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34748867055
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A 57:43 mixture of the diastereomers, the configuration of which was not determined, was obtained
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A 57:43 mixture of the diastereomers, the configuration of which was not determined, was obtained.
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21
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84985594987
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[2+2] Cycloadditions of various cyclophiles to bicyclopropylidene have also been observed to proceed at ambient pressure via well-stabilized 1,4-zwitterionic intermediates: a W. Weber, I. Erden, A. de Meijere, Angew. Chem. 1980, 92, 387-388;
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[2+2] Cycloadditions of various cyclophiles to bicyclopropylidene have also been observed to proceed at ambient pressure via well-stabilized 1,4-zwitterionic intermediates: a) W. Weber, I. Erden, A. de Meijere, Angew. Chem. 1980, 92, 387-388;
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41949114965
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(1-Bromocyclopropyl)methanol was previously prepared by bromohydroxylation of methylenecyclopropane: R. Köster, S. Arora, P. Binger, Justus Liebigs Ann. Chem. 1973, 1219-1235.
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(1-Bromocyclopropyl)methanol was previously prepared by bromohydroxylation of methylenecyclopropane: R. Köster, S. Arora, P. Binger, Justus Liebigs Ann. Chem. 1973, 1219-1235.
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25
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33845183742
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Methyl 1-bromocyclopropanecarboxylate can easily be prepared on a large scale from inexpensive γ-butyrolactone in three simple steps: H. M. R. Hoffmann, K. Eggert, A. Walenta, D. Schomburg, R. Wartchow, F. H. Allen, J. Org. Chem. 1989, 54, 6096-6100.
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Methyl 1-bromocyclopropanecarboxylate can easily be prepared on a large scale from inexpensive γ-butyrolactone in three simple steps: H. M. R. Hoffmann, K. Eggert, A. Walenta, D. Schomburg, R. Wartchow, F. H. Allen, J. Org. Chem. 1989, 54, 6096-6100.
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