Aluminum alkyl complexes containing bidentate, mono- or di-anionic pyrrolyl ligands: Intramolecular elimination of methane and 1-hexene polymerization

Journal of the Chinese Chemical Society

Volumn 53, Issue 6, 2006, Pages 1297-1302

  Zhou, Chong Chin ^a   Hung, Chen Hsiung ^a   Huang, Jui Hsien ^a   Lee, Ting Yu ^b  

^a NATIONAL CHANGHUA UNIVERSITY OF EDUCATION   (Taiwan)

^b NATIONAL UNIVERSITY OF KAOHSIUNG   (Taiwan)

Author keywords

Aluminum; Hexene polymerization; Intramolecular eliminatin; Pyrrolyl

Indexed keywords

EID: 34548569272     PISSN: 00094536     EISSN: None     Source Type: Journal    
DOI: 10.1002/jccs.200600173     Document Type: Article

References (38)

1. (a) LaPointe, R. E. U.S. Patent No. 5321106, June 14, 1994.
2. (b) Lai, S.; Wilson, J. R.; Knight, G. W.; Stevens, J. C.; Chum, P. -W. U.S. Patent, No. 5272236, December, 1993.
3. (c) Canich, J. A. M. Eu. Pat. App. 90309899.4, September 10, 1990.
4. (d) Devore, D. D.; Timmers, F. J.; Hasha, D. L.; Rosen, R. K.; Marks, T. J.; Deck, P. A.; Stern, C. L. Organometallics 1995, 14, 3132.
5. (e) Shipiro, P. J.; Bunel, E.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1990, 9, 867.
6. (f) Schwink, L.; Knochel, P.; Eberle, T.; Okuda, J. Organometallics 1998, 17, 7.
7. (g) Chen, Y.-X.; Marks, T. J. Organometallics 1997, 16, 3649.
8. (h) Sinnema, P.-J.; van der Veen, L.; Spek, A. L.; Veldman, N.; Teuben, J. H. Organometallics 1997, 16, 4245.
9. (i) Carpenetti, D. W.; Kloppenburg, L.; Kupec, J. T.; Peterson, J. L. Organometallics 1996, 15, 1572.
10. (j) Chen, E. Y. -X.; Kruper, W. J.; Roof, G.; Wilson, D. R. J. Am. Chem. Soc. 2001, 123, 745.
11. