Molten carbonate fuel cell dynamical modeling

Journal of Fuel Cell Science and Technology

Volumn 4, Issue 3, 2007, Pages 283-293

  Bittanti, Sergio ^a   Canevese, Silvia ^a   De Marco, Antonio ^a   Giuffrida, Giorgio ^a   Errigo, Antonio ^b   Prandoni, Valter ^b  

^a POLITECNICO DI MILANO   (Italy)

^b CESI   (Italy)

Author keywords

Dynamical model; Electrochemistry; Engineering technology; Molten carbonate fuel cell; Partial differential equations; Simulation

Indexed keywords

ALGEBRA; COMPUTER SIMULATION; DYNAMIC MODELS; ELECTROCHEMISTRY; FLOW OF GASES; GAS DYNAMICS; PARTIAL DIFFERENTIAL EQUATIONS; THERMODYNAMICS;

FUEL CELL STACK; GAS CROSSFLOW;

MOLTEN CARBONATE FUEL CELLS (MCFC);

EID: 34748870132     PISSN: 1550624X     EISSN: None     Source Type: Journal    
DOI: 10.1115/1.2743074     Document Type: Article

References (41)

1. O'Shea, T.P., and J. Leo, A., 1994, "Santa Clara Demonstration Project 2-MW Carbonate Fuel Cell Power Plant," Proceedings of the 1994 29th Intersociety Energy Conversion Engineering Conference, Monterey, CA, 2, pp. 817-822.
2. Andrews, C. J., and Weiner, S. A., 2004, "Visions of a Hydrogen Future," IEEE Power & Energy Magazine, 2(2), pp. 26-34.
3. Kordesch, K., and Simader, G., 1996, Fuel Cells and Their Applications, VCH, Federal Republic of Germany.
4. Kowalenko, K., 2004, "Getting a Handle on Hydrogen, IEEE - The Institute, 28(3), pp. 14-18.
5. Gurney, J. H., 2004, "Building a Case for the Hydrogen Economy," IEEE Power & Energy Magazine, 2(2), pp. 35-39.
6. Ronchetti, M., and Iacobazzi, A., 2002, "CELLE A COMBUSTIBILE: Stato di Sviluppo e Prospettive delta Tecnologia," Grande Progetto Idrogeno e Celle a Combustibile, ENEA, Italy.
7. Bittanti, S., Canevese, S., De Marco, A., Errigo, A., and Prandoni, V., 2005, "MCFC Electrochemistry Modeling," Proceedings of the 7th International Molten Salt Symposium, Toulouse, France.
8. Ghezel-Ayagh, H., Daly, J. M., and Wang, Z.-H., 2003, "Advances in Direct Fuel Cell/Gas Turbine Power Plants," Proceedings FuelCell Energy, ASME, New York.
9. Scagliotti, M., 2003, "Celle a Combustibile e Impianti Ibridi," AEI, 90, pp. 32-37.
10. Scagliotti, M., Strobino, G., Araldi, P., and Savoldelli, P., 1999, "Sperimentazione di una Soluzione Innovativa per la Configurazione di Stack MCFC," Giornata di studio sulle Pile a Combustibile, AIM, Milan, Italy.
11. Lukas, M., Ghezel-Ayagh, H., and Lee, K. Y., 1999, "Development of a Stack Simulation Model for Control Study on Direct Reforming Molten Carbonate Fuel Cell Power Plant," IEEE Trans. Energy Convers., 14(4), pp. 1651-1657.
12. Lukas, M., Ghezel-Ayagh, H., and Lee, K. Y., 2000, "Modeling, Simulation and Control of Direct Reforming Molten Carbonate Fuel Cell Power Plant," Proceedings IFAC Symp. Power Plants and Power Systems Control, Bruxelles, pp. 127-132.
13. Lukas, M., and Ghezel-Ayagh, H., 2001, "An Explicit Dynamic Model for Direct Reforming Carbonate Fuel Cell Stack," IEEE Trans. Energy Convers., 16(3), pp. 289-295.
14. l4 Van Duijn, C. J., and Fehribach, J. D., 1993, "Analysis for a Molten Carbonate Fuel Cell," Electron. J. Differ. Equations, 1993(06), pp. 1-25.
15. He, W., 1994, "The Dynamic Performance of a Molten Carbonate Fuel Cell in Power-Generation System," J. Power Sources, 52, pp. 179-184.
16. He, W., 2000, "Dynamic Simulations of Molten Carbonate Fuel-Cell Systems," Ph.D. thesis, Delft University, The Netherlands.
17. He, W., and Chen, Q., 1998, "Three-Dimensional Simulation of a Molten Carbonate Fuel Cell Stack under Transient Conditions," J. Power Sources, 73, pp. 182-192.
18. Giner, J., and Hunter, C., 1969, "The Mechanism of Operation of the Teflon-Bounded Gas Diffusion Electrode: A Mathematical Model," J. Electrochem. Soc., 116, pp. 1124-1130.
