Synthesis, structure, electrochemistry, and Mössbauer effect studies of the ferraphosphadicarbollides [(C5R5)Fe(PC 2B8H10)] (R = H, Me)

European Journal of Inorganic Chemistry

Volumn , Issue 26, 2007, Pages 4190-4196

  Kudinov, Alexander R ^a   Herber, Rolfe H ^b   Zanello, Piero ^c   Perekalin, Dmitry S ^a   Glukhov, Ivan V ^a   Nowik, Israel ^b   Corsini, Maddalena ^c   Fedi, Serena ^c   Laschi, Franco ^c  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b HEBREW UNIVERSITY OF JERUSALEM   (Israel)

^c UNIVERSITY OF SIENA   (Italy)

Author keywords

Carboranes; Electrochemistry; Iron; M ssbauer spectroscopy; X ray diffraction

Indexed keywords

ATOMS; IRON; ISOMERS; SINGLE CRYSTALS; X RAY DIFFRACTION;

150 ° C; CARBORANES; CYCLIC VOLTAMMETRIC; ELECTROCHEMICAL INVESTIGATIONS; METAL ATOMS; MÖSSBAUE SPECTROSCOPY; OXIDATION PROCESS; ROOT MEAN SQUARE; TIME-SCALES; X- RAY DIFFRACTIONS;

ELECTROCHEMISTRY;

EID: 34748899610     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200700288     Document Type: Article

References (28)

1. M. F. Hawthorne, R. L. Pilling, J. Am. Chem. Soc. 1965, 87, 3987-3988.
2. D. S. Perekalin, J. Holub, D. G. Golovanov, K. A. Lyssenko, P. V. Petrovskii, B. Štíbr, A. R. Kudinov, Organometallics 2005, 24, 4387-4392.
3. a) R. H. Herber, A. R. Kudinov, P. Zanello, I. Nowik, D. S. Perekalin, V. I. Meshcheryakov, K. A. Lyssenko, M. Corsini, S. Fedi, Eur. J. Inorg. Chem. 2006, 1786-1795;
4. b) A. R. Kudinov, V. I. Meshcheryakov, P. V. Petrovskii, M. I. Rybinskaya, Izv. Akad. Nauk, Ser. Khim. 1999, 177-179;
5. Russ. Chem. Bull. 1999, 48, 176-177.
6. B. Štíbr, J. Holub, M. Bakardjiev, I. Pavlík, O. L. Tok, I. Císařova, B. Wrackmeyer, M. Herberhold, Chem. Eur. J. 2003, 2239-2244.
7. a) D. S. Perekalin, I. V. Glukhov, B. Štíbr, A. R. Kudinov, Inorg. Chim. Acta 2006, 359, 3264-3268;
8. b) J. Holub, B. Grüner, D. S. Perekalin, D. G. Golovanov, K. A. Lyssenko, P. V. Petrovskii, A. R. Kudinov, B. Štíbr, Inorg. Chem. 2005, 44, 1655-1659.
9. We use the numbering system in which the metal vertex bears number 1.
10. 11B NMR spectroscopy: E. V. Mutseneck, D. S. Perekalin, J. Holub, Z. A. Starikova, K. A. Lyssenko, P. V. Petrovskii, P. Zanello, M. Corsini, B. Štíbr, A. R. Kudinov, Organometallics 2006, 25, 2419-2426.
11. B. Štíbr, J. Holub, M. Bakardjiev, I. Pavlík, O. L. Tok, B. Wrackmeyer, Eur. J. Inorg. Chem. 2003, 2524-2528.
12. -1 calculated at the B3LYP/6-311+G**//B3LYP/6-31G* level: F. A. Kiani, M. Hofmann, Organometallics 2006, 25, 485-490.
13. Unfortunately, the X-ray structures of 5b and 6b were not solved because of severe disorder and libration even at 120 K.
14. J. M. Oliva, N. L. Allan, P. v. R. Schleyer, C. Viñas, F. Teixidor, J. Am. Chem. Soc. 2005, 127, 13538-13547.
15. A. Haaland, J. E. Nilsson, Acta Chem. Scand. 1968, 23, 2653-2656.
16. G. Laus, H. Schottenberger, K. Wurst, R. H. Herber, U. Griesser, J. Phys. Chem. B 2004, 108, 5082-5087.
17. R. H. Herber, in Chemical Mössbauer Spectroscopy (Ed.: R. H. Herber), Plenum Press, New York, 1984.
18. R. H. Herber, I. Nowik, V. Kahlenberg, H. Kopacka, H. Schottenberger, Eur. J. Inorg. Chem. 2006, 3255-3260, and references cited therein.
19. a) F. E. Mabbs, D. Collison, Electron Paramagnetic Resonance of d Transition Metal Compounds, in Studies in Inorganic Chemistry, Elsevier, New York, 1992, vol. 16;
20. b) J. R. Pilbrow, Transition Ion Electron Paramagnetic Resonance, Oxford Science Publications, Oxford, 1990;
21. c) R. S. Drago, Physical Methods for Chemists, Saunders College Publ., New York; 1992.
22. G. P. Lozos, B. M. Hoffman, C. G. Franz, Quantum Chemistry Program Exchange 1974, 11, 265.
23. B. Štíbr, J. Holub, M. Bakardjiev, D. Hnyk, O. L. Tok, W. Milius, B. Wrackmeyer, Eur. J. Inorg. Chem. 2002, 2320-2326.
24. P. Zanello, F. Laschi, M. Fontani, C. Mealli, A. Ienco, K. Tang, X. Jin, L. Li, J. Chem. Soc. Dalton Trans. 1999, 965-970.
25. SMART (V5.051) and SAINT (V5.00), Area detector control and integration software, Bruker AXS Inc., Madison, WI 53719, USA, 1998.
26. G. M. Sheldrick, SHELXTL-97 (V5.10), Bruker AXS Inc., Madison, WI 53719, USA, 1997.
27. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery Jr, R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian 98, revision A.7, Gaussian, Inc., Pittsburgh, PA, 1998.
28. U. Dörfler, D. L. Ormsby, R. Greatrex, J. D. Kennedy, Inorg. Chim. Acta 2000, 304, 268-273.