Low-pressure dependency of the isotopic enrichment in ozone: Stratospheric implications

Journal of Geophysical Research: Atmospheres

Volumn 107, Issue D23, 2002, Pages

  Bhattacharya, S K ^a   Chakraborty, Subrata ^a   Savarino, Joel ^b,c   Thiemens, Mark H ^b  

^a PHYSICAL RESEARCH LABORATORY   (India)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c UNIV GRENOBLE ALPES   (France)

Author keywords

Mass independent fractionation; Ozone dissociation; Stratospheric isotope profile; Stratospheric ozone; Turnover time

Indexed keywords

EID: 34548629185     PISSN: 2169897X     EISSN: 21698996     Source Type: Journal    
DOI: 10.1029/2002JD002508     Document Type: Article

References (28)

1. Abbas, M. M., J. Guo, B. Carli, F. Mencaraglia, M. Carlotti, and I. G. Nolt, Heavy ozone distributionin the stratosphere from far-infrared observations, J. Geophys. Res., 92, 13,231-13,239, 1987.
2. Anderson, S. M., K. Mauersberger, and J. Morton, Progress and Problems in Atmospheric Chemistry, edited by J. Baker, World Sci., River Edge, N. J., 1995.
3. Banks, P. M., and G. Kockarts, Aeromony, Part A, Academic, San Diego, 1973.
4. Bhattacharya, S. K., and M. H. Thiemens, Isotopic fractionation in ozone decomposition, Geophys. Res. Lett., 15, 9 -12, 1988.
5. Chakraborty, S., and S. K. Bhattacharya, Oxygen isotope anomaly in surface induced ozone dissociation, Chem. Phys. Lett., in press, 2002a.
6. Chakraborty, S., and S. K. Bhattacharya, Oxygen isotopic fractionation during UV and visible light photo-dissociation of ozone, J. Chem. Phys., in press, 2002b.
7. DeMore, W. P., S. P. Sander, C. J. Howard, A. R. Ravisankara, D. M. Golden, C. E. Kolb, R. F. Hampson, M. J. Kurylo, and M. J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, JPL Publ., 97-104, 266 pp., 1997.
8. Gao, Y. Q., and R. A. Marcus, Strange and unconventional isotope effects in ozone formation, Science, 293, 259-263, 2001.
9. Gao, Y. Q., and R. A. Marcus, On the theory of the strange and unconventional isotopic effects in ozone formation, J. Chem. Phys., 116, 137-154, 2002.
10. Goldman, A., F. J. Murcray, D. G. Murcray, J. J. Kosters, C. P. Rinsland, J. M. Flaud, C. Camy-Peyret, and A. Barbe, Isotopic abundances of stratospheric ozone from balloon-borne high resolution infrared solar spectra, J. Geophys. Res., 94, 8467-8473, 1989.
11. Hathorn, B. C., and R. A. Marcus, An intramolecular theory of the massindependent isotope effect for ozone, I, J. Chem. Phys., 111, 4087-4100, 1999.
12. Hathorn, B. C., and R. A. Marcus, Estimation of vibrational frequencies and vibrational densities of states in isotopically substituted nonlinear triatomic molecules, J. Phys. Chem, 111, 5586-5589, 2002.
13. Irion, F. W., M. R. Gunson, C. P. Rinsland, Y. L. Yung, M. C. Abrams, A. Y. Chang, and A. Goldman, Heavy ozone enrichments from ATMOS infrared solar spectra, Geophys. Res. Lett., 23, 2377-2380, 1996.
14. Kim, S., and J. Yang, Temperature and pressure dependences on the isotopic fractionation effect in the thermal decomposition of ozone, J. Astron. Space Sci., 14, 297-312, 1997.
15. Krankowsky, D., P. Lämmerzahl, and K. Mauersberger, Isotopic measurements of stratospheric ozone, Geophys. Res. Lett., 27, 2593-2595, 2000.
16. Matsumi, Y., F. J. Comes, G. Hancock, A. Hofzumahaus, A. J. Hynes, M. Kawasaki, and A. R. Ravishankara, Quantum yields for production of O(1D) in the ultraviolet photolysis of ozone: Recommendation based on evaluation of laboratory data, J. Geophys. Res., 107(D3), 4024, doi: 10.1029/2001JD000510, 2002.
17. Mauersberger, K., Measurement of heavy ozone in the stratosphere, Geophys. Res. Lett., 8, 935-937, 1981.
18. Mauersberger, K., Ozone measurements in the stratosphere, Geophys. Res. Lett., 14, 80-83, 1987.
19. Mauersberger, K., P. Lammerzahl, and D. Krankowsky, Stratospheric ozone isotope enrichments: Revisited, Geophys. Res. Lett., 28(16), 3155-3158, 2001.
20. Meier, A., and J. Notholt, Determination of the isotopic abundances of heavy O3 as observed in arctic ground based FTIR spectra, Geophys. Res. Lett., 23, 551-554, 1996.
21. Miller, C. E., and Y. L. Yung, Photo-induced isotopic fractionation, J. Geophys. Res., 105, 29,039- 29,051, 2000.
22. Morton, J., J. Barnes, B. Schueler, and K. Mauersberger, Laboratory studies of heavy ozone, J. Geophys. Res., 95, 901-907, 1990.
23. Rinsland, C. P., V. M. Devi, J. M. Flaud, C. Camy-Peyret, M. A. Smith, and G. M. Stokes, Identification of 18O-isotope lines of ozone in infrared ground based solar absorption spectra, J. Geophys. Res., 90, 10,719- 10,725, 1985.
24. Schueler, B., J. Morton, and K. Mauersberger, Measurement of isotopic abundances in collected stratospheric ozone samples, Geophys. Res. Lett., 17, 1295-1298, 1990.
25. Thiemens, M. H., and J. E. Heidenreich III, The mass-independent fractionation of oxygen: A novel isotope effect and its possible cosmochemical implications, Science, 219, 1073-1075, 1983.
26. Thiemens, M. H., and T. Jackson, Production of isotopically heavy ozone by ultraviolet light photolysis of O2, Geophys. Res. Lett., 14, 624-627, 1987.
27. Thiemens, M. H., and T. Jackson, New experimental evidence for the mechanism for production of isotopically heavy O3, Geophys. Res. Lett., 15, 639-642, 1988.
28. Wen, J., and M. H. Thiemens, Experimental and theoretical study of isotope effects on ozone decomposition, J. Geophys. Res., 96, 10,911 - 10,921, 1991.