Epoxy and polyurethane networks in thin films on metals - Formation, structure, properties

Soft Materials

Volumn 5, Issue 2-3, 2007, Pages 87-134

  Wehlack, Carsten ^a   Possart, Wulff ^a   Krger, Jan K ^b   Mller, Ullrich ^b  

^a SAARLAND UNIVERSITY   (Germany)

^b UNIVERSITY OF LUXEMBOURG   (Luxembourg)

Author keywords

Amine cured epoxy; Chemical structure; IR spectroscopy; Morphology; Polymer metal interphase; Polyurethane; Thin films

Indexed keywords

COMPLEXATION; EPOXY RESINS; POLYMER FILMS; POLYURETHANES; SURFACE CHEMISTRY; THIN FILMS;

AMINE-CURED EPOXY; POLYADDITION; POLYMER-METAL COMPOUNDS; POLYMER-METAL INTERPHASES;

STRUCTURE (COMPOSITION);

EID: 34548606207     PISSN: 1539445X     EISSN: 15394468     Source Type: Journal    
DOI: 10.1080/15394450701554536     Document Type: Article

References (67)

1. Barthés-Labrousse, M.-G. (1996) Adhesion mechanisms at amine-cured epoxy/aluminium interfaces. Journal, of Adhesion, 57 (1-4): 1-4, 65-75.
2. Bischof, C. and Possart, W. (1982) Adhäsion-Theoretische und experimentelle Grundlagen; AkademieVerlag: Berlin.
3. Dieckhoff, S., Brockmann, W., Faupel, F., Possart, W., and Krüger, J.K. (2004) Adhäsions-und Alterungsmechanismen in Polymer-Metaull- Übergängen; Report BMBF-Project No. 03D0074, TIB Hannover: Germany.
4. Gaillard, F., Romand, M., Verchere, D., and Hoquaux, H. (1994) Zinc coated steel/epoxy adhesive systems: investigation of the interfacial zone by FTIR spectroscopy. Journal of Adhesion, 46 (1-4): 227-241.
5. Kraus, R., Wilke, W., Zhuk, A., Luzinow, I., Minko, S., and Voronow, V. (1997) Investigation of debonding processes in particle-filled polymer materials by acoustic emission: Part I acoustic emission and debonding stress. Journal of Materials Science, 32 (16); 4397-4403.
6. Lotfipour, M., Reeves, L.A., Kiroski, D., and Packham, D.E. (1994) The interphase in rubbermetal moulding: The influence on adhesion of sulphur-containing emulsifier residues in nitrile rubber. Journal of'Adhesion, 47: 33-40.
7. Marsh, J., Minel, L., Barthés-Labrousse, MV-G., and Gorse, D. (1996) The nature of the surface acidity of anodised titanium: an XPS study using 1,2-diaminoethane. Applied Surface Science, 99 (4): 335-343.
8. Marsh, J., Minel, L., Barthés-Labrousse, M.-G., and Gorse, D. (1998) Interaction of epoxy model molecules with Al, anodized Al and Cu: An XPS study. Applied, Surface Science, 133 (4): 270-286.
9. Sharpe, L.H. (1972) The interphase in adhesion. Journal of Adhesion, 4: 51-64.
10. Bentadjine, S., Petiaud, R., Roche, A.A., and Massardier, V. (2001) Organo-metallic complex characterization formed when liquid epoxy-diamine mixtures are applied onto metallic substrates. Polymer, 42 (14): 6271-6282.
11. Bouchet, J., Roche, A.A., and Jaquelin, E. (2001) Determination of residual stresses in coated metallic substrates. Journal of Adhesion Science and Technology, 15 (3): 321-344.
12. Bouchet, J., Roche, A.A., Jacquelin, E., and Scherer, G. W. (2001) Adhesion Aspects of Thin Films; Mlttal, K.L. (ed.); Brill Academic Publishers: Leiden, Netherlands, Vol. I.
13. Bouchet, J. and Roche, A.A. (2002) The formation of epoxy/metal interphases: Mechanisms and their role in practical adhesion. Journal of Adhesion, 78 (9): 799-830.