19. Bennion, D. N., and Tobias, C. W., 1966, "Current Distribution at a Gas-Electrode-Electrolyte Interface (Parts I and II)," J. Electrochem. Soc., 113(6), pp. 589-599.
20. Yuh, C. Y., and Selman, J. R., 1984, "Polarization of the Molten Carbonate Fuel Cell Anode, and Cathode," J. Electrochem. Soc., 131, pp. 2062-2069.
21. Elam, M., Peled, E., and Gileadi, E., 1983, "Cyclic Voltametry in Solutions of Aluminum Bromide and kBr in Aromatics Hydrocarbons," J. Electrochem. Soc., 130, pp. 585-590.
22. Canevese, S., De Marco, A., Moretti, G., and Prandoni, V., 2004, "Un Modello di Pila a Combustibile a Carbonati Fusi," Automazione e Strumentazione, pp. 77-84.
23. Bittanti, S., Canevese, S., De Marco, A., Moretti, G., and Prandoni, V., 2005, "Molten Carbonate Fuel Cell Modelling," Proceedings 17th IFAC World Congress, Prague, Czech Republic.
24. Hamann, C. H., Hamnett, A., and Vielstich, W., 1998, Electrochemistry, Wiley-VCH, Berlin, Germany.
25. Goodridge, F., and Scott, K., Electrochemical Process Engineering, Wiley, New York.
26. Prandoni, V., and De Marco, A., 2003, "Modelli Matematici Dinamici delle Reazioni Elettrochimiche, Catalitiche e Trasferimenti di Massa in Celle a Combustibile," Milan, Italy, CESI Internal Report No. A3 /021830.
27. Errigo, A., 2004, "Modellistica delle Reazioni Elettrochimiche e del Trasporto Ionico in Celle a Combustibile," Master thesis, Politecnico di Milano, Milan, Italy.
28. Bittanti, S., Canevese, S., De Marco, A., Errigo, A., and Prandoni, V., 2005, "MCFC Electrochemistry Modelling," Proceedings 7th International Molten Salt Symposium, Toulouse, France.
29. Canevese, S., 2005, "Modelling and Control of Fuel Cells," Ph.D. thesis, Politecnico di Milano, Milan, Italy.
30. Moretti, G., 2003, "Molten Carbonate Fuel Cell: Modellistica e Simulazione," Master thesis, Politecnico di Milano, Milan, Italy.
31. Xu, J., and Froment, G. F., 1989, "Methane Steam Reforming, Methanation, and Water-Gas Shift: I. Intrinsic Kinetics," AIChE J., 35(1).
32. Dell'Oca, M., 1998-1999, "Ambiente di Simulazione e Modelli Matematici di Processi Termoidraulici," Master thesis, Politecnico di Milano, Milan, Italy.
33. Cattaneo, C., De Marco, A., and Bolzern, P., 2001, "Metodologia di Sviluppo di Modelli per la Simulazione di Processi Termoidraulici in Ambito MatLab Simulink," Politecnico di Milano, Milan, Italy, Internal Report No. 94.
34. Goodrige, F., Bard, A. J., and Faulkner, L. R., 1980, Electrochemical Methods, Wiley, New York.
35. Ang, P. G. P., and Sammels, A. F., 1980, "Influence of Electrolyte Composition Electrode Kinetics in the Molten Carbonate Fuel Cell," J. Electrochem. Soc., 127(6), pp. 1287-1293.
36. Will, F. G., and Ben Daniel, D. J., 1969, "Significance of Electrolyte Films for Performance of Porous Hydrogen Elecrodes," J. Electrochem. Soc., 119(7), pp. 933-937.
37. Burshtein, R. Chs., Markin, V. S., Pshenichnikov, A. G., Chismadgev, V. A., and Chirkov, Y. G., 1964, "Carbon Monoxide Electroxidation on Porous Pt-Ru Electrodes in Sulphuric Acid," Electrochim. Acta, 9, pp. 773-787.
38. Giuffrida, G., 2005, "Simulazione di Una Molten Carbonate Fuel Cell: Integrazione di un Modello Fluidodinamico Tridimensionale e di un Modello Elettrochimico," Master thesis, Politecnico di Milano, Milan, Italy.
39. Leva, A., and Maffezzoni, C., 2004, "Modelling of Power Plants, Thermal Power Plant Simulation and Control, D. Flynn, ed., Vol. 2, IEEE Power & Energy Series, IEEE, New York, pp. 17-60.
40. Eitelberg, E., 1983, "A Simple A2-Stable Numerical Method for State Space Models With Stiff Oscillations," Math. Comput. Simul., 25(4), pp. 346-355.
41. EG & G Services, Parsons Inc., 2000, Fuel Cell Handbook, 5th ed., U.S. Dept. of Energy, Office of Fossil Energy, National Energy Technology Laboratory, Morgantown, West Virginia, WV.