A new copper(II) di-μ2-carboxylato bridged dinuclear complex: [Cu(oda)phen]2 · 6H2O (oda = oxydiacetate, phen = phenanthroline)

Inorganic Chemistry Communications

Volumn 10, Issue 11, 2007, Pages 1249-1252

  Baggio, Ricardo ^a   Calvo, Rafael ^b   Garland, Maria T ^c   Peña, Octavio ^d   Perec, Mireille ^e   Slep, Leonardo D ^e  

^a DEPARTAMENTO DE FÍSICA   (Argentina)

^b UNIVERSIDAD NACIONAL DEL LITORAL   (Argentina)

^c DEPARTAMENTO DE FÍSICA   (Chile)

^d UNIVERSITÉ DE RENNES 1   (France)

^e Instituto de Quimica Fisica de los Materiales Medio Ambiente y Energia   (Argentina)

Author keywords

Copper(II); Crystal structure; Magnetism; Oxydiacetate

Indexed keywords

EID: 35348870326     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2007.07.028     Document Type: Article

References (24)

1. Bleaney B., and Bowers K.D. Proc. Roy. Soc. London A 214 (1952) 451
2. Kahn O. Molecular Magnetism (1993), VCH Publ., New York
3. Willet R.D., Gatteschi D., and Kahn O. Magneto-Structural Correlations in Exchange Coupled Systems vol. C140 (1985), Reidel, Dordrecht, The Netherlands
4. Gatteschi D., Kahn O., Miller J.S., and Palacio F. Magnetic Molecular Materials vol. E198 (1991), Plenum, New York
5. Oldham C. In: Wilkinson G., Gillard R.D., and McCleverty J.A. (Eds). Comprehensive Coordination Chemistry vol. 2 (1987), Pergamon, London 435
6. Grirrane A., Pastor A., Ienco A., Mealli C., and Galindo A. J. Chem. Soc. Dalton Trans. (2002) 371 and references therein
7. Whitlow S., and Davey G. J. Chem. Soc. Dalton Trans. (1975) 1228
8. Cao L., Li N., and Xu D.-J. Acta Crystallogr. E 60 (2004) m1066
9. Gonzalez-Pérez J.M., Alarcón-Payer C., Castiñeiras A., Pivetta T., Lezama L., Choquesillo- Lazarte D., Crisponi G., and Niclós-Gutiérrez J. Inorg. Chem. 45 (2006) 877
10. Bonomo R.P., Rizzarelli E., Bresciani Pahor N., and Nardin G. Inorg. Chim. Acta 54 (1981) L17
11. Bresciani Pahor N., Nardin G., Bonomo R.P., and Rizzarelli E. J. Chem. Soc. Dalton Trans. (1983) 1797
12. Wu Z.-Y., Xu D.-J., Luo Y., Wu J.-Y., and Chiang M.Y. Acta Crystallogr. C 59 (2003) m307
13. Baggio R., Garland M.T., Manzur J., Peña O., Perec M., Spodine E., and Vega A. Inorg. Chim. Acta 286 (1999) 74
14. Grirrane A., Pastor A., Álvarez E., Mealli C., Ienco I., and Galindo A. Inorg. Chem. Commun. 9 (2006) 160
15. Grirrane A., Pastor A., Galindo A., del Rio D., Orlandini A., Mealli C., Ienco I., Caneschi A., and Sanz J.F. Angew. Chem. Int. Ed. 44 (2005) 3429
16. -1): 1630vs,vbr, 1570vs, 1517s, 1496m, 1428s.
17. min = 0.5905/0.4721, data/parameters = 3072/265, Siemens R3m diffractometer, graphite monochromated Mo Kα radiation (λ = 0.71073 Å). Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication No. CCDC 649553. Copies of this information can be obtained, free of charge from The Director, CCDC, 12 Union Road, Cambridge, CB21EZ, UK (fax: +44 1223 336033; e-mail:deposit@ccdc.cam.ac.uk).
18. PLATON:. Spek A.L. J. Appl. Crystallogr. 36 (2003) 7
19. SHELXL97:. Sheldrick G.M. (1997), University of Göttingen, Germany
20. SHELXTL-NT:. Bruker. (Version 6.10) for Windows NT (2001), Bruker AXS Inc., Madison, Wisconsin, USA
21. CDS:. Allen F.H. Acta Crystallogr. B 58 (2002) 380
22. Susceptibility and magnetization measurements were performed in powder samples with a Quantum Design SQUID magnetometer model MPMS XL5, using calibrated gelatin capsules as sample holders. The magnetic susceptibility was measured in the temperature interval between 2 and 300 K, with an applied field of 25 mT. The magnetization measurements were performed at 2 K, with a maximum field of 5 T. The susceptibility and magnetization data were corrected for diamagnetism of the constituent atoms, obtained using Pascal's constants and temperature independent paramagnetism [2]. The contribution of the gelatin capsule was subtracted from the measured values.
23. Soda T., Kitagawa Y., Onishi T., Takano Y., Shigeta Y., Nagao H., Yoshioka Y., and Yamaguchi K. Chem. Phys. Lett. 319 (2000) 223
24. Frisch M.J., et al. Gaussian 03, Revision D.01 (2004), Gaussian Inc., Wallingford, CT