New one-pot methods for the synthesis of metallonium dications [1,2-(η5:σ:σ-C5Me3(CH2)2(η5-Cp*)Os]2+ and [1,1′-(η5:σ-C5Me4CH2)2Os]2+ based on decamethylosmocene or its derivatives

Russian Chemical Bulletin

Volumn 52, Issue 11, 2003, Pages 2424-2433

  Kamyshova, A A ^a   Kreindlin, A Z ^a   Rybinskaya, M I ^a   Petrovskii, P V ^a   Kruglova, N V ^a   Borisov, Yu A ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

Alkoxylation; Decamethylosmocene; Metallocenylmethyl dications; NMR spectra; Protonation; Quantum chemical calculations; UV photolysis

Indexed keywords

OSMIUM DERIVATIVE; RUTHENIUM DERIVATIVE;

ARTICLE; ATMOSPHERE; CHEMICAL REACTION; DENSITY FUNCTIONAL THEORY; HEATING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOLYSIS; ROOM TEMPERATURE; SYNTHESIS;

EID: 3543102685     PISSN: 10665285     EISSN: None     Source Type: Journal    
DOI: 10.1023/B:RUCB.0000012365.61206.9f     Document Type: Article

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