Preparation of substituted anilines from nitro compounds by using supported gold catalysts

Nature Protocols

Volumn 1, Issue 6, 2007, Pages 2590-2595

  Corma, Avelino ^a   Serna, Pedro ^a  

^a CSIC   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ANILINE DERIVATIVE; GOLD; NITROBENZENE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMISTRY; HYDROGENATION; SYNTHESIS;

ANILINE COMPOUNDS; CATALYSIS; GOLD; HYDROGENATION; NITROBENZENES;

EID: 34548829884     PISSN: 17542189     EISSN: 17502799     Source Type: Journal    
DOI: 10.1038/nprot.2006.441     Document Type: Article

References (13)

1. Bae, J.W., Cho, Y.J., Lee, S.H. & Toon, C.M. Chemoselective reduction of nitroaromatics to anilines using decaborane in methanol. Tetrahedron Lett., 41, 175-177 (2000).
2. Li, C.-H. et al. Nitrobenzene hydrogenation with carbon nanotube-supported platinum catalyst under mild conditions. J. Mol. Catal. A: Chem. 226, 101-105 (2005).
3. Gowda, S. & Gowda, D.C. Application of hydrazinium monoformate as new hydrogen donor with Raney nickel: A facile reduction of nitro and nitrile moieties. Tetrahedron 58, 2211-2213 (2002).
4. Toti, A. et al. Hydrogenation of single and multiple N-N or N-O bonds by Ru(II) catalysts in homogeneous phase. J. Organomet. Chem. 690, 3641-3651 (2005).
5. Kovar, R.F. & Arnold, F.E. Ethynyl-substituted aromatic ortho diamines and method of synthesis. U.S. Patent 3,975,444 to the U.S. Air Force. (1976).
6. Suchy, M., Winternitz, P. & Zeller, M. Herbicidal compositions comprising 3-aryluracyl derivative as active ingredient and process for producing for producing the active ingredient. WO Patent 91/00278 to Ciba-Geigy. (1991).
7. Butera, J. & Bagli, J. n-Heteroaralkyl-substituted 1-aryloxy-2-propanolamine and propylamine derivatives possessing class iii antiarrhythmic activity. WO Patent 91/09023 to American Home Products. (1991).
8. Burawoy, A. & Critchley, J.P. Electronic spectra of organic molecules and their interpretation V: Effect of terminal groups containing multiple bonds on the K-bands of conjugated systems. Tetrahedron 5, 340 (1959).
9. Braden, R., Knupfer, H. & Hartung, S. Process for the preparation of unsaturated amino compounds. U.S. Patent 4,002,673 to Bayer AG. (1977).
10. Braden, R., Knupfer, H. & Hartung, S. Process for the preparation of unsaturated amino compounds. U.S. Patent 4,051,177 to Bayer AG. (1977).
11. Narendra, M.A., Shivanand, O.P. & Madhukar, D.R. Selective hydrogenation of nitrogen containing aromatics WO Patent 2005.070.869 to Council Scient. Ind. Res. (2005).
12. Blaser, H.U., Siegrist, U., Steiner, H. & Studer, M. Aromatic Nitro Compounds. Fine Chemicals Through Heterogeneous Catalysis (eds. Sheldon, R.A., van Bekkum, H.) 389-406 (Wiley-VCH, Weinheim, Germany, 2001).
13. Corma, A. & Serna, P. Chemoselective hydrogenation of nitro compounds with supported gold catalysts. Science 313, 332 (2006).