Catalytic seawater flue gas desulfurization process: An experimental pilot plant study

Environmental Science and Technology

Volumn 41, Issue 20, 2007, Pages 7114-7119

  Vidal B , F ^a   Ollero, P ^a   Gutierrez Ortiz F J ^a   Villanueva, A ^a  

^a UNIVERSITY OF SEVILLE   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC EFFECT; NONCATALYTIC OXIDATION; PACKED TOWER; SPRAY COLUMN;

ACTIVATED CARBON; CATALYTIC OXIDATION; DESULFURIZATION; ECONOMIC ANALYSIS; PILOT PLANTS; SEAWATER;

FLUE GASES;

SEA WATER;

ACTIVATED CARBON; CATALYTIC OXIDATION; DESULFURIZATION; ECONOMIC ANALYSIS; FLUE GASES; PILOT PLANTS; SEAWATER;

ACTIVATED CARBON; ASSESSMENT METHOD; CATALYSIS; COMPARATIVE STUDY; COST-BENEFIT ANALYSIS; GAS; OXIDATION; PH; REMOVAL EXPERIMENT; SEAWATER; SULFUR; WATER FLOW;

ARTICLE; CATALYSIS; CATALYST; DESULFURIZATION; EXPERIMENTAL STUDY; FLUE GAS; INTERMETHOD COMPARISON; OXIDATION; PH; PILOT STUDY; TECHNIQUE;

CARBON; CATALYSIS; GASES; OXIDATION-REDUCTION; PILOT PROJECTS; SEAWATER; SULFUR;

EID: 35348893326     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es0706899     Document Type: Article

References (18)

1. Takeshita, M.; Soud, H. N. FGD Performance and Experience on Coal Fired Plants; IEACR/58; IEA Coal Research: London, 1993.
2. Soud, H. N. Developments in FGD; CCC/29; IEA Coal Research: London, 2000.
3. Bromley, L. A. Use of seawater to scrub sulfur dioxide from stack gases. Int. J. Sulfur Chem. 1972, B, 7, 1, 77-84.
4. Tokerud, A. Sea Water used as SO2 removal agent. Modern-Power-Syst. June 1989, 9, 6, 21-25.
5. Radojevic, M. The use of sea water for flue gas desulphurisation. Environ. Technol. Lett. 1989, 10, 71-76.
6. Tilly, B.; Griffiths, A.; Golland, E. Flue gas Desulphurisation at Longannet. Institute of Energy's second international conference on combustion and emissions control. Inst. Energy, London 1995, 49-60.
7. Vidal B., F.; Ollero, P. A Kinetic Study of the Oxidation of S(IV) in Seawater. Environ. Sci. Technol. 2001, 35 (13), 2792-2796.
8. Vidal B., F.; Ollero, P.; Gutierrez Ortiz., F. J.; Arjona, R. Catalytic Oxidation of S(IV) in Seawater Slurries of activated Carbon. Environ. Sci. Technol. 2005, 39 (13), 5031-5036.
9. Clarke, A. G.; Radojévic, M. Chloride Ion effects on the aqueous oxidation of SO2. Atmos. Environ. 1983. 17 (3), 617-624.
10. Zheng, Y. J.; Kiil, S.; Johnsson, J. E. Experimental investigation of a pilot-scale jet bubbling reactor for wet flue gas desulphurization. Chem. Eng. Sci. 2003, 58, 4695-4703.
11. Gutiérrez Ortiz, F. J.; Vidal Barrero, F.; Ollero, P.; Salvador, L.; Cortés, V. Pilot-Plant Technical Assessment of Wet Flue Gas Desulfurization Using Limestone. Ind. Eng. Chem. Res. 2006, 45, 1466-1477.
12. Vohler, O. et al. Activated Carbon. Ullmann's Encyclopedia of Industrial Chemistry; Wiley-VCH Verlag GmbH: Weinheim, Germany, 2001.
13. Sivaji, K.; Murty, G. S. R. N. Kinetics of sulphite oxidation reaction. Ind. Eng. Chem. Fundam. 1982, 21, 344-352.
14. Chen-Chen, F.; McCoy, B. J.; Smith, J. M. Slurry Reactor Studies of Homogeneous and Heterogeneous Reactions. AICHE J. 1989, 35, 2, 259-266.
15. Zhang, J.-Z.; Millero, F. J. The rate of sulfite oxidation in seawater. Geochim. Cosmochim. Acta 1991, 55, 677-685.
16. Ermakov, A. N.; Poskrebyshev, G. A.; Purmal, A. P. Sulfite Oxidation: The State-of-the-Art of the Problem. Kinet. Catal. 1997, 38, 3, 295-308.
17. Shaikh, A. A.; Zaidi, S. M. J. Kinetics of Catalytic Oxidation of Aqueous Sodium Sulfite. React. Kinet. Catal. Lett. 1998, 64, 2, 343-349.
18. Vidal B., F.; Ollero, P. Response to Comment on "A Kinetic Study of the Oxidation of S(IV) in Seawater". Environ. Sci. Technol. 2002, 36 (4), 818-819.