Addition of alkenes to deltahedral zintl clusters by reaction with alkynes: Synthesis and structure of [Fc-CH=CH-Ge9-CH=CH-Fc]2-, an organo-zintl-organometallic anion

Angewandte Chemie - International Edition

Volumn 46, Issue 35, 2007, Pages 6695-6698

  Hull, Michael W ^a   Sevov, Slavi C ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

Alkenes; Cluster compounds; Germanium; Metallocenes; Zintl anions

Indexed keywords

CHEMICAL BONDS; GERMANIUM; NEGATIVE IONS; ORGANOMETALLICS; REACTION KINETICS; SYNTHESIS (CHEMICAL);

CLUSTER COMPOUNDS; ETHYLENEDIAMINE SOLUTION YIELDS; ZINTL ANIONS;

OLEFINS;

EID: 34548601966     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200701950     Document Type: Article

References (18)

1. For a recent review, see: S. C. Sevov, J. M. Goicoechea, Organometallics 2006, 25, 5678.
2. M. W. Hull, A. Ugrinov, I. Petrov, S. C. Sevov, Inorg. Chem. 2007, 46, 2704.
3. A. Ugrinov, S. C. Sevov, J. Am. Chem. Soc. 2002, 124, 2442.
4. A. Ugrinov, S. C. Sevov, J. Am. Chem. Soc. 2003, 125, 14 059.
5. For a recent review, see: A. Schnepf, Coord. Chem. Rev. 2006, 250, 2758,
6. M. Somer, W. Carrillo-Cabrera, E. M. Peters, K. Peters, H. G. von Schnering, Z. Anorg. Allg. Chem. 1998, 624, 1915.
7. F. H. Allen, Acta Crystallogr. Sect. B 2002, 58, 380.
8. a) K. N. Campbell, L. T. Eby, J. Am. Chem. Soc. 1941, 63, 216;
9. b) A. L. Henne, K. W. Greenlee, J. Am. Chem. Soc. 1943, 65, 2020;
10. c) H. O. House, E. F. Kinloch, J. Org. Chem. 1974, 39, 747.
11. A. Ugrinov, S. C. Sevov, Chem. Eur. J. 2004, 10, 3727.
12. T. F. Fässler, M. Hunziker, M. E. Spahr, H. Lueken, H. Schilder, Z. Anorg. Allg. Chem. 2000, 626, 692.
13. For a review, see: A. Schnepf, H. Schnöckel, Angew. Chem. 2002, 114, 3682;
14. Angew. Chem. Int. Ed. 2002, 41, 3533.
15. a) J. M. Goicoechea, M. W. Hull, S. C. Sevov, J. Am. Chem. Soc. 2007, 129, 7885-7893;
16. b) J. M. Goicoechea, S. C. Sevov, Angew. Chem. 2006, 118, 5271;
17. Angew. Chem. Int. Ed. 2006, 45, 5147.
18. G. M. Sheldrick, Bruker-Nonius AXS, Madison, WI, USA, 2001.