Spectrofluorometric determination of cephalexin in pharmaceutical preparations and spiked human urine using 2-cyanoacetamide

Spectroscopy Letters

Volumn 40, Issue 6, 2007, Pages 797-809

  El Wasseef, Dalia R ^a,b  

^a Mansoura University 35516   (Egypt)

^b MANSOURA UNIVERSITY   (Egypt)

Author keywords

2 cyanoacetamide; Cephalexin; Spectrofluorometry

Indexed keywords

EID: 35648977616     PISSN: 00387010     EISSN: 15322289     Source Type: Journal    
DOI: 10.1080/00387010701506588     Document Type: Article

References (32)

1. Saleh, G. A.; Askal, H. F.; Radwan, M. A.; Omar, M. A. Use of charge transfer complexation in the spectrophotometric analysis of certain cephalosporins. Talanta 2001, 54, 1205-1215.
2. Saleh, G. A.; Askal, H. F.; Darwish, I. A.; El-Shorbagi, A.-N. A Spectroscopic analytical study for the charge transfer complexation of certain cephalosporins with chloranilic acid. Anal. Sci. 2003, 19, 281-287.
3. El-Obeid, H. A.; Gad-Kariem, E. A.; Al-Rashood, K. A.; Al-Khamees, H. A.; El-Shafie, F. S.; Bawazeer, G. A. M. A selective colorimetric method for the determination of penicillins and cephalosporins with α-aminoacyl functions. Anal. Lett. 1999, 32, 2809-2823.
4. Martinez, L. G.; Cabeza, A. S.; Falco, P. C.; Reig, F. B. A New procedure for the determination of cephalexin with 1,2-nahthoquinone 4-sulphonate in pharmaceutical and urine samples using solid-phase extraction cartridges and UV-visible detection. Anal. Chem. Acta 1998, 370, 115-123.
5. Thongpoon, Ch.; Liawruangrath, B.; Liawruangrath, S.; Wheatley, A. R.; Townshend, A. Flow-injection chemiluminescence determination of cephalosporins in pharmaceutical preparations using tris (2,2′-bipyridyl) ruthenium (II)-potassium permanganate system. Anal. Chem. Acta 2005, 553, 123-133.
6. Wang, J. W.; Xiong, H. Y. Flow-injection chemiluminescence determination of cephalexin and cephradine in pharmaceuticals. Fenxi Shiyanshi 2004, 23, 9-13.
7. Al-Momani, I. F. Spectrophotometric determination of selected cephalosporins in drug formulations using flow injection analysis. J. Pharm. Biomed. Anal. 2001, 25, 751-757.
8. Xu, M.; Ma, H.; Song, J. Polarographic behavior of cephalexin and its determination in pharmaceuticals and human serum. J. Pharm. Biomed. Anal. 2004, 35, 1075-1081.
9. Abdel Gaber, A. A.; Ghandour, M. A.; El-Said, H. S. Polarographic studies of some metal(II) complexes with cephalosporins selected from the first generation. Anal. Lett. 2003, 36, 1245-1260.
10. AboEl-Maali, N.; Osman, A. H.; Aly, A. A.; Al-Hazmi, G. A. Voltammetric analysis of Cu(II), Cd(II) and Zn(II) complexes and their cyclic voltammetry with several cephalosporin antibiotics. Bioelectrochemistry 2005, 65, 95-104.
11. Joshi, Sh. HPLC separation of antibiotics present in formulated and unformulated samples. J. Pharm. Biomed. Anal. 2002, 28, 795-809.
12. Samanidou, V. F.; Hapeshi, E. A.; Papdoyannis, I. N. Rapid and sensitive high-performance liquid chromatographic determination of four cephalosporin antibiotics in pharmaceuticals and body fluids. J. Chromatogr. B 2003, 788, 147-158.
13. Zendelovska, D.; Stafilov, T.; Petrov, S. Simultaneous quantification of cefaclor and cephalexin in blood plasma using high-performance liquid chromatography with UV detection. Acta Pharmaceutica 2002, 52, 243-250.
