Sulfur K-edge XAS of WV{double bond, long}O vs. MoV{double bond, long}O bis(dithiolene) complexes: Contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes

Journal of Inorganic Biochemistry

Volumn 101, Issue 11-12, 2007, Pages 1594-1600

  Tenderholt, Adam L ^a   Szilagyi, Robert K ^a   Holm, Richard H ^b   Hodgson, Keith O ^a,c   Hedman, Britt ^c   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

^b HARVARD UNIVERSITY   (United States)

^c SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

Author keywords

Density functional theory; Dithiolene complex; Molybdenum; Oxotransferase; Relativistic effects; Tungsten; X ray absorption spectroscopy

Indexed keywords

CARBON; MOLYBDENUM COMPLEX; NITROGEN; SULFUR; TUNGSTEN DERIVATIVE;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL BOND; DENSITY FUNCTIONAL THEORY; ENERGY; OXIDATION REDUCTION POTENTIAL; OXIDATION REDUCTION REACTION; ROENTGEN SPECTROSCOPY;

ABSORPTIOMETRY, PHOTON; ENZYMES; MOLECULAR STRUCTURE; MOLYBDENUM; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; SULFUR; THERMODYNAMICS; TUNGSTEN;

EID: 35348884868     PISSN: 01620134     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jinorgbio.2007.07.011     Document Type: Article

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