Eu incorporation behavior of a Mg-Al-Cl layered double hydroxide

Clays and Clay Minerals

Volumn 55, Issue 4, 2007, Pages 354-360

  Curtius, Hilde ^a   Ufer, Kristian ^a  

^a FORSCHUNGSZENTRUM JÜLICH   (Germany)

Author keywords

Europium; Fuel elements; Incorporation; LDH; Secondary phases; Stacking faults

Indexed keywords

ADDITION REACTIONS; COPRECIPITATION; LATTICE CONSTANTS; MAGNESIUM ALLOYS; STACKING FAULTS; STOICHIOMETRY; SYNTHESIS (CHEMICAL);

MOLAR STOICHIOMETRY; SECONDARY PHASES;

EUROPIUM;

ANION; CRYSTAL STRUCTURE; EUROPIUM; HYDROXIDE; LATTICE DYNAMICS; LEACHING; MINERAL SYNTHESIS; PRECIPITATION (CHEMISTRY); STACKING; STOICHIOMETRY; X-RAY DIFFRACTION;

EID: 34848874459     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.2007.0550403     Document Type: Article

References (18)

1. Allmann, R. and Donnay, J.D.H. (1969) About the structure of iowaite. American Mineralogist, 54, 296-298.
2. Bergmann, J., Friedel, P. and Kleeberg, R. (1998) BGMN - a new fundamental parameters based Rietveld program for laboratory X-ray sources, its use in quantitative analysis and structure investigations. Commission of Powder Diffraction, International Union of Crystallography, CPD Newsletter, 20, 5-8.
3. Bookin, A.S. and Drits, V.A. (1993) Polytype diversity of the hydrotalcite-like minerals. I. Possible polytypes and their diffraction features. Clays and Clay Minerals, 41, 551-557.
4. Brücher, H., Curtius, H. and Fachinger, J. (2001) R&D for Back-End options for irradiated research reactor fuel in Germany. Transactions of the 5th Topical Meeting on Research Reactor Fuel Management, April 1-3 2001, Aachen, Germany, ENS RRFM.
5. Drits, V.A. and Bookin, A.S. (2001) Crystal structure and X-ray identification of layered double hydroxides. Pp. 39-92 in: Layered Double Hydroxides: Present and Future (V. Rives, editor). Nova Science, New York.
6. Drits, V. A. and Tchoubar, C. (1990) X-ray Diffraction by Disordered Lamellar Structures. Springer Verlag, New York, 371 pp.
7. Duff, C.M., Coughlin, J.U. and Hunter D.G. (2002) Uranium co-precipitation with iron oxide minerals. Geochimica et Cosmochimica Acta, 66, 3533-3547.
8. 35Cl NMR observations and molecular dynamics modelling. Chemistry of Materials, 14, 2078-2085.
9. Mazeina, L., Curtius, H., Fachinger, J. and Odoj, R. (2003) Characterisation of secondary products of uranium-aluminium material test reactor fuel element corrosion in repository-relevant brine. Journal of Nuclear Material, 323, 1-7.
10. Miyata, S. (1975) The synthesis of hydrotalcite-like compounds and their structures and physico-chemical properties. Clays and Clay Minerals, 31, 369-375.
11. 3. Journal of Inorganic and Nuclear Chemistry, 41, 525-532.
12. Plançon, A. (2002) CALCIPOW: a program for calculating the diffraction by disordered lamellar structures. Journal of Applied Crystallography, 35, 377.
13. Radha, A.V., Shivakumara, C. and Kamath, P.V. (2005) DIFFaX simulations of stacking faults in layered double hydroxides (LDHs). Clays and Clay Minerals, 53, 520-527.
14. Rietveld, H.M. (1967) Line profiles of neutron powder-diffraction peaks for structure refinement. Acta Crystallographica, 22, 151-152.
15. Solovyov, L.A. (2004) Full-profile refinement by derivative difference minimization. Journal of Appied Crystallography, 37, 743-749.
16. Stumpf, T., Curtius, H., Walther, C., Dardenne, K., Ufer, K. and Fanghänel, Th. (2007) Incorporation of Eu(III) into a hydrotalcite: a TRLFS and EXAFS study. Environmental Science and Technology, 41, 3186-3191.
17. Thomas, G.S., Rajamathi, M. and Kamath, P.V. (2004) DiffaX simulations of polytypism and disorder in hydrotalcite. Clays and Clay Minerals, 52, 693-699.
18. Weiss, A. and Toth, E. (1996) Untersuchungen zur Synthese, Quellungseigenschaften und Anionenaustausch von kristallchemisch modifizierten Doppelhydroxiden vom Hydrotalkit-Typ. Jahrestagung der DTTG, Freiberg, 267-276.