Reduction of 2,2,2-trifluoro-1-arylethanones with alkyl phosphines

Tetrahedron

Volumn 63, Issue 51, 2007, Pages 12731-12734

  Shi, Min ^a,b   Liu, Xu Guang ^a   Guo, Ying Wen ^b   Zhang, Wen ^b  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

2,2,2 Trifluoro 1 arylethanone; Alkyl phosphine; Deuterium labeling experiment; Hydrogen transfer

Indexed keywords

2,2,2 TRIFLUORO 1 PHENYLETHANONE; DEUTERIUM; OXIDIZING AGENT; PHOSPHINE DERIVATIVE; TRIMETHYLPHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; HYDROGENATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; REDUCTION; ROOM TEMPERATURE;

TRIFLUORO;

EID: 35748975173     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2007.09.084     Document Type: Article

References (19)

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11. 1H NMR spectrum.
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16. We greatly appreciate one of the reviewers for his kind revision on the reaction mechanism.
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18. This chiral phosphine was synthesized according to the previous literature:. Shi M., and Li C.Q. Tetrahedron: Asymmetry 16 (2005) 1385-1391
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