Reductive dechlorination of tetrachloroethylene and trichloroethylene by mackinawite (FeS) in the presence of metals: Reaction rates

Environmental Science and Technology

Volumn 41, Issue 18, 2007, Pages 6390-6396

  Jeong, Hoon Y ^a   Hayes, Kim F ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION (PROCESS); DECHLORINATION; IRON COMPOUNDS; MECHANICAL PERMEABILITY;

METAL SULFIDES; TRANSFORMATION PATHWAY;

ETHYLENE;

COBALT; COBALT SULFATE; IRON; MERCURY; METAL OXIDE; NICKEL; SULFIDE; TETRACHLOROETHYLENE; TRICHLOROETHYLENE;

CONCENTRATION (PROCESS); DECHLORINATION; ETHYLENE; IRON COMPOUNDS; MECHANICAL PERMEABILITY;

ANOXIC CONDITIONS; DECHLORINATION; IRON SULFIDE; REACTION RATE; REDUCTION; TETRACHLOROETHYLENE;

ARTICLE; CHEMICAL REACTION; DECHLORINATION; KINETICS; POLLUTANT; WASTE MANAGEMENT;

FERROUS COMPOUNDS; HYDROCARBONS, CHLORINATED; KINETICS; METALS; OXIDATION-REDUCTION; TETRACHLOROETHYLENE; TRICHLOROETHYLENE;

EID: 34548779089     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es0706394     Document Type: Article

References (51)

