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For atomic states with a permanent quadrupole moment, the long-range part of the potential comes from the interaction of ion charge with the atom quadrupole moment.
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1D solutions 10 11 are valid at all distances for k→0 (E→ ω).
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c.m. and relative motions can be decoupled in the lowest order when the size of the molecule is much smaller than the harmonic oscillator lengths li and la.
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At least for the internal states with the total angular momentum J=1 2.
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