Concentration rebound following in situ chemical oxidation in fractured clay

Ground Water

Volumn 45, Issue 6, 2007, Pages 692-702

  Mundle, Keely ^a   Reynolds, David A ^b   West, Michael R ^a   Kueper, Bernard H ^a  

^a QUEEN S UNIVERSITY   (Canada)

^b UNIVERSITY OF WESTERN AUSTRALIA   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

AQUIFERS; CONCENTRATION (PROCESS); MATHEMATICAL MODELS; NUMERICAL METHODS; OXIDATION; PECLET NUMBER; POTASSIUM COMPOUNDS; TRICHLOROETHYLENE;

FRACTURED CLAY; MULTISPECIES MATRIX DIFFUSION; POTASSIUM PERMANGANATE; TRANSIENT FLOW;

CLAY;

ALUMINUM SILICATE; TRICHLOROETHYLENE;

ADVECTION; CLAY; COMPUTER SIMULATION; DIMENSIONLESS NUMBER; FRACTURED MEDIUM; HYDROGEOLOGY; NUMERICAL MODEL; OXIDATION; POTASSIUM; SENSITIVITY ANALYSIS; TETRACHLOROETHYLENE; TRANSIENT FLOW; TRICHLOROETHYLENE; TWO-DIMENSIONAL MODELING;

ARTICLE; CHEMISTRY; CLAY; OXIDATION REDUCTION REACTION; SEDIMENT; THEORETICAL MODEL; WATER POLLUTANT;

ALUMINUM SILICATES; GEOLOGIC SEDIMENTS; MODELS, THEORETICAL; OXIDATION-REDUCTION; TRICHLOROETHYLENE; WATER POLLUTANTS, CHEMICAL;

EID: 35648995500     PISSN: 0017467X     EISSN: 17456584     Source Type: Journal    
DOI: 10.1111/j.1745-6584.2007.00359.x     Document Type: Article

References (43)