1. Westrick, J. J.; Mello, J. W.; Thomas, R. F. The groundwater supply survey. Am. Water Works Assoc. J. 1984, 76, 52-59.
2. U.S. Environmental Protection Agency. Common Chemicals Found at Superfund Sites; EPA 540/R-94/044; Office of Emergency and Remedial Response: Washington D. C., 1994.
3. Butler, E. C.; Hayes, K. F. Kinetics of the transformation of trichloroethylene and tetrachloroethylene by iron sulfide. Environ. Sci. Technol. 1999, 33, 2021-2027.
4. Butler, E. C.; Hayes, K. F. Factors influencing rates and products in the transformation of trichloroethylene by iron sulfide and iron metal. Environ. Sci. Technol. 2001, 35, 3884-3891.
5. Goldhaber, M. B.; Kaplan, I. R. The sulfur cycle. In the Sea; Goldberg, E. D., Ed.; Wiley-Interscience: New York, 1974; pp 569-655.
6. Rickard, D. T. The chemistry of iron sulphide formation at low temperatures. Stockholm Contr. Geol. 1969, 26, 67-95.
7. Berner, R. A. Iron sulfides formed from aqueous solution at low temperatures and atmospheric pressures. J. Geol. 1964, 72, 293-306.
8. Rickard, D. T. Kinetics and mechanism of the sulfidization of goethite. Am. J. Sci. 1974, 274, 941-952.
9. Roh, Y.; Lee, S. Y.; Elless, M. P. Characterization of corrosion products in the permeable reactive barriers. Environ. Geol. 2000, 40, 184-194.
10. Furukawa, Y.; Kim, J.-W.; Watkins, J.; Wilkin, R. T. Formation of ferrihydrite and associated iron corrosion products in permeable reactive barriers of zero-valent iron. Environ. Sci. Technol. 2002, 36, 5469-5475.
11. Riley, R. G.; Zachara, J. M.; Wobber, F. J. Chemical Contaminants on DOE Lands and Selection of Contaminant Mixtures for Subsurface Science Research; DOE/ER-0547T; U.S. Department of Energy: Washington D. C., 1992.
12. II on the reductive dechlorination of carbon tetrachloride by green rust. Environ. Sci. Technol. 2003, 37, 2905-2912.
13. Maithreepala, R. A.; Doong, R.-A. Enhanced dechlorination of chlorinated methanes and ethenes by chloride green rust in the presence of copper(II). Environ. Sci. Technol. 2005, 39, 4082-4090.
14. Dries, J.; Bastiaens, L.; Springael, D.; Agathos, S.; Diels, L. Combined removal of chlorinated ethenes and heavy metals by zerovalent iron in batch and continuous flow column systems. Environ. Sci. Technol. 2005, 39, 8460-8465.
15. Jeong, H. Y.; Hayes, K. F. Impact of transition metals on reductive dechlorination rate of hexachloroethane by mackinawite. Environ. Sci. Technol. 2003, 37, 4650-4655.
16. Jeong, H. Y. Removal of Heavy Metals and Reductive Dechlorination of Chlorinated Organic Pollutants by Nanosized FeS, Ph.D. Dissertation, University of Michigan, Ann Arbor, MI, 2005.
17. Butler, E. C. Transformation of Halogenated Organic Compounds by Iron Sulfide, Ph.D. Dissertation, University of Michigan, Ann Arbor, MI, 1998.
18. Danielsen, K. M.; Gland, J. L.; Hayes, K. F. Influence of amine buffers on carbon tetrachloride reductive dechlorination by the iron oxide magnetite. Environ. Sci. Technol. 2005, 39, 756-763.
19. Arnold, W. A.; Roberts, A. L. Pathways and kinetics of chlorinated ethylene and chlorinated acetylene reaction with Fe(0) particles. Environ. Sci. Technol. 2000, 34, 1794-1805.
20. Nirmalakhandan, N. N.; Speece, R. E. QSAR model for predicting Henry's constant. Environ. Sci. Technol. 1988, 22, 1349-1357.
21. Pearson, R. G. Hard and soft acids and bases. J. Am. Chem. Soc. 1963, 85, 3533-3539.
22. Lowry, G. V.; Reinhard, M. Hydrodehalogenation of 1- to 3-carbon halogenated organic compounds in water using a palladium catalyst and hydrogen gas. Environ. Sci. Technol. 1999, 33, 1905-1910.
23. Lee, W.; Batchelor, B. Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 1. Pyrite and magnetite. Environ. Sci. Technol. 2002, 36, 5147-5154.
24. Arnold, W. A.; Roberts, A. L. Pathways of chlorinated ethylene and chlorinated acetylene reaction with Zn(0). Environ. Sci. Technol. 1998, 32, 3017-3025.
25. Lee, W.; Batchelor, B. Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 2. Green rust. Environ. Sci. Technol. 2002, 36, 5348-5354.
26. Perlinger, J. A.; Angst, W.; Schwarzenbach, R. P. Kinetics of the reduction of hexachloroethane by juglone in solutions containing hydrogen sulfide. Environ. Sci. Technol. 1996, 30, 3408-3417.
