistry of a complex Mn-bearing alkali amphibole ("tirodite") on the verge of exsolution. Eur J Mineral 5:1153-1160
93. Oberti R, Ungaretti L, Cannillo E, Hawthorne FC (1993) The mechanism of Cl incorporation in amphibole. Am Mineral 78:746-752
94. Oberti R, Ungaretti L, Cannillo E, Hawthorne FC, Memmi I (1995a) Temperature-dependent Al order-disorder in the tetrahedral double-chain of C2/m amphiboles. Eur J Mineral 7:1049-1063
95. Oberti R, Sardone N, Hawthorne FC, Raudsepp M, Turnock AC (1995b) Synthesis and crystal-structure refinement of synthetic fluor-pargasite. Can Mineral 33:25-31
96. Oberti R, Hawthorne FC, Cámara F, Raudsepp M (1998) Synthetic fluoro-amphiboles: site preferences of Al, Ga, Sc and inductive effects on mean bond-lengths of octahedra. Can Mineral 36:1245-1252
97. Oberti R, Caballero JM, Ottolini L, López-Andrés S, Herreros V (2000) Sodic-ferripedrizite, a new monoclinic amphibole bridging the magnesium-manganese-lithium and the sodium-calcium groups. Am Mineral 85:578-585
98. Oberti R, Cámara F, Caballero JM, Ottolini L (2003a) Sodic-ferri-ferropedrizite and ferri-clinoferroholmquistite: Mineral data and degree of order of the A-site cations in Li-rich amphiboles. Can Mineral 41:1345-1354
99. BLi amphiboles. Eur J Mineral 15:309-319
100. Oberti R, Cámara F, Caballero JM (2004) Ferri-ottoliniite and ferriwhittakerite, two new end-members of the new Group 5 for monoclinic amphiboles. Am Mineral 89:888-893
101. Oberti R, Hawthorne FC, Cannillo E, Cámara F (2007a) Long-range order in amphiboles. Rev Mineral 67: xxx-yyy
102. Oberti R, Della Ventura G, Cámara F (2007b) New amphibole compositions. Rev Mineral 67:xxx-yyy
103. Oberti R, Boiocchi M, Smith DC, Medenbach O (2007c) Aluminotaramite, alumino-magnesiotaramite, and fluoro-alumino-magnesiotaramite: mineral data and crystal chemistry. Am Mineral 92:1428-1435
104. Ottolini L, Hawthorne FC (2001) SIMS ionization of hydrogen in silicates: A case study of komerupine. J Anal Atomic Spectrom 16:1266-1270
105. Ottolini L, Oberti R (2000) Accurate quantification of H, Li, Be, B, F, Ba, REE, Y, Th and U in complex matrices: a combined approach based on SIMS and single-crystal structure refinement. Anal Chem 72(16):3731-3738
106. Ottolini L, Bottazzi P, Vannucci R (1993) Quantification of Li, Be and B in silicates by secondary ion mass spectrometry using conventional energy filtering. Anal Chem 65:1960-1968
107. Ottolini L, Bottazzi P, Zanetti A, Vannucci R (1995) Determination of hydrogen in silicates by secondary ion mass spectrometry. Analyst 120:1309-1313
108. Papike JJ, Ross M, Clarke JR (1969) Crystal chemical characterization of clinoamphiboles based on five new structure refinements. Mineral Soc Am Spec Pap 2:117-136
109. Papike JJ, Cameron KL, Baldwin K (1974) Amphiboles and pyroxenes: characterization of OTHER than quadrilateral components and estimates of ferric iron from microprobe data. Geol Soc Am Abstr Prog 6:1053-1054
110. H2O in the upper mantle. Am Mineral 80:534-548
111. Popp RK, Hibbert HA, Lamb WM (2006) Oxy-amphibole equilibria in Ti-bearing calcic amphiboles: Experimental investigation and petrologic implications for mantle-derived amphiboles. Am Mineral 91:54-66
112. Previde Massara E (1990) Studio cristallochimico delle principali fasi mineralogichedelle eclogiti di Liset (Western Gneiss Region, Norvegia). PhD Dissertation, Università di Pavia, Italy
113. Rastsvetaeva RK, Puscharovskii DY, Vinogradova RA, Pekov IV (1996) Crystal structure of dashkesanite. Crystallogr Rep 41(1):58-62
114. Robinson K, Gibbs GV, Ribbe PH, Hall MR (1973) Cation distributions in three hornblendes. Am J Sci 273A:522-535
115. Robinson P, Ross M, Jaffe HW (1971) Composition of the anthophyllite-gedrite series, comparisons of gedrite-hornblende, and the anthophyllite-gedrite solvus. Am Mineral 56:1004-1041
116. Rossi G, Oberd R, Dal Negro A, Molin GM, Mellini M (1987) Residual electron density at the M2 site in C2/c clinopyroxenes: relationships with bulk chemistry and sub-solidus evolution. Phys Chem Mineral 14:514-520
117. Sato H, Yamaguchi Y, Makino K (1997) Cl incorporation into successively zoned ampiboles from the Ramnes cauldron, Norway. Am Mineral 82:316-324
