On the mechanism of CO 2 insertion into the mg-N bond of molecular mono-and dinuclear magnesium compounds: A quantum chemical Study

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 633, Issue 13-14, 2007, Pages 2191-2198

  Himmel, H J ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Amides; CO 2 fixation; Magnesium; Quantum chemical calculations; Reaction mechanism

Indexed keywords

EID: 35648971150     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200700160     Document Type: Article

References (28)

1. See, for example: R. Han, G. Parkin, J. Am. Chem. Soc. 1992, 114, 748.
2. See, for example: C.-C. Chang, M. S. Ameerunisha, Coord. Chem. Rev. 1999, 189, 199.
3. K. C. Yang, C. C. Chang, C. S. Yeh, G. H. Lee, S. M. Peng, Organometallics 2001, 20, 126.
4. Y. Tang, L. N. Zakharov, A. L. Rheingold, R. A. Kemp, Organometallics 2004, 23, 4788.
5. M. T. Caudle, R. A. Nieman, V. G. Young, Jr., Inorg. Chem. 2001, 40, 1571.
6. M. T. Caudle, J. B. Benedict, C. K. Mobley, N. A. Straessler, T. L. Groy, Inorg. Chem. 2002, 41, 3183.
7. H.-J. Himmel, Eur. J. Inorg. Chem. 2007, 675.
8. M. M. Olmstead, W. J. Grigsby, D. R. Chacon, T. Hascall, P. P. Power, Inorg. Chim. Acta 1996, 251, 273.
9. K. W. Henderson, R. E. Mulvey, A. E. Dorigo, J. Organomet. Chem. 1996, 518, 139.
10. B. Conway, E. Hevia, A. R. Kennedy, R. E. Mulvey, S. Weatherstone, Dalton Trans. 2005, 1532.
11. W. Clegg, F. J. Craig, K. W. Henderson, A. R. Kennedy, R. E. Mulvey, P. A. O'Neil, D. Reed, Inorg. Chem. 1997, 36, 6238.
12. L. M. Engelhardt, B. S. Jolly, P. C. Junk, C. L. Raston, B. W. Skelton, A. H. White, Aust. J. Chem. 1986, 39, 1337.
13. T.-Y. Jer, C.-C. Chang, G.-H. Lee, S.-M. Peng, Y. Wang, Inorg. Chem. 1994, 33, 99.
14. R. A. Bartlett, M. M. Olmstead, P. P. Power, Inorg. Chem. 1994, 33, 4800.
15. Y. Tang, L. N. Zakharov, A. L. Rheingold, Organometallics 2005, 24, 836.
16. F. Calderazzo, G. Pampaloni, M. Sperrle, U. Englert, Z. Naturforsch. 1992, 47b, 389.
17. D. Belli Dell'Amico, F. Calderazzo, U. Giurlani, G. Pelizzi, Chem. Ber. 1987, 120, 955.
18. a) R. Ahlrichs, M. Bär, M. Häser, H. Horn, C. Kölmel, Chem. Phys. Lett. 1989, 162, 165;
19. b) K. Eichkorn, O. Treutler, H. Öhm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 1995, 240, 283;
20. c) K. Eichkorn, O. Treutler, H. Öhm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 1995, 242, 652;
21. d) K. Eichkorn, F. Weigend, O. Treutler, R. Ahlrichs, Theor. Chem. Acc. 1997, 97, 119;
22. e) F. Weigend, M. Häser, Theor. Chem. Acc. 1997, 97, 331;
23. f) F. Weigend, M. Häser, H. Patzelt, R. Ahlrichs, Chem. Phys. Lett. 1998, 294, 143.
24. a) A. D. Becke, J. Chem. Phys. 1993, 98, 5648;
25. b) P. J. Stephens, F. J. Devlin, C. F. Chabalowski, M. J. Frisch, J. Phys. Chem. 1994, 98, 11623.
26. S. O. N. Lill, U. Köhn, E. Anders, Eur. J. Org. Chem. 2004, 2868.
27. A. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 1992, 97, 2571.
28. A. Klamt, G. Schürmann, J. Chem. Soc., Perkin Trans. 2 1993, 799.