Compact radial reactor with a structured porous metal catalyst for the conversion of natural gas to synthesis gas: Experiment and modeling

Industrial and Engineering Chemistry Research

Volumn 43, Issue 16, 2004, Pages 4721-4731

  Kirillov, V A ^a   Bobrin, A S ^a   Kuzin, N A ^a   Kuzmin, V A ^a   Shigarov, A B ^a   Skomorokhov, V B ^a   Smirnov, E I ^a   Sobyanin, V A ^a  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; COMBUSTION; MIXTURES; NATURAL GAS; POROSITY; POROUS MATERIALS; SYNTHESIS GAS;

METAL CATALYSTS; STRUCTURED CATALYSTS;

CHEMICAL REACTORS;

CHROMIUM; METAL; NICKEL;

REACTOR;

ARTICLE; CATALYSIS; CATALYST; COMBUSTION; COMPACT RADIAL REACTOR; GAS; GAS FLOW; HEATING; MATHEMATICAL MODEL; PRESSURE; REACTOR; THERMAL CONDUCTIVITY; VOLUMETRY;

EID: 3543038186     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie030785s     Document Type: Article

References (27)

1. Pena, M. A.; Gomez, J. P.; Fierro, J. L. G. New catalytic routes for syngas and hydrogen production (Review). Appl. Catal. A: Gen. 1996, 144, 7-57.
2. Prettre, M.; Eichner, C.; Perrin, M. The catalytic oxidation of methane to carbon monoxide and hydrogen. Trans. Faraday Soc. 1946, 43, 335-340.
3. Vermeiren, W. J. M.; E. Blomsma, P. A.; Jacobs, P. A. Catalytic and thermodynamic approach of the ox reforming reaction of methane. Catal. Today 1992, 13, 427-436.
4. 3 catalyst. J. Catal. 1991, 132, 117-127.
5. de Groote, A. M.; Froment, G. F. Simulation of the catalytic partial oxidation of methane to synthesis gas. Appl. Catal. A: Gen. 1996, 138, 245-264.
6. de Smet, C. R. H.; de Croon, M. H. J. M.; Berger, R. J.; Marin, G. B.; Scheuten, J. C. Design of adiabatic fixed-bed reactors for the partial oxidation of methane to synthesis gas. Application to production of methanol and hydrogen-for-fuel-cells. Chem. Eng. Sci. 2001, 56, 4849-4861.
7. Avci, A. K.; Trimm, D. L.; Ilsen Onsan, Z. Heterogeneous reactor modeling for simulation of catalytic oxidation and steam reforming of methane. Chem. Eng. Sci. 2001, 56, 641-649.
8. Frauhammer, J.; Eigenberger, G.; Hippel, L. V.; Arntz, D. A new reactor concept for endothermic high-temperature reactions. Chem. Eng. Sci. 1999, 54, 3661-3670.
9. Kolios, G.; Frauhammer, J.; Eigenberger, G. Efficient reactor concepts for coupling endothermic and exothermic reactions. Chem. Eng. Sci. 2002, 57, 1505-1510.
10. Kirillov, V. A.; Kuzin, N. A.; Kulikov, A. V.; Fadeev, S. I.; Shigarov, A. B.; Sobyanin, V. A. Thermally coupled catalytic reactor for steam reforming of methane and liquid hydrocarbons: Experiment and mathematical modeling. Theor. Found. Chem. Eng. 2003, 37, 2, 1-9 (in Russian).
11. Lukyanov, B. N.; Kirillov, V. A.; Kuzin, N. A.; Danilova, M. M.; Kulikov, A. V.; Shigarov A. B. Catalytic heat generating element for autonomous domestic heating systems. Chem. Eng. J. 2003, 91, 191-198.
12. Ivanova, A. S.; Bobrova, I. I.; Moroz, E. M. Kinet. Katal. 1993, 34 (4), 758-762, (in Russian).
13. Anokhin, V. A.; Deryuzhkina, V. I.; Pereguzov, V. A.; Menshov, V. I. Fundamentals of Catalytic Conversion of Hydrocarbons; Naukova Dumka: Kiev, 1977; p 63 (in Russian).
14. Choudhary, V. R.; Rajput, A. M.; Prabhakar, B. Catal. Lett. 1992, 15 (4), 363-370.
15. Handbook of AZOTCHIC; Melnikhov, E. Ya., Ed.; Khimiya: Moscow, 1986 (in Russian).
16. Yamamoto, R.; Morka, Y.; Suzuki, K. et al. J. Chem. Soc. Jpn. Ind. Chem. Soc. 1957, 60 (8), 1020.
17. Hawthorn, R. D. Afterburner catalyst-effects of heat and mass transfer between gas and catalyst surface. AIChE Symp. Ser. 1974, 70 (137), 428-438.
18. Kutateladze, S. S.; Borischanskii, V. M. A Handbook of Heat Transfer; Energia: Moscow, 1959 (in Russian).
19. Prasad, B. S. V. Heat Transfer Eng. 1998, 17, 3.
20. Idelchik, I. E. Handbook of Hydraulic Resistance, 3rd ed.; Begell House: New York, 1994.
21. Trimm, D. L.; Lam, C.-W. The combustion of methane on platinum-alumina fibre catalysts. I. Kinetics and mechanism. Chem. Eng. Sci, 1980, 35, 1405-1413.
22. Khomenko, A. A.; Apelbaum, L. O.; Shub, F. S.; Snagovskii S.; Temkin, M. I. Kinetics of the reaction of methane and steam and reverse hydrogenation of carbon oxide on the nickel surface. Kinet. Katal. 1971, 12, 423-429.
23. Numaguchi, T.; Kikuchi, K. Intrinsic kinetics and design simulation in a complex reaction network: Steam-methane reforming. Chem. Eng. Sci. 1988, 43, 2295-2301.
24. Reid, R. C.; Prausnitz, J. M.; Poling, B. E. Properties of Gases and Liquids; 4th ed.; McGraw-Hill: New York, 1987.
25. Smal, F. V.; Arsenov, E. E. A Perspective Fuels for Cars; Transport: Moscow, 1979 (in Russian).
26. U.S. Patent 4,108,114, 1978.
27. Sorokin, A. I.; Mirzoev, G. K. A comparison of internal combustion engines with fuel cells power plant. In 2nd All-Russian Fuel Cells Workshop, Novosibirsk, Jun 29-Jul 2, 2003; pp 19-28 (in Russian).