메뉴 건너뛰기




Volumn 46, Issue 20, 2007, Pages 8258-8263

Sulfoxide as a ligand in iron(II) porphyrinates: S- or O-bound?

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; PORPHYRIN; SULFOXIDE;

EID: 35348845769     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic7008495     Document Type: Article
Times cited : (12)

References (50)
  • 2
    • 0003859242 scopus 로고    scopus 로고
    • Gilbert, D. L, Colton, C. A, Eds, Kluwer Academic/Plenum: New York
    • Gilbert, D. L.; Colton, C. A.; Eds. Reactive Oxygen Species in Biological Systems; Kluwer Academic/Plenum: New York, 1999.
    • (1999) Reactive Oxygen Species in Biological Systems
  • 6
    • 35348845379 scopus 로고    scopus 로고
    • The following abbreviations are used in this paper: NMR, nuclear magnetic resonance; AcMP8, N-acetylmicroperoxidase-8; TPP, dianion of meso-tetraphenylporphyrin; TpivPP, dianion of α,α,α, α-tetrakis-(o-pivalamidophenyl)porphyrin; TDCP(NO2) 8P, dianion of meso-tetrakis(o-dichlorophenyl)-β- octanitroporphyrin; PPIX, dianion of protoporphyrin IX; Np, porphyrinato nitrogen; TMSO; tetramethylenesulfoxide; THT, tetrahydrothiophen; PMS, pentamethylene sulfide; THF, tetrahydrogenfuran; EtOH, ethanol; PrOH, propanol; DMSO, dimethylsulfoxide; DecMS, thioethers n-decylmethyl sulfide; SPh2, diphenyl sulfide; 1-Melm, 1-methylimidazole; 1-Vinlm, 1-vinylimidazole; 1-BzylIm, 1-benzylimidazole; 4-CNPy, 4-cyanopyridine; 3-CNPy, 3-cyanopyridine; 4-MePy, 4-methylpyridine; Pc, phthalocyanine; HSAB, hard-soft-acid-base; ESR, electronic spin resonance; 18-C-6,1,4,7,10,13,16-hexaoxacyclooctadecane; 222,1,10-diaza
    • p, porphyrinato nitrogen; TMSO; tetramethylenesulfoxide; THT, tetrahydrothiophen; PMS, pentamethylene sulfide; THF, tetrahydrogenfuran; EtOH, ethanol; PrOH, propanol; DMSO, dimethylsulfoxide; DecMS, thioethers n-decylmethyl sulfide; SPh2, diphenyl sulfide; 1-Melm, 1-methylimidazole; 1-Vinlm, 1-vinylimidazole; 1-BzylIm, 1-benzylimidazole; 4-CNPy, 4-cyanopyridine; 3-CNPy, 3-cyanopyridine; 4-MePy, 4-methylpyridine; Pc, phthalocyanine; HSAB, hard-soft-acid-base; ESR, electronic spin resonance; 18-C-6,1,4,7,10,13,16-hexaoxacyclooctadecane; 222,1,10-diaza-4,7,-13,16,21,24-hexaoxabicyclo[8.8.8]hexacosane.
  • 15
    • 0003946851 scopus 로고
    • Smith, K. M, Ed, Elsevier Scientifc Publishing: Amsterdam, The Netherlands, Chapter 5
    • (b) Buchler, J. W. In Porphyrins and Metalloporphyrins; Smith, K. M., Ed.; Elsevier Scientifc Publishing: Amsterdam, The Netherlands, 1975; Chapter 5.
    • (1975) Porphyrins and Metalloporphyrins
    • Buchler, J.W.1
  • 18
    • 35348928875 scopus 로고    scopus 로고
    • Even under these dilute solution conditions, we see no spectral changes resulting from the presence of EtSH and we conclude that EtSH does not coordinate to iron. The relatively long times of the titrations do require EtSH
    • Even under these dilute solution conditions, we see no spectral changes resulting from the presence of EtSH and we conclude that EtSH does not coordinate to iron. The relatively long times of the titrations do require EtSH.
  • 22
    • 35348906923 scopus 로고    scopus 로고
    • R1, Σ||Fo, Fc|, Σ|Fo| and wR2, w(Fo2, Fc2)2, wFo 4]}1/2. The conventional R factors R1 are based on F, with F set to 0 for negative F2. The criterion of F2 > 2σ(F2) was used only for calculating R1. R factors based on F2(wR2) are statistically about twice as large as those based on F, and R factors based on all data will be even larger
    • 2(wR2) are statistically about twice as large as those based on F, and R factors based on all data will be even larger.
  • 24
    • 0001602005 scopus 로고    scopus 로고
    • Collman, J. P.; Brauman, J. I.; Doxsee, K. M.; Halben, T. R.; Bumenberg, E.; Linder, R. E.; LaMar, G. N.; Del, Gaudio, J.; Lang, G.; Spartalian, K. J. Am. Chem. Soc. 1980, 102, 4182.
    • Collman, J. P.; Brauman, J. I.; Doxsee, K. M.; Halben, T. R.; Bumenberg, E.; Linder, R. E.; LaMar, G. N.; Del, Gaudio, J.; Lang, G.; Spartalian, K. J. Am. Chem. Soc. 1980, 102, 4182.
  • 49
    • 24244471921 scopus 로고    scopus 로고
    • Forgács, G.; Schultz, G.; I. Hargittai, I.; Jalsovszky, I.; Kucsman, A.; J. Chem. Soc., Faraday Trans. 1989, 2, 85, 303.
    • Forgács, G.; Schultz, G.; I. Hargittai, I.; Jalsovszky, I.; Kucsman, A.; J. Chem. Soc., Faraday Trans. 1989, 2, 85, 303.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.