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Volumn 72, Issue 21, 2007, Pages 8095-8098

Characterization of equatorial and axial six-membered-ring peroxyl radicals

Author keywords

[No Author keywords available]

Indexed keywords

PEROXYL MOIETY;

EID: 35348820516     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo7014592     Document Type: Article
Times cited : (7)

References (27)
  • 11
    • 35348833804 scopus 로고    scopus 로고
    • 5b In fact, a very broad singlet was obtained that decayed completely on cutting off the light, leaving no long-lived peroxyl signal. The observed singlet is presumably due to a mixture of cyclohexyl and n-alkyl peroxyl radicals, with the lines being broadened by the increased viscosity induced by the dodecyl chains.
    • 5b In fact, a very broad singlet was obtained that decayed completely on cutting off the light, leaving no long-lived peroxyl signal. The observed singlet is presumably due to a mixture of cyclohexyl and n-alkyl peroxyl radicals, with the lines being broadened by the increased viscosity induced by the dodecyl chains.
  • 12
    • 35348863386 scopus 로고    scopus 로고
    • Dβ ≤ 0.9 G (by simulation).
    • Dβ ≤ 0.9 G (by simulation).
  • 13
    • 35348872250 scopus 로고    scopus 로고
    • Note that the shoulders on the high-field components of the spectra in parts d and e of Figure 1 are also due to t-BuOO*.
    • Note that the shoulders on the high-field components of the spectra in parts d and e of Figure 1 are also due to t-BuOO*.
  • 14
    • 35348815826 scopus 로고    scopus 로고
    • The rapid decay of the singlet in Figure 1f confirmed that it was not the persistent t-BuOO*.
    • The rapid decay of the singlet in Figure 1f confirmed that it was not the persistent t-BuOO*.
  • 18
    • 35348862742 scopus 로고    scopus 로고
    • 1 in cyclohexylperoxyl.
    • 1 in cyclohexylperoxyl.
  • 22
    • 35348907591 scopus 로고    scopus 로고
    • Frisch, M. J.; et al. Gaussian 03, revision D.01; Gaussian, Inc.,: Pittsburgh, PA, 2003 (see the Supporting Information for full citation).
    • Frisch, M. J.; et al. Gaussian 03, revision D.01; Gaussian, Inc.,: Pittsburgh, PA, 2003 (see the Supporting Information for full citation).
  • 25
    • 35348898691 scopus 로고    scopus 로고
    • -1 involving donation from a lone pair orbital on the ring oxygen to an antibonding orbital associated with the peroxyl C-O. The 1,3-dioxa axial radicals, 5a and 6a, exhibited two interactions of the same magnitude and character.
    • -1 involving donation from a lone pair orbital on the ring oxygen to an antibonding orbital associated with the peroxyl C-O. The 1,3-dioxa axial radicals, 5a and 6a, exhibited two interactions of the same magnitude and character.
  • 26
    • 35348841788 scopus 로고    scopus 로고
    • See the Supporting Information for the averaging method
    • See the Supporting Information for the averaging method.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.