1. Allen, T.J., J. Dablow, B. Marvin, M.L. Barackman, J. Baker, and B. Blanford. 2004. TCE oxidation by potassium permanganate injection to enhance groundwater remediation. In Chemical-Based Remediation Technologies, ed. A.R. Gavaskar and A.S.C. Chen, CD (2C-06). Columbs, Ohio : Battelle Press.
2. Barcelona, M.J., and T.R. Holm. 1991. Oxidation-reduction capacities of aquifer solids. Environmental Science and Technology 25, no. 9 : 1565 1572.
3. Bear, J. 1972. Dynamics of Fluids in Porous Media. New York : American Elsevier Publishing Company.
4. Brooks, R.H., and A.T. Corey. 1966. Properties of porous media affecting fluid flow. Journal of Irrigation and Drainage Division American Society of Civil Engineering 92, no. IR2 : 61 88.
5. Clement, T.P. 1997. RT3D - A modular computer code for simulating reactive multi-species transport in 3-dimensional groundwater systems. PNNL-SA-28967. Richard, Washington : Pacific Northwest National Laboratory.
6. Clement, T.P., Y. Sun, B.S. Hooker, and J.N. Petersen. 1998. Modeling multispecies reactive transport in ground water. Groundwater Monitoring and Remediation 18, no. 2 : 79 92.
7. Conrad, S.H., R.J. Glass, and W.J. Peplinski. 2002. Bench-scale visualization of DNAPL remediation processes in analog heterogeneous aquifers: Surfactant floods and in situ oxidation using permanganate. Journal of Contaminant Hydrology 58, no. 1-2 : 13 49.
8. Crother, R.A., J. Shipley, and R.A. Vogl. 2004. Changes in water quality due to potassium permanganate injection. In Chemical-Based Remediation Technologies, ed. A.R. Gavaskar and A.S.C. Chen, CD (2C-38). Columbs, Ohio : Battelle Press.
9. Dai, Q., and S. Reitsma. 2004. Kinetic study of permanganate oxidation of tetrachloroethylene at a high pH under acidic conditions. Remediation 14, no. 4 : 67 79.
10. Dickson, A, and N.R. Thomson. 2001. Dissolution on entrapped DNAPLs in variable aperture fractures: Experimental data and empirical model. Environment and Science Technology 37 : 4128 4137.
11. Gates, D.D., R.L. Siegrist, and S.R. Cline. 1995. Chemical oxidation of volatile and semivolatile organic compounds in soil. In 88th Annual Meeting and Exhibition, Air and Waste Management Association. CONF-950646-21.
12. Glass, R.J, and M.J. Nicholl. 1995. Quantitative visualization of entrapped phase dissolution within a horizontal flowing fracture. Geophysical Research Letters 22, 1413 1416.
13. Goldstein, K.J., A.R. Vitolins, D. Navon, B.L. Parker, S. Chapman, and G.A. Anderson. 2004. Characterization and pilot-scale studies for chemical oxidation remediation of fractured shale. Remediation 14, no. 4 : 19 37.
14. Hood, E.D., and N.R. Thomson. 2002. Impact of diffusion and natural oxidant demand on permanganate into low-permeability porous media. In Chemical Oxidation and Reactive Barriers; Remediation of Chlorinated and Recalcitrant Compounds, International Conference on Remediation of Chlorinated and Recalcitrant Compounds, ed. A.R. Gavaskar and A.S.C. Chen. Columbs, Ohio : Battelle Press.
15. Hood, E.D., and N.R. Thomson. 2000. Numerical simulation of in situ chemical oxidation. In Chemical Oxidation and Reactive Barriers; Remediation of Chlorinated and Recalcitrant Compounds, International Conference on Remediation of Chlorinated and Recalcitrant Compounds. Columbs, Ohio : Battelle Press, 82 90.
16. Hood, E.D., N.R. Thomson, D. Grosse, and G.J. Farquhar. 2002. Experimental determination of the kinetic rate law for the oxidation of perchloroethylene by potassium permanganate. Chemosphere 40, no. 12 : 1383 1388.
17. Huang, K.C., G.E. Hoag, P. Chheda, B.A. Woody, and G.M. Dobbs. 2001. Oxidation of chlorinated ethenes by potassium permanganate: A kinetic study. Journal of Hazardous Materials B87, no. 6 : 155 169.
18. Johnson, R.L., J.A. Cherry, and J.F. Pankow. 1989. Diffusive contaminant transport in natural clay: A field example and implications for clay-lined waste disposal sites. Environmental Science and Technology 23, no. 3 : 340 349.
19. Kueper, B.H., and D.B. McWhorter. 1991. The behavior of dense, nonaqueous phase liquids in fracture clay and rock. Ground Water 29, no. 5 : 716 728.
20. Li, X.D., and F.W. Schwartz. 2000. Efficiency problems related to permanganate oxidation schemes. In Chemical Oxidation and Reactive Barriers: Remediation of Chlorinated and Recalcitrant Compounds, International Conference on Remediation of Chlorinated and Recalcitrant Compounds, ed. G.B. Wickamanayake, A.R. Gavaskar, and A.S.C. Chen, 41 48. Columbs, Ohio : Battelle Press.
