Innovation in sodium borohydride production process from borosilicate glass with sodium under hydrogen atmosphere: "high pressure process"

International Journal of Hydrogen Energy

Volumn 32, Issue 16, 2007, Pages 3981-3986

  Kantürk, Aysel ^a   Pişkin, Sabriye ^a  

^a YILDIZ TECHNICAL UNIVERSITY   (Turkey)

Author keywords

Borosilicate glass; High pressure; Hydrogen storage; Sodium borohydride

Indexed keywords

BOROSILICATE GLASS; HIGH PRESSURE EFFECTS; HYDROGEN; HYDROGEN STORAGE; HYDROGENATION; PRESSURE DROP; QUARTZ; SODIUM COMPOUNDS;

CONVERSION REACTION; QUARTZ POWDER; SODIUM BOROHYDRIDE;

HYDRIDES;

EID: 35548936585     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2007.04.047     Document Type: Article

References (15)

1. Schlinger H.I., Brown H.C., Finholt A.E., Gilbert J.R., Hoekstra H.R., and Hyde E.K. Sodium borohydrite, its hydrolysis and its use as a reducing agent and in the generation of hydrogen. J Am Chem Soc 75 (1953) 215-219
2. Kim J., Lee H., Han S., Kim H., Song M., and Lee J. Production of hydrogen from sodium borohydride in alkaline solution: development of catalyst with high performance. Int J Hydrogen Energy 29 (2004) 263-267
3. Dinçer I. Environmental impacts of energy. Energy Policy 27 (1999) 845-854
4. Veziroglu T.N. Hydrogen movement and the next action: fossil fuels industry and sustainability economics. Int J Hydrogen Energy 22 (1997) 551-556
5. Zhang J., Fisher T.S., Gore J., Hazra D., and Ramachandran P.V. Heat of reaction measurements of sodium borohydride alcoholysis and hydrolysis. Int J Hydrogen Energy 3 (2006) 2292-2298
6. Wee J. A comparison of sodium borohydride as a fuel for proton exchange membrane fuel cells and for direct borohydride fuel cells. J Power Sources 155 (2006) 329-339
7. Amendola S.C., Sharp-Goldman S.L., Janjua M.S., Kelly M.T., Pettilo P.J., and Binder M. An ultrsafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst. J Power Sources 85 (2000) 186-189
8. Kojima Y., Suzuki K., Fukumoto K., Sasaki M., Yamamoto T., Kawai Y., and Hayaski H. Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide. Int J Hydrogen Energy 27 (2002) 1029-1034
9. Kojima Y., and Haga T. Recyling process of sodium metaborate to sodium borohydride. Int J Hydrogen Energy 28 (2003) 989-993
10. 2 with dehydrate borax through ball milling at room temperature. J Alloys Compd 349 (2003) 232-236
11. Cooper BH, Electrolytic process for the production of alkaline metal borohydrides, US Patent 3734842, 1973.
12. Hale CH, Sharifian H. Production of metal borohydrides and organic onuim borohydrides. US Patent 4931154, 1990.
13. Calabretta D.L., and Davis B.R. Investigation of the anhydrous molten Na-B-O-H system and the concept: Electrolytic hydriding of sodium boron oxide species. J Power Sources 164 (2007) 782-791
14. 4 production techniques form borax and determinate the production parameters. MS thesis, Yildiz Technical University, Turkey; 2006.
15. Avramov I., Vassilev T., and Penkov I. The glass transition temperature of silicate and borate glass. J Non-Crystalline Solid 351 (2005) 427-476