118. Sawaki T (1989) Sadanagaite and subsilicic ferroan pargasite from thermally metamorphosed rocks in the Nogo-Hakusan area, central Japan, Mineral Mag 53:99-106
119. Schindler M, Sokolova E, Abdu J, Hawthorne FC, Evans BW, Ishida K (2007) The crystal chemistry of the gedrite-group amphiboles: I: Crystal structure and site populations. Can Mineral (submitted)
120. Schumacher JC (1991) Empirical ferric iron corrections: necessity, assumptions, and effects on selected geothermobarometers. Mineral Mag 55:3-18
121. Schumacher JC (1997) Appendix 2. The estimation of the proportion of ferric iron in the electron-microprobe analysis of amphiboles. Can Mineral 35:238-246
122. Schumacher JC (2007) Metamorphic amphiboles: compositions and coexistence. Rev Mineral 67: xxx-yyy
123. Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A32:751-767
124. Shimazaki H, Bunno M, Ozawa T (1984) Sadanagaite and magnesio-sadanagaite, new silica-poor members of calcic amphibole from Japan. Am Mineral 69:465-471
125. Sokolova EV, Hawthorne FC, Kabalov Y, Schneider J, McCammon C (2000a) The crystal chemistry of potassic-ferrisadanagaite. Can Mineral 38:669-674
126. Sokolova EV, Kabalov YuK, McCammon C, Schneider J, Konev, AA (2000b) Cation partitioning in an unusual strontian potassicrichterite from Siberia: Rietveld structure refinement and Mössbauer spectroscopy. Mineral Mag 64:19-24
127. Sokolova EV, Hawthorne FC, Gorbatova V, McCammon C, Schneider J (2001) Ferrian winchite from the Ilmen Mountains, Southern Urals, Russia, and some problems with the current scheme for amphibole nomenclature. Can Mineral 39:171-177
128. Stout JH (1972) Phase petrology and mineral chemistry of coexisting amphiboles from Telemark, Norway. J Petrol 13:99-145
129. Sueno S, Matsubara S, Gibbs GV, Boisen MB Jr (1998) A crystal chemical study of protoanthophyllite: orthoamphiboles with the protoamphibole structure. Phys Chem Mineral 25:366-377
130. Suwa K, Enami M, Horiuchi T (1987) Chlorine-rich potassium hastingsite from West Ongul Island, Lützow-Holm Bay, East Antarctica. Mineral Mag 51:709-714
131. 2, a new anhydrous amphibole from the Kajlidongri Manganese Mine, Jhabua District, Madhya Pradesh, India. Am Mineral 90:304-309
132. 4+ partitioning in pargasite and kaersutite. Eur J Mineral 11:345-354
133. Tiepolo M, Zanetti A, Vannucci R (2005) Determination of lithium, beryllium and boron at trace levels by laser ablation-inductively couple plasma-sector field mass spectrometry. Geostandards Geoanalytical Res 29:211-224
134. Ungaretti L (1980) Recent developments in X-ray single crystal diffractometry applied to the crystal-chemical study of amphiboles. God Jugosl Cent Krist 15:29-65
135. 4+ ordering in amphiboles from the Kola Superdeep Borehole: Correlation of crystal-chemical and Mössbauer measurements. GAC-MAC-CSPG-CSSS Joint Meeting, Halifax, Abstracts 30:197
136. van Aken PA, Liebscher B (2002) Quantification of ferrous/ferric ratios in minerals: new evaluation schemes of Fe L23 electron energy-loss near-edge spectra. Phys Chem Mineral 29:188-200
137. Vanko DA (1986) High-chlorine amphiboles from oceanic rocks: product of highly saline hydrothermal fluids? Am Mineral 71:51-59
138. Volfinger M, Robert JL, Vielzeuf D, Neiva AMR (1985) Structural control of the chlorine content of OH-bearing silicates (micas and amphiboles). Geochim Cosmochim Acta 49:37-48
139. Warren BE (1930) The crystal structure and chemical composition of the monoclinic amphiboles. Z Kristallogr 72:493-517
140. Welch MD, Cámara F, Della Ventura G, Iezzi G (2007) Non-ambient in situ studies of amphiboles. Rev Mineral 67: xxx-yyy
141. Whittaker EJW (1960) The crystal chemistry of the amphiboles. Acta Crystallogr 13:291-298
142. Zanetti A, Vannucci R, Bottazzi P, Oberti R, Ottolini L (1996) Infiltration metsomatism at Lherz as monitored by systematic ion-microprobe investigations close to a hornblendite vein. Chem Geol 134:113-133
143. Zhu C, Xu H, Ilton ES, Veblen DR, Henry DJ, Tivey MK, Thompson G (1994) TEM-AEM observations of Cl-rich amphibole and biotite and possible petrologic implications. Am Mineral 79:909-920