Fractionation of ethylene/1 -pentene copolymers using a combination of SEC-FTIR and SEC-HPer DSC

Journal of Polymer Science, Part B: Polymer Physics

Volumn 45, Issue 21, 2007, Pages 2956-2965

  Luruli, Nyambeni ^a   Pijpers, Thijs ^b   Brüll, Robert ^c   Grumel, Valérie ^a   Pasch, Harald ^c   Mathot, Vincent ^b,d  

^a STELLENBOSCH UNIVERSITY   (South Africa)

^b UNIVERSITY OF LEUVEN   (Belgium)

^c FRAUNHOFER INSTITUTE FOR STRUCTURAL DURABILITY AND SYSTEM RELIABILITY LBF   (Germany)

^d SciTe   (Netherlands)

Author keywords

Catalysis; Copolymerization; Ethylene 1 pentene copolymers; Fractionation of polymers; High performance differential scanning calorimetry (HPer DSC); Melting and crystallization temperatures; SEC FTIR; Short chain branching distribution; Thermal properties

Indexed keywords

CATALYSIS; COPOLYMERIZATION; DIFFERENTIAL SCANNING CALORIMETRY; ETHYLENE; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FRACTIONATION; MOLECULAR WEIGHT; SIZE EXCLUSION CHROMATOGRAPHY; SYNTHESIS (CHEMICAL); THERMODYNAMIC PROPERTIES;

CRYSTALLIZATION TEMPERATURES; FRACTIONATION OF POLYMERS; HIGH PERFORMANCE DIFFERENTIAL SCANNING CALORIMETRY; SHORT CHAIN BRANCHING DISTRIBUTION;

COPOLYMERS;

EID: 35348991652     PISSN: 08876266     EISSN: None     Source Type: Journal    
DOI: 10.1002/polb.21127     Document Type: Article

References (25)

1. Kaminsky, W. J Polym Sci Part A: Polym Chem 2004, 42, 3911.
2. Kaminsky, W. Macromol Symp 2002, 177, 61.
3. Wild, L. Trend Polym Sci 1993, 1, 50.
4. Wild, L. Adv Polym Sci 1990, 98, 1.
5. Soares, J. B. P. Anantawaraskul, S. J Polym Sci Part B: Polym Phys 2005, 43, 1557.
6. Monrabal, B. TREF and CRYSTAF technologies for polymer characterization. In Encyclopedia of Analytical Chemistry, Mayers, R. A., Ed.; John Wiley & Sons, Inc.: New York, 2000, Vol. 14, pp 1-20.
7. DesLauriers, P. J.; Rohlfing, D. C.; Hsieh, E. T. Polymer 2002, 43, 159.
8. Willis, J. N.; Wheeler, L. Adv Chem Ser 1995, 247, 253.
9. Tackx, P.; Bremmers, S. Polym Mater Sci Eng 1998, 78, 50.
10. Luruli, N.; Grumel, V.; Brüll, R.; Du Toit, A.; Pasch, H.; van Reenen, A. J.; Raubenheimer, H. G. J Polym Sci Part A: Polym Chem 2004, 42, 5121.
11. de Goede, S.; Brüll, R.; Pasch, H.; Marshall, N. Macromol Symp 2003, 193, 35.
12. Graef, S. M.; Brüll, R.; Pasch, H.; Wahner, U. M. e-polymer 2003, e-005.
13. Mathot, V. B. F. J Therm Anal Cal 2001, 64, 15.
14. Pijpers, M. F. J.; Mathot, V. B. F.; Goderis, B.; Scherrenberg, R.; van der Vegte, E. Macromolecules 2002, 35, 3601.
15. McGregor, C.; Saunders, H. M.; Buckton, G.; Saklatvala, R. D.; Thermochimica Acta 2004, 417, 231.
16. Abdulkarim, S. M.; Long, K.; Lai, O. M.; Muhammad, S. K. S.; Ghazali, H. M. Food Chem 2005, 93, 253.
17. Busico, V.; Cipullo, R. Prog Polym Sci 2001, 26, 443.
18. Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J Am Chem Soc 1992, 114, 1025.
19. Ewen, J. J Am Chem Soc 1984, 106, 6355.
20. Zambelli, A.; Ammendola, P.; Grassi, A.; Longo, R; Proto, A. Macromolecules 1986, 19, 2703.
21. Cheng, H.; Ewen, J. Makromol Chem 1931 1989, 190.
22. Luruli, N.; Heinz, L.; Grumel, V.; Brüll, R.; Pasch, H.; Raubenheimer, H. G. Polymer 2006, 47. 56.
23. Heiland, K.; Kaminsky, W.; Makromol Chem Phys 1992, 193, 601.
24. Mathot, V. B. F.; Pijpers, M. F. J Polym Bull 1984, 11, 297.
25. Mathot, V. B. F. In Calorimetry and Thermal Analysis of Polymers; Mathot, V. B. F., Ed.; Hanser Publishers: Munich, 1994; Chapter 9, pp 231-299.