-
2
-
-
0035276296
-
-
(b) Schuchardt, U.; Cardoso, D.; Sercheli, R.; Pereira, R.; da Cruz, R. S.; Guerreiro, M. C.; Mandelli, D.; Spinace, E. V.; Pires, E. L. Appl. Catal. A 2001, 211, 1.
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(2001)
Appl. Catal. A
, vol.211
, pp. 1
-
-
Schuchardt, U.1
Cardoso, D.2
Sercheli, R.3
Pereira, R.4
da Cruz, R.S.5
Guerreiro, M.C.6
Mandelli, D.7
Spinace, E.V.8
Pires, E.L.9
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3
-
-
17744397135
-
-
(c) Hermans, I.; Nguyen, T. L.; Jacobs, P. A.; Peeters, J. ChemPhysChem 2005, 6, 637.
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(2005)
ChemPhysChem
, vol.6
, pp. 637
-
-
Hermans, I.1
Nguyen, T.L.2
Jacobs, P.A.3
Peeters, J.4
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7
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-
9444277149
-
-
DiLabio, G. A.; Ingold, K. U.; Roydhouse, M. D.; Walton, J. C. Org. Lett. 2004, 6, 4319.
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(2004)
Org. Lett
, vol.6
, pp. 4319
-
-
DiLabio, G.A.1
Ingold, K.U.2
Roydhouse, M.D.3
Walton, J.C.4
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11
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-
35348833804
-
-
5b In fact, a very broad singlet was obtained that decayed completely on cutting off the light, leaving no long-lived peroxyl signal. The observed singlet is presumably due to a mixture of cyclohexyl and n-alkyl peroxyl radicals, with the lines being broadened by the increased viscosity induced by the dodecyl chains.
-
5b In fact, a very broad singlet was obtained that decayed completely on cutting off the light, leaving no long-lived peroxyl signal. The observed singlet is presumably due to a mixture of cyclohexyl and n-alkyl peroxyl radicals, with the lines being broadened by the increased viscosity induced by the dodecyl chains.
-
-
-
-
12
-
-
35348863386
-
-
Dβ ≤ 0.9 G (by simulation).
-
Dβ ≤ 0.9 G (by simulation).
-
-
-
-
13
-
-
35348872250
-
-
Note that the shoulders on the high-field components of the spectra in parts d and e of Figure 1 are also due to t-BuOO*.
-
Note that the shoulders on the high-field components of the spectra in parts d and e of Figure 1 are also due to t-BuOO*.
-
-
-
-
14
-
-
35348815826
-
-
The rapid decay of the singlet in Figure 1f confirmed that it was not the persistent t-BuOO*.
-
The rapid decay of the singlet in Figure 1f confirmed that it was not the persistent t-BuOO*.
-
-
-
-
16
-
-
0003740356
-
-
Thatcher, G. R, Ed, American Chemical Society: Washington, DC
-
(a) Thatcher, G. R. The Anomeric Effect and Associated Stereoelectronic Effects; Thatcher, G. R., Ed.; American Chemical Society: Washington, DC, 1993.
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(1993)
The Anomeric Effect and Associated Stereoelectronic Effects
-
-
Thatcher, G.R.1
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18
-
-
35348862742
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-
1 in cyclohexylperoxyl.
-
1 in cyclohexylperoxyl.
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-
-
-
20
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-
0345491105
-
-
(b) Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785-789.
-
(1988)
Phys. Rev. B
, vol.37
, pp. 785-789
-
-
Lee, C.1
Yang, W.2
Parr, R.G.3
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22
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-
35348907591
-
-
Frisch, M. J.; et al. Gaussian 03, revision D.01; Gaussian, Inc.,: Pittsburgh, PA, 2003 (see the Supporting Information for full citation).
-
Frisch, M. J.; et al. Gaussian 03, revision D.01; Gaussian, Inc.,: Pittsburgh, PA, 2003 (see the Supporting Information for full citation).
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-
-
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23
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0041352870
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-
(a) Lii, J. H.; Chen, K. H.; Durkin, K. A.; Allinger, N. L. J. Comput. Chem. 2003, 24, 1473.
-
(2003)
J. Comput. Chem
, vol.24
, pp. 1473
-
-
Lii, J.H.1
Chen, K.H.2
Durkin, K.A.3
Allinger, N.L.4
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24
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-
29444436339
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-
(b) Jones Wheldon, A.; Vickrey, T. L.; Tschumper, G. S. J. Phys. Chem. A 2005, 109, 11073.
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(2005)
J. Phys. Chem. A
, vol.109
, pp. 11073
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-
Jones Wheldon, A.1
Vickrey, T.L.2
Tschumper, G.S.3
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25
-
-
35348898691
-
-
-1 involving donation from a lone pair orbital on the ring oxygen to an antibonding orbital associated with the peroxyl C-O. The 1,3-dioxa axial radicals, 5a and 6a, exhibited two interactions of the same magnitude and character.
-
-1 involving donation from a lone pair orbital on the ring oxygen to an antibonding orbital associated with the peroxyl C-O. The 1,3-dioxa axial radicals, 5a and 6a, exhibited two interactions of the same magnitude and character.
-
-
-
-
26
-
-
35348841788
-
-
See the Supporting Information for the averaging method
-
See the Supporting Information for the averaging method.
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