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The phenyl-based systems reported earlier (ref 38) are poly-Ph methanethiols. They have a thiolated benzylic group in one end of the molecule and phenylic hydrogen in the other end; therefore, their intrinsic structure is very different and they are considerably less conductive than the dithiolated poly-Ph studied here. The fact that they have similar β values to the one we obtain in the current study suggests that the decay factor β is mostly dependent on the core structure of the molecules rather than on the end groups, the interface geometry, or the degree of orbital overlap between the end groups and the backbone of the molecule.
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This is clear from Figure 7, for V > 0.4 V
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2 is qualitative rather than quantitative. Other important factors (such as the inclusion of more energy levels in G and the self-energy broadening which is not taken here into account) can alter the results in different situations. However, our qualitative treatment of the problem is convenient and straightforward as long as one knows its limitations.
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