Structural flexibility of carboxylate bridging exemplified by a series of μ-acetato dizinc complexes

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 633, Issue 13-14, 2007, Pages 2178-2186

  Gil, Miguel Alvariño ^a   Maringgele, Walter ^a   Dechert, Sebastian ^a   Meyer, Franc ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Binuclear complexes; Carboxylate bridges; Pyrazolate complexes; Zinc

Indexed keywords

EID: 35648933533     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200700200     Document Type: Article

References (29)

1. C. J. Carrell, H. L. Carrell, J. Erlebacher, J. P. Glusker, J. Am. Chem. Soc. 1988, 110, 8651-8656.
2. G. B. Deacon, R. J. Phillips, Coord. Chem. Rev. 1980, 33, 227-250.
3. V. Zelenák, Z. Vargová, K. Györyová, Spectrochim. Acta A 2007, 66, 262-272.
4. R. L. Rardin, W. B. Tolman, S. J. Lippard, New. J. Chem. 1991, 15, 417-430.
5. a) M. E. Andersson, M. Hoegbom, A. Rinaldo-Matthis, K. Andersson, K. Kristoffer, B.-M. Sjoeberg, P. Nordlung, J. Am. Chem. Soc. 1999, 121, 2346-2352;
6. b) M. Torrent, D. Musaev, K. Morokuma, J. Phys. Chem. B 2001, 105, 322-327;
7. c) B. J. Gherman, M.-H. Baik, S. J. Lippard, R. A. Friesner, J. Am. Chem. Soc. 2004, 126, 2978-2990;
8. d) G. Lemercier, E. Mulliez, C. Brouca-Cabarrecq, F. Dahan, J.-P. Tuchagues, Inorg. Chem. 2004, 43, 2105-2113;
9. e) S. F. Sousa, P. A. Fernandes, M. J. Ramos, Biophys. J. 2005, 88, 483-494;
10. f) M. S. McCormick, M. H. Sazinsky, K. L. Condon, S. J. Lippard, J. Am. Chem. Soc. 2006, 125, 15108-15110.
11. a) V. Robert, G. Lemercier, J. Am. Chem. Soc. 2006, 128, 1183-1197;
12. b) S. F. Sousa, P. A. Fernandes, M. J. Ramos, J. Am. Chem. Soc. 2007, 129, 1378-1385.
13. A. Demsar, J. Kosmrlj, S. Petricek, J. Am. Chem. Soc. 2002, 124, 3951-3958.
14. M. T. Caudle, W. W. Brennessel, V. G. Young Jr., Inorg. Chem. 2005, 44, 3233-3240.
15. F. Meyer, S. Beyreuther, K. Heinze, L. Zsolnai, Chem. Ber./Recueil 1997, 130, 605-613.
16. J. Ackermann, F. Meyer, H. Pritzkow, Inorg. Chim. Acta 2004, 357, 3703-3711.
17. A. Prokofieva, A. I. Prikhod'ko, E. A. Enyedy, E. Farkas, W. Maringgele, S. Demeshko, S. Dechert, F Meyer, Inorg. Chem. 2007, 46, 4298-4307.
18. J. C. Rôder, F. Meyer, H. Pritzkow, Organometallics 2001, 20, 811-817.
19. The angular structural parameter τ is defined as τ = (β - α)/60, where α and β represent two basal angles with β > α. It is a measure for the degree of trigonality: a perfect TB-5 structure is associated with τ = 1, while τ = 0 is expected for an idealized SPY-5 geometry: A. W. Addision, T. N. Rao, J. Reedijk, J. van Rijn, G. C. Verschoor, J. Chem. Soc, Dalton Trans. 1984, 1349.
20. F. Meyer, K. Heinze, B. Nuber, L. Zsolnai, J. Chem. Soc., Dalton Trans. 1998, 207-213.
21. J. Klingele, S. Dechert, F. Meyer, Coord. Chem. Rev., in preparation.
22. B. Bauer-Siebenlist, F. Meyer, E. Farkas, D. Vidovic, J. A. Cuesta-Seijo, R. Herbst-Irmer, H. Pritzkow, Inorg. Chem. 2004, 43, 4189-4202.
23. B. Bauer-Siebenlist, F. Meyer, E. Farkas, D. Vidovic, S. Dechert, Chem. Eur. J. 2005, 11, 5343-5352.
24. 3 up to 2.5 Å for d(Zn-O) gave 669 hits in a range from 1.88 to 2.42 Å, a mean value of 2.02 Å, and a median value of 2.00 Å.
25. T. G. Schenck, J. M. Downes, C. R. C. Milne, P. B. Mackenzie, H. Boucher, J. Whelan, B. Bosnich, Inorg. Chem. 1985, 24, 2334-2337.
26. a) G. M. Sheldrick, SHELXL 97 Program for Crystal Structure Refinement, Universität Göttingen, 1997;
27. b) G. M. Sheldrick, SHELXS 97 Program for Crystal Structure Solution, Universität Göttingen, 1997.
28. STOE & CIE GmbH, X-RED, Darmstadt, 2002.
29. G. M. Sheldrick, SADABS Program for Empirical Absorption Correction of Area Detector Data, Universität Göttingen, 1996.