21. Lide, D.R., ed. 2004. CRC Handbook of Chemistry and Physics, 85th ed. Boca Raton, Florida : CRC Press.
22. Longino, B.L., and B.H. Kueper. 1999. Nonwetting phase retention and mobilization in rock fractures. Water Resources Research 35, no. 7 : 2085 2093.
23. MacKinnon, L.K., and N.R. Thomson. 2002. Laboratory in situ chemical oxidation of a perchloroethylene pool using permanganate. Journal of Contaminant Hydrology 56, no. 1-2 : 49 74.
24. Marvin, B.K., J. Chambers, A. Leavitt, and C.G. Schreier. 2004. Chemical and engineering challenges to in situ permanganate remediation. In Chemical-Based Remediation Technologies, ed. A.R. Gavaskar and A.S.C. Chen, CD (2C-04). Columbs, Ohio : Battelle Press.
25. Marvin, B.K., J. Chambers, A. Leavitt, and C.G. Schreier. 2002. Chemical and engineering challenges to in situ permanganate remediation. In International Conference on Remediation of Chlorinated and Recalcitrant Compounds. Columbs, Ohio : Battelle Press.
26. Mumford, K.G. 2002. Investigation of natural oxidant demand reactions in a sandy aquifer material. Master's diss., Department of Civil Engineering, University of Waterloo.
27. Mumford, K.G., N.R. Thomson, and R.M. Allen-King. 2005. Bench scale investigation of permanganate natural oxidant demand kinetics. Environment Science and Technology 29, no. 8 : 2835 2840.
28. Mundle, K. 2006. Concentration rebound following in situ chemical oxidation in fractured clay. M.Sc. thesis, Department of Civil Engineering, Queen's University, Kingston, Ontario, Canada.
29. Pankow, J.F., and J.A. Cherry. 1996. Chlorinated Solvents and Other DNAPLs in Groundwater. Portland, Oregon : Waterloo Press.
30. Parker, B.L., R.W. Gillham, and J.A. Cherry. 1994. Diffusive disappearance of immiscible-phase organic liquids in fractured geologic media. Ground Water 32, no. 5 : 805 820.
31. Reitsma, S., and Kueper, B.H. 1994. Laboratory measurement of capillary pressure saturation curves in a natural rock fracture. Water Resources Research 30, no. 4 : 865 878.
32. Schnarr, M., C. Farquhar, E. Hood, T. Gonullu, and B. Stickney. 1998. Laboratory and controlled field experiments using potassium permanganate to remediate trichloroethylene and perchloroethylene dnapls in porous media. Journal of Contaminant Hydrology 29, no. 3 : 205 224.
33. Schroth, M.H., M. Oostrom, T.W. Wiestma, and J.D. Istok. 2001. In-situ oxidation of trichloroethene by permanganate: Effects on porous medium hydraulic properties. Journal of Contaminant Hydrology 20, no. 1-2 : 79 98.
34. Siegrist, R.L., O.R. West, M.I. Morris, D.A. Pickering, D.W. Greene, C.A. Muhr, D.D. Davenport, and J.S. Gierke. 1995. In situ mixed region vapor stripping in low-permeability media. 2. full-scale field experiments. Environmental Science and Technology 29, no. 9 : 2198 2207.
35. Struse, A.M., R.L. Siegrist, H.E. Dawson, and M.A. Urynowicz. 2002. Diffusive transport of permanganate during in situ oxidation. Journal of Environmental Engineering 128, no. 4 : 327 334.
36. Sudicky, E.A., and E.O. Frind. 1982. Contaminant transport in fractured porous media: Analytical solutions for a system of parallel fractures. Water Resources Research 18, no. 6 : 1634 1642.
37. Tang, D.H., E.O. Frind, and E.A. Sudicky. 1981. Contaminant transport in fractured porous media: Analytical solution for a single fracture. Water Resources Research 17, no. 3 : 555 564.
38. Tunnicliffe, B.S., and N.R. Thomson. 2004. Mass removal of chlorinated ethenes from rough-walled fractures using permanganate. Journal of Contaminant Hydrology 75, no. 1-2 : 91 114.
39. Urynowicz, M.A., and R.L. Siegrist. 2005. Interphase mass transfer during chemical oxidation of TCE DNAPL in an aqueous system. Journal of Contaminant Hydrology 80, no. 3-4 : 93 106.
40. Vella, P.A., and B. Veronda. 1992. Oxidation of Trichloroethylene: Comparison of Potassium Permanganate and Fenton's Reagent, Chemical Oxidation Technologies for the Nineties. Lancaster, Pennsylvania : Technomin.
41. Yan, Y.E., and F.W. Schwartz. 1999. Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate. Journal of Contaminant Hydrology 27, no. 3 : 343 365.
42. Zhang, H., and F.W. Schwartz. 2000a. Simulating the in situ oxidative treatment of chlorinated ethylenes by potassium permanganate. Water Resources Research 36, no. 10 : 3031 3042.
43. Zhang, H., and F.W. Schwartz. 2000b. Simulation of oxidative treatment of a chlorinated compounds by permanganate. In Second International Conference on Remediation of Chlorinated and Recalcitrant Compounds, May 22-25, Monterey, Pennsylvania, ed. A.R. Gavaskar, and A.S.C. Chen, 1 16. Columbs, Ohio : Battelle Press.