Two types of intramolecular addition of an Al-N multiple-bonded monomer LAlNAr′ arising from the reaction of LAl with N3Ar′ (L = HC[(CMe)(NAr)]2, Ar′ = 2,6-Ar2C6H 3, Ar = 2,6-iPr2C6H3)

Journal of the American Chemical Society

Volumn 126, Issue 31, 2004, Pages 9472-9473

  Zhu, Hongping ^a   Chai, Jianfang ^a   Chandrasekhar, Vadapalli ^a   Roesky, Herbert W ^a   Magull, Jörg ^a   Vidovic, Denis ^a   Schmidt, Hans Georg ^a   Noltemeyer, Mathias ^a   Power, Philip P ^b   Merrill, William A ^b  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM; HEXANE; IMIDE; MONOMER; NITROGEN; TOLUENE;

ARTICLE; CHEMICAL BOND; CRYSTAL STRUCTURE; CYCLOADDITION; INFRARED SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; THERMOSTABILITY;

EID: 3543141936     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0475712     Document Type: Article

References (18)

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14. 2 = 0.1496 for all (8758) data.
15. Cui, C.; Köpke, S.; Herbst-Irmer, R.; Roesky, H. W.; Noltemeyer, M.; Schmidt, H.-G.; Wrackmeyer, B. J. Am. Chem. Soc. 2001, 123, 9091.
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18. 1H NMR spectrum of the starting material LAl was measured as a reference. The resonances of γ-CH at δ 5.11, 5.13, 5.14, and 5.15 ppm respectively correspond to -50, -30, -10, 25 °C.