27. Kriegman-King, M. R.; Reinhard, M. Transformation of carbon tetrachloride in the presence of sulfide, biotite, and vermiculite. Environ. Sci. Technol. 1992, 26, 2198-2206.
28. Roberts, A. L.; Sanborn, P. N.; Gschwend, P. M. Nucleophilic substitution reactions of dihalomethanes with hydrogen sulfide species. Environ. Sci. Technol. 1992, 26, 2263-2274.
29. Pecher, K.; Haderlein, S. B.; Schwarzenbach, R. P. Reduction of polyhalogenated methanes by surface-bound Fe(II) in aqueous suspensions of iron oxides. Environ. Sci. Technol. 2002, 36, 1734-1741.
30. Satapanajaru, T.; Shea, P. J.; Comfort, S. D.; Roh, Y. Green rust and iron oxide formation influences metolachlor dechlorination during zerovalent iron treatment. Environ. Sci. Technol. 2003, 37, 5219-5227.
31. Schwertmann, U.; Taylor, R. M. Iron oxides. In Minerals in Soil Environments; Soil Science Society of America: Madison, WI, 1977; pp 145-181.
32. Dotson, R. L. Characterization and studies of some four, five, and six coordinate transition and representative metal complexes of tris-(hydroxymethyl) -aminomethane. J. Inorg. Nucl. Chem. 1972, 34, 3131-3138.
33. Hwang, I.; Batchelor, B. Reductive dechlorination of tetrachloroethylene by Fe(II) in cement slurries. Environ. Sci. Technol. 2000, 34, 5017-5022.
34. Gantzer, C. J.; Wackett, L. P. Reductive dechlorination catalyzed by bacterial transition-metal coenzymes. Environ. Sci. Technol. 1991, 25, 715-722.
35. Glod, G.; Angst, W.; Holliger, C.; Schwarzenbach, R. P. Corrinoid-mediated reduction of tetrachloroethene, trichloroethene, and trichlorofluoroethene in homogeneous aqueous solution: Reaction kinetics and reaction mechanisms. Environ. Sci. Technol. 1997, 31, 253-260.
36. Morel, F. M. M.; Hering, J. G. Principles and Applications of Aquatic Chemistry, Wiley-Interscience: New York, 1993.
37. O'Loughlin, E. J.; Burris, D. R.; Delcomyn, C. A. Reductive dechlorination of trichloroethene mediated by humic-metal complexes. Environ. Sci. Technol. 1999, 33, 1145-1147.
38. Ma, H.; O'Loughlin, E. J.; Burris, D. R. Factors affecting humic-nickel complex mediated reduction of trichloroethene in homogeneous aqueous solution. Environ. Sci. Technol. 2001, 35, 717-724.
39. Scherer, M. M.; Balko, B. A.; Gallagher, D. A.; Tratnyek, P. G. Correlation analysis of rate constants for dechlorination by zero-valent iron. Environ. Sci. Technol. 1998, 32, 3026-3033.
40. Zallen, R.; Slade, M. Plasma edge and band structure of cubic HgS. Solid State Commun. 1970, 8, 1291-1294.
41. Amonette, J. E.; Workman, D. J.; Kennedy, D. W.; Fruchter, J. S.; Gorby, Y. A. Dechlorination of carbon tetrachloride by Fe(II) associated with goethite. Environ. Sci. Technol. 2000, 34, 4606-4613.
42. Taylor, L. A.; Finger, L. W. Structural refinement and composition of mackinawite. Carnegie Inst. Washington Geophys. Lab. Annu. Rep. 1970, 69, 318-322.
43. Vaughan, D. J.; Ridout, M. S. Mössbauer studies of some sulphide minerals. J. Inorg. Nucl. Chem. 1971, 33, 741-746.
44. Bebie, J.; Schoonen, M. A. A.; Fuhrmann, M.; Strongin, D. R. Surface charge development on transition metal sulfides: An electrokinetic study. Geochim. Cosmochim. Acta 1998, 62, 633-642.
45. Dzombak, D. A.; Morel, F. M. M. Surface Complexation Modeling, Hydrous Ferric Oxide; John Wiley and Sons: New York, 1990.
46. Schecher, W. D.; McAvoy, D. C. MINEQL+ 4.5; Environmental Research Software: Hallowell, ME, 2001.
47. Widler, A. M.; Seward, T. M. The adsorption of gold(I) hydrosulphide complexes by iron sulphide surfaces. Geochim. Cosmochim. Acta 2002, 66, 383-402.
48. Mullet, M.; Boursiquot, S.; Ehrhardt, J.-J. Removal of hexavalent chromium from solutions by mackinawite, tetragonal FeS. Colloids Surf. A 2004, 244, 77-85.
49. Sokhn, J.; De Leij, F. A. A. M.; Hart, T. D.; Lynch, J. M. Effect of copper on the degradation of phenanthrene by soil microorganisms. Lett. Appl. Microbiol. 2001, 33, 164-168.
50. Phillips, D. H.; Gu, B.; Watson, D. B.; Roh, Y.; Liang, L.; Lee, S. Y. Performance evaluation of a zerovalent iron reactive barrier: mineralogical characteristics. Environ. Sci. Technol. 2000, 34, 4169-4176.
51. Liang, L.; Moline, G. R.; Kamolpomwijit, W.; West, O. R. Influence of hydrogeochemical processes on zero-valent iron reactive barrier performance: A field investigation. J. Contam. Hydrol. 2005, 78, 291-312.