14. Kaskhedikar, S. G.; Argal, A. Simultaneous estimation of bromhexine hydrochloride and cephalexin in capsule by high performance liquid chromatography. Indian Drugs 2001, 38, 137-139.
15. Steppe, M.; Prado, M. S. A.; Tavares, M. F. M.; Pinto, T. J. A.; Kedor-Hackmann, E. R.; Santoro, M. I.R.M. Comparison of micellar electro kinetic chromatography, liquid chromatography, and microbiologic assay for analysis of cephalexin in oral suspensions. J. AOAC Int. 2003, 86, 707-713.
16. Sciacchitano, C. J.; Mopper, B.; Specchio, J. J. Identification and separation of five cephalosporins by micellar electrokinetic capillary chromatography. J. Chromatogr. B. 1994, 657, 395-399.
17. Ma, Q. L.; Yang, J. H.; Wu, X.; Huang, F.; Sun, L. M. A Selective fluorimetric method for the determination of some β-lactamic antibiotics. Anal. Lett. 2000, 33, 2689-2699.
18. British Pharmacopoeia; Her Majesty's Stationary Office: London, UK, 2000; Vol. I and II, pp. 253.
19. The United States Pharmacopeia 27, National Formulary 22. Asian edition U.S. Pharmacopeial Convention: Rockville MD, 2004; p. 394.
20. Hefnawy, M.; El-shabrawy, Y.; Belal, F. Spectrofluorometric determination of alpha-aminocephalosporins in biological fluids and pharmaceutical preparations. J. Pharm. Biomed. Anal. 1999, 21, 703-707.
21. Aly, F. A.; Hefnawy, M. M.; Belal, F. A selective spectrofluorimetric method for the determination of some α-aminocephalosporins in formulations and biological fluids. Anal. Lett. 1996, 29, 117-130.
22. Honda, S.; Takahashi, M.; Araki, Y.; Kakehi, K. Postcolumn derivatization of catecholamines with 2-cyanoacetamide for fluorimetric monitoring in high-performance liquid chromatopgraphy. J. Chromatogr. Biomed. Appl. 1983, 274, 45-52.
23. Honda, S.; Takahashi, M.; Kaheki, K.; Ganno, S. Rapid, automated analysis of monosaccharides by high performance anion exchange chromatography of borate complexes with fluorimetric detection using 2-cyanoacetamide. Anal. Biochem. 1981, 113, 130-138.
24. Aly, F. A. Spectrofluorimetric determination of prenalterol hydrochloride in pharmaceutical preparations and biological fluids. J. Pharm. Biomed. Anal. 1999, 18, 993-997.
25. Rizk, M.; Belal, F.; Ibrahim, F.; Ahmed, S. M.; el-Enany, N. M. Fluorimetric determination of oxamniquine in biological fluids. Il Farmaco 1999, 54, 47-50.
26. Yang, J.; Ma, Q.; Huang, F.; Sun, L.; Dong, J. A new fluorimetric method for the determination of ascorbic acid. Anal. Lett. 1998, 31, 2757-2766.
27. Zakhari, N. A. Spectrophotometric assay of certain aminoglycosides using 2-cyanoacetamide. Anal. Lett. 1990, 23, 1843-1849.
28. Liu, Y.; Yang, J.; Wu, X.; Li, L. Fluorometric determination of 3,4-dihydroxyphenylalanine with 2-cyanoacetamide. J. Fluorescence 2003, 13, 123-128.
29. Rose, J. Chemistry, physical and theoretical. In Advanced Physico-Chemical Experiments, Sir Isaac Pitman & Sons: London, 1964; p. 67.
30. Marrelli, L.P. In Analytical Profiles Drug Substances; K. Florey (ed.), Academic Press: New York, 1975; Vol. 4, p. 36.
31. Miller, J. N.; Miller, J. C. In Statistics and Chemometrics for Analytical Chemistry, 5th edn.; Pearson Education Ltd: London, 2005; p. 121.
32. Sweetman, S. (ed.) Martindale: The Complete Drug Reference, 35th edn.; Pharmaceutical Press: London, 2007.