A new method to visualize and characterize the pore structure of TENCEL® (lyocell) and other man-made cellulosic fibres using a fluorescent dye molecular probe

Journal of Applied Polymer Science

Volumn 106, Issue 3, 2007, Pages 2083-2091

  Abu Rous, Mohammad ^a,b   Varga, Ksenija ^a   Bechtold, Thomas ^a   Schuster, Kurt Christian ^b  

^a INNSBRUCK MEDICAL UNIVERSITY   (Austria)

^b LENZING AG   (Austria)

Author keywords

Cellulosic fibers; Diffusion; Dyes pigments; Fluorescence; Structure

Indexed keywords

DIFFUSION; DYES; ENZYME ACTIVITY; FLUORESCENCE MICROSCOPY; NATURAL FIBERS; PORE STRUCTURE; SWELLING;

CELLULOSIC FIBERS; DYE PENETRATION; FLUORESCENT DYE;

CELLULOSE;

CELLULOSE; DIFFUSION; DYES; NATURAL FIBERS; SWELLING;

CELLULOSIC FIBER; DIFFUSION; DYE; FIBER PROPERTY; FLUORESCENCE; MOLECULAR STRUCTURE; VISCOSE RAYON FIBER;

EID: 34948887776     PISSN: 00218995     EISSN: 10974628     Source Type: Journal    
DOI: 10.1002/app.26722     Document Type: Article

References (31)

1. Fink, H. P.; Ganster, J.; Fraatr, J.; Nywlt, M. Relation between structure and properties of cellulosic man-made fibres. Paper presented at the Akzo-Nobel Viscose Chemistry's Seminar, Stockholm, May 30 - June 3, 1994.
2. Atalla, R. In Comprehensive Natural Products Chemistry; Barton, D., Nakanishi, K., Meth-Cohn, O., Eds.; Vol. 3: Carbohydrates and Their Derivatives Including Tannins, Cellulose, and Related Lignins; Pinto, B. M., Vol. Ed.; Elsevier Science: Oxford, 1999; Chapter 16.
3. Lenz, J.; Schurz, J.; Wrentschur, E. Holzforschung 1988, 42, 117.
4. Hearle, J. W. S. J Polym Sci 1958, 28, 432.
5. Hearle, J. W. S. In Regenerated Cellulose Fibres, Physical Structure and Fibre Properties; Woodings, C., Ed.; Woodhead: Cambridge, England, 2001; Chapter 8.
6. Bredereck, K.; Hermanutz, F. Rev Prog Color 2005, 35, 59.
7. Horio, M. Text Res J 1950, 20, 373.
8. Sisson, W. A. Text Res J 1960, 30, 153.
9. Cox, N. L. US Pat. 2,535,044, 2,535,045, and 2,536,014 (1950).
10. Calistru, E.; Ciovica, S. Caluloza Hirtie 1968, 17, 137.
11. Zhang, J.; Zhu, H.; Shi, M.; Lai, K. Chem Fibres Int 1999, 49, 494.
12. Coulsey, H. A.; Smith, S. B. Lenzinger Berichte 1996, 75, 51.
13. Mortimer, S. A. Etude de la Structuration des Fibres Lyocell, Ph.D. Thesis, CERMAV-CNRS, Université Joseph Fourier - Grenoble I, 1995.
14. Schuster, K. C.; Rohrer, C.; Eichinger, D.; Schmidtbauer, J.; Aldred, P.; Firgo, H. In Natural Fibres, Plastics and Composits; Wallenberger, F. T.; Weston, N. E., Eds.; Kluwer Academic: Boston, 2003; Chapter 9.
15. Shen, T. C.; Cabasso, J. Macromolecular Solutions: Solvent-Property Relationship in Polymers; Seymour, R. B., Stahl, G. A., Eds.; Pergamon: New York, 1982.
16. Biganska, O. Etude phyisico-chimique des solutions de cellulose dans la N-methylmorpholine-N-oxyde, Ph.D. Thesis, L'Ecole Nationale des Mines de Paris, 2002.
17. TAPPI (Technical Association of the Pulp and Paper Industry). Standard T412 OM-94.
18. Bredereck, K.; Blüher, A.; Hoffmann-Frey, A. Das Papier 1990, 44, 648.
19. Gruber, M. Untersuchungen zur supramolekularen Struktur und Farbstoffadsorption von Cellulosefasern, Ph.D. Thesis, Institut für Textil- und Faserchemie, University of Stuttgart, 1998.
20. Kasahara K.; Sasaki, H.; Donkai, N.; Takagishi, T. Text Res J 2004, 74, 509.
21. Ibbett, R.; Kaenthong, S. Dyes Pigments 2006, 71, 168.
22. Abu-Rous, M.; Manian, A. P.; Rôder, T.; Lichtscheidl, I.; Schuster, K. C. Lenzinger Berichte 2004, 83, 92.
23. Abu Rous, M.; Ingolic, E.; Schuster, K. C. Cellulose 2006, 13, 411.
24. Schuster, K. C.; Suchomel, F.; Männer, J.; Abu-Rous, M.; Firgo, H. Macromol Symp 2006, 244, 149.
25. Abu Rous, M.; Ingolic, E.; Schuster, K. C. Revelation of the pore structure of Lyocell and other cellulosics applying fluorescence and electron microscopy. In Proceedings of the Fifth Autex Conference, Portoroz, Slovenia, June 2005. ISBN 86-435-0709-1.
26. Anonymous.TENCEL Dyeing and Finishing Manual; Courtaulds Fibres; Langweid a. L., Germany, p A6.
27. Ellmann, J. Personal communication; CIBA-Ceigy: Germany; 2006.
28. Shore, J. In Colorants and Auxiliaries, Vol. 2: Fluorescent Brightening Agents; Shore, J., Ed.; Society of Dyers and Colorists, 2002; Chapter 11.
29. Bach, H.; Pfeil, E.; Philippar W.; Reich M. Angew Chem Wiley: Germany, 1963, 9, 407.
30. Hagege, R.; Kassenbeck, P.; Meimoun, D.; Parisot, A. Text Res J 1969, 39, 1015.
31. Sjöberg, J.; Potthast, A.; Rosenau, T.; Kosma, P.; Sixta, H. Biomacromolecules 2005, 6, 3146.