14. Müder, E., Mai, K., and Pisanova, E. (2000) Interphase characterization in polymer composites-monitoring of interphasial behavior in dependence on the mode of loading. Composite Interfaces, 7(3): 133-147.
15. Possart, W. and Schlett, V. (1995) XPS of the Interphase between PMMA and metals. A study of degradation and interaction. Journal of Adhesion, 48: 25-46.
16. Possart, W., Dieckhoff, S., Fanter, D., Gesang, T., Hartwig, A., Höper, R., Schlett, V., and Hennemann, O.-D. (1996) Studies on the interphase of a model adhesive joint. Joumal of Adhesion, 57: 227-244.
17. Possart, W. and Krüger, J.K. (2002) Proceedings of the 6th European Adhesion Conference EURADH 2002 and the 8th International Conference on the Science & Technology of Adhesionand Adhesives ADHESION '02, Glasgow, Great Britain, September 10-13, 2002: The Institute of Materials UK, IOM Communications, 7-8.
18. Roche, A.A., Bouchet, J., and Bentadjine, S. (2002) Formation of epoxy-diamine/metal interphases. International Journal of Adhesion, & Adhesives, 22 (6): 431-441.
19. Possart, W., Krüger, J.K., Dieckhoff, S., Britz, T., Neurohr, IL, Valeske, B., Wehlack, C., and Wilken, R. (2002) Adhäsion und, Vernetzung eines Modell-Epoxids auf oxidierlen Aluminium-und Magnesiumoberfiä clien; Report DFG-Project No. Po 577/3-1, Kr 653/9-1, Di 792/1-1, Saarbrücken, Germany.
20. Wehlack, C. and Possart, W. (2004) Polymer Spectroscopy; Gregoriou, V.G. (ed.); Wiley-VCH: Weinheim, Germany, Vol. 205, 251-261.
21. Kanzow, J., Faupel, F., Egger, W., Sperr, P., Kögel, G., Wehlack, C., Meiser, A., and Possart, W. (2004) Behaviorln Proceedings of the 7th European Adhesion Conference EURADH 2004, Freiburg im Breisgau, Germany, September 5-9: 194-200.
22. Wehlack, C. and Possart, W. (2004) Proceedings of the 7th European Adhesion Conference EURADH 2004, Freiburg im Breisgau, Germany, September 5-9; 49-54.
23. Wehlack, C., Schneider, B., Ott, M., and Possart, W. (2004) In Proceedings of the 7th European Adhesion Conference EURADH 2004, Freiburg im Breisgau, Germany, September 5-9; 405-410.
24. Wehlack, C., Krämer, R., and Possart, W. (2004) In Proceedings of the 7th European Adhesion Conference EURADH 2004, Freiburg im Breisgau, Germany, September 5-9; 411-416.
25. Wehlack, C. and Possart, W. (2005) In Adhesion-Current Research and Applications; Possart, W. (ed.); Wiley-VCH: Weinheim, 71 -88, Chapter 6.
26. Ellis, B. (ed.) (1993) Chemistry and Technology of Epoxy Resins; Chapman & Hall: London, Chapter 3.
27. Jahn, H. (1969) Epoxidharze; VEB Deutscher Verlag für Grundstoffindustrie: Leipzig, 45-50.
28. Lee, H.L. and Neville, K. (1967) Handbook of Epoxy Resins; McGraw-Hill: New York/Chapter 5.
29. Pascault, J.-P., Sautereau, IL, Verdu,. J., and Williams, R.J.J. (2002) Thermosetting Polymers; Marcel Decker, Inc.: New York, Basel, 146-151.
30. Affrossman, S., Brown, N.M.D., Pethrick, RA, Sharma, V.K., and Turner, R.J. (1983) Inelastic electron tunneling spectroscopic studies of adsorption of a simulated epoxy resin. Applications of Surface Science, 16: 469-473.
