Hydrogen release from a mixture of NaBH4 and Mg(OH)2

International Journal of Hydrogen Energy

Volumn 32, Issue 15 SPEC. ISS., 2007, Pages 3370-3375

  Drozd, Vadym ^a   Saxena, Surendra ^a   Garimella, Subrahmanyam V ^a   Durygin, Andriy ^a  

^a FLORIDA INTERNATIONAL UNIVERSITY   (United States)

Author keywords

Hydride hydroxide reaction; Hydrogen generation

Indexed keywords

CRYSTALLINE MATERIALS; HIGH TEMPERATURE EFFECTS; HYDRIDES; HYDROGEN PRODUCTION; REACTION KINETICS;

HYDROGEN GENERATION; HYDROXIDE REACTION;

SODIUM COMPOUNDS;

EID: 35348818958     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2007.02.007     Document Type: Article

References (34)

1. Stasinevich D.S., and Egorenko G.A. Thermographic study of borohydrides of alkali metals and magnesium at pressures up to 10 atm. Zh Neorg Khim 13 3 (1968) 654-658
2. Ostroff A.G., and Sanderson R.T. Oxidation and thermal decomposition of sodium and potassium borohydrides. J Inorg Nucl Chem 4 (1957) 230-231
3. 4. J Alloys Compd 356-357 (2003) 515-520
4. Cho Y.W., Shim J.H., and Lee B.J. Thermal destabilization of binary and complex metal hydrides by chemical reaction: a thermodynamic analysis. Comput Coupling Phase Diagr Thermochem 30 (2006) 65-69
5. 4). J Alloys Compd 427 1-2 (2007) 291-299
6. Schlesinger H.I., Brown H.C., Finholt A.E., Gilbreath J.R., Hoekstra H.R., and Hyde E.K. Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen. J Am Chem Soc 75 (1953) 215-219
7. Aiello R., Sharp J.H., and Matthews M.A. Production of hydrogen from chemical hydrides via hydrolysis with steam. Int J Hydrogen Energy 24 12 (1999) 1123-1130
8. Ramachandran PV, Hazra D, Reddy MVR. Sodium borohydride cycle: controlled generation of hydrogen and efficient regeneration. US patent application no. 11/125,796; 2004.
9. Shafirovich E, Diakov V, Varma A. Combustion-assisted hydrolysis of sodium borohydride for hydrogen generation. Int J Hydrogen Energy 2007;32(2):207-11.
10. Chew WM, Ayers OE, Murfree JA, Martignoni P. Solid propellants for generating hydrogen. US patent no. 4,061,512; 1977.
11. 4 (M = Li, Na, and K). Mater Sci Eng B 108 (2004) 51-53
12. Stull DR, Prophet H. JANAF Thermochemical tables. Washington: U.S. Department of Commerce; 1985 [Cp Fitted by CRCT, Montreal].
13. Kojima Y., Suzuki K., Fukumoto K., Kawai Y., Kimbara M., Nakanishi H., et al. Development of 10 kW-scale hydrogen generator using chemical hydride. J Power Sources 125 (2004) 22-26
14. Amendola S.C., Onnerud P., Kelly M.T., Pettilo P.J., Sharp-Goldman S.L., and Binder M. A novel high power density borohydride-air cell. J Power Sources 84 (1999) 130-133
15. Li Z.P., Liu B.H., Arai K., and Suda S. A fuel cell development for using borohydrides as the fuel. J Electrochem Soc 150 7 (2003) A868-A872
16. Kaufman C.M., and Sen B. Hydrogen generation by hydrolysis of sodium tetrahydroborate: effect of acids and transition metals and their salts. J Chem Soc, Dalton Trans 2 (1985) 307-313
17. Levy A., Brown J.B., and Luons C.J. Catalyzed hydrolysis of sodium borohydride. Ind Eng Chem 52 3 (1960) 211-214
18. 4 solution using the high-performance Co-B catalyst. J Power Sources 144 (2005) 129-134
19. Amendola S.C., Sharp-Goldman S.L., Janjua M.S., Spencer N.C., Kelly M.T., Petillo P.J., et al. A safe, portable hydrogen gas generator using aqueous borohydride solution and Ru catalyst. Int J Hydrogen Energy 25 (2000) 969-975
20. Kojima Y., Suzuki K., Fukumoto K., Sasaki M., Yamamoto T., Kawai Y., et al. Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide. Int J Hydrogen Energy 27 (2002) 1029-1034
21. Kojima Y., and Haga T. Recycling process of sodium metaborate to sodium borohydride. Int J Hydrogen Energy 28 9 (2003) 989-993
22. Ay M., Midilli A., and Dince I. Investigation of hydrogen production from boron compounds for pem fuel cells. J Power Sources 157 (2006) 104-113
23. Mazur DJ, Weinberg NL, Guibault LJ, Chin AA, Tomantschger K. One-step electrosynthesis of borohydride. US patent application no. 20050224365;2005.
24. L'vov B.V., and Ugolkov V. Kinetics and mechanism of free-surface decomposition of Group IIA and IIB hydroxides analyzed thermogravimetrically by the third-law method. Thermochim Acta 413 1-2 (2004) 7-15
25. Harrison LG. The theory of solid state phase kinetics, In: Bamford H, Tipper CFH, editors, Chemical kinetics. Amsterdam: Elsevier, 1969. p. 458-462.
26. Mikheeva V.I., Breitsis V., Kuznetsov V.A., and Kryukova O.N. Reaction of sodium tetrahydroborate with sodium hydroxide. Dokl Akad Nauk SSSR. 187 1 (1969) 103-105
27. 4) during controlled mechanical milling. J Alloys Compd 397 1-2 (2005) 276-281
28. 6 by X-ray powder diffraction. Mater Res Bull 23 3 (1998) 447-452
29. Toby B.H. EXPGUI, a graphical user interface for GSAS. J. Appl. Cryst. 34 (2001) 210-221
30. Larson AC, Von Dreele RB, General structure analysis system (GSAS), Los Alamos National Laboratory Report LAUR 86-748, 2000.
31. Meera B.N., and Ramakrishna J. Raman study of borate glasses. J Non-Cryst Solids 159 1-2 (1993) 1-21
32. Konijnendijk W.L., and Stevels J.M. The structure of borate glasses studied by Raman scattering. J Non-Cryst Solids 18 3 (1975) 307-331
33. Youngman R.E., and Zwanziger J.W. Network modification in potassium borate glasses: structural studies with NMR and Raman spectroscopies. J Phys Chem 100 (1996) 16720-16728
34. 3 - CaO glasses. J Mol Struct 651-653 (2003) 485-488