31. Affrossman, S. and MacDonald, S.M. (1994) The adsorption of a model epoxy-resin, N-propyl-2-hydroxybutylamine, on aluminium surface studied by static secondary ion mass-spectroscopy. Langmuir, 10 (7): 2257-2261.
32. Boerio, F.J. and Chen, S.L (1979) Reflection-absorption infrared spectroscopy and ellipsometry of epoxy films on metals. Applied Spectroscopy, 33 (2): 121-126.
33. Bolouri, H., Pethrick, R.A., and Affrossman, S. (1983) Bonding of a simulated epoxy resin to aluminium surfaces studied by XPS. Applications of Surface Science, 17: 231-240.
34. Brown, N.M.D., Turner, R.J., Affrossman, S., Dunkln, I.R., Pethrick, R.A., and Shields, C.J. (1985) Adsorption of a simulated epoxy resin fragment: IETS and matrix ssolation IVR. study of an adduct of N-propylamine and 1,2-epoxy butane. Spectrochimka Acta B, 40 B (5/6); 847-851.
35. Fauquet, C., Dubot, P., Minel, L., Barthés-Labrousse, M.-G., Rei Vilar, M., and Villatte, M. (1994) Adsorption of monoethanolamine on clean, oxidized and hydroxylated aluminium surfaces: A model for amine-cured epoxy/aluminium interfaces. Applied Surface Science, 81: 435-441.
36. Fondeur, F. and Koenig, J.L. (1993) Microscopic FF-IR studies of epoxy adhesive films on chemically treated aluminum. Applied Spectroscopy, 47 (1): 1-6.
37. Kempfer, G., Kasper, F., Kreysig, D., Uhlemann, E., and Welsch, F. (1976) Chemie für Lehrer, Band 9: Synthetische Hochpolymere; VEB Deutscher Verlag der Wissenschaften: Berlin.
38. Farkas, A. and Mills, G.A. (1962) Catalytic effects in isocyanate reactions. Advanced Catalysis, 13: 393-446.
39. Thomas, P. (ed.) (1998) Waterborne & Solvent Based Surface Coating Resins and their Applications; John Wiley & Sons: Chichester: New York.
40. Evans, S.D. and Houghton, R.P. (2000) On. the mechanism of the copper(II) catalysis of the formation of urethanes from alcohols and isocyanates. Journal of Molecular Catalysis A: Chemical, 164(1-2), 157-164.
41. 2 in the formation of urethane from a diisocyanate derivative and EtOH. Journal of Molecular Catalysis A: Chemical, 130 (1-2): 101-105.
42. Lipatova, T.E. and Nizel'skii, Y.N. (1970) Mechanism of urethane formation through, catalyst complex with Rfactants. Doklady Akademii Nauk Sssr, 190 (4): 880-883.
43. Lipatova, T.E. and Nizel'skii, Y.N. (1972) Mechanism of catalysis by copper chelates of urethane formation. Zhurnal Fizicheskoi Khimii, 46 (9): 2294-2297.
44. Nizelsky, Y.N., Ishchenko, S.S., and Lipatova, T.E. (1973) Study of catalytic activity of Cu(II) coordination compounds in reaction of urethane formation. Dopovidi Akademii Nauk Ukrainskoi Rsr, Seriya B, 35: 431 -435.
45. Lipatova, T.E. and Nizel'skii, Y.N. (1981) Coordination catalysis in reactions of polyaddition. Advances in Urethane Science and Technology, 8: 217-243.
46. Thome, N.A., Thuéry, P., Frichet, A., Giminez, P., and Sartre, A. (1990) Hydration of oxide films on aluminium and its relation to polymer adhesion. Surface and Interface Analysis, 16 (1-2): 236-240.
47. Dillingham, R.G. and Moriarty, C.J. (2002) In Proceedings of the 25th Annual Meeting of the Adhesion Society and the 2nd World Congress on Adhesion and Related phenomena (WCARP-II); Orlando Florida, USA, February 10-14; Pocius, A.V. and Dillards, J.G. (eds.); The Adhesion Society: Orlando, 2002, 316-319.
48. Dillingham, R.G. and Moriarty, C.J. (2003) The adhesion of isocyanate-based polymers to steel. Journal of Adhesion, 79: 269-285.
49. Milosevic, M. and Berets, S.L. (1993) Applications of the theory of optical spectroscopy to numerical simulations. Applied, Spectroscopy, 47 (5): 566-574.
50. Stenzel, O. (1996) Das Dünnschichtspektrum; 1. Aufl.; Akademie Verlag: Berlin.
51. Theiss, W. (2002) Analysis of Optical Spectra by Computer Simulation-front Basks to Batch Mode; M. Theiss Hard- und Software for Optical Spectroscopy: Aachen, Germany.
52. Theiss, M.W. (2004) SCOUT 2-Spektrum Interpretation by Simulation, V2.22; Hard- and Software for Optical Spectroscopy: Dr.-Bernhard-Klein-Str. 110, D-52078; Aachen, Germany.
53. Possart, W., Krüger, J.K., Wehlack, C., Müller, U., Petersen, C., Bactavachalou, R., and Meiser, A. (2006) Formation and Structure of Epoxy Network Interphases at the Contact to Native Metal Surfaces. Comptes Rendus Chimie, 9 (1): 60-79.
54. Wehlack, C., Valeske, B., Schneider, B., and Possart, W. (2002) Proceedings of the 7th International Conference on Adhesion and Surface Analysis, England, March 26-27; Loughborough University.
55. Schneider, B. (2001) PhD Dissertation, Saarland University: Saarbrücken: Germany.
56. Schneider, B., Hennemann, O.-D., and Possart, W. (2002) The adhesion of maleic anhydride on native aluminium oxide; An approach, by infrared spectroscopy and quantum-mechanical modeling. Journal of Adhesion, 78: 779-797.
57. Fata, D. (2005) PhD Dissertation, Saarland University: Saarbrücken, Germany.
58. Pascault, J.-P., Sautereau, H., Verdu, J., and Williams, R.J.J. (2002) In Thermosetting Polymers; Pascault, J.-P., Sautereau, H., Verdu, J. and Williams, R.J.J. (eds.); Marcel Decker, Inc.: New York, Basel, 206-225, Chapter 7.
59. Harrod, J.F. (1962) Reactions of primary amines with epoxides. Journal, of Applied Polymer Science, 6 (24): S63-S64.
60. Shechter, L., Wynstra, J., and Kurkjy, R.P. (1956) Glycidyl ether reactions with amines. Industrial and Engineering Chemistry, 48 (1): 94-97.
61. Riccardi, C.C., Adabbo, H.E., Williams, R.J.J., and Curing (1984) Reactions of epoxy resins with diamines. Journal of Applied Polymer Science, 29: 2481-2491.
62. Bockenheimer, C. (1998) Diploma Thesis; Saarland University: Saarbrücken, Germany.
63. Bockenheimer, C., Fata, D., and Possart, W. (2004) New aspects of aging in epoxy networks. I. Thermal aging. Journal of Applied Polymer Science, 91 (1): 361-368.
64. Bockenheimer, C., Fata, D., and Possart, W. (2004) New aspects of aging in epoxy networks. II. Hydrothermal aging. Journal of Applied Polymer Science, 91 (1): 369-377.
65. Meiser, A. (2003) Diploma Thesis; Saarland University: Saarbrücken, Germany.
66. Meiser, A., Wehlack, C., and Possart, W. (2005) Adhesion - Current Research and Applications; Possart, W. (ed.); Wiley-VCH: Weinheim: Germany, 445-463, Chapter 28.
67. Lin-Vien, D., Colthup, N.B., Fateley, W.G., and Grasselli, J.G. (eds.) (1991) The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules; Academic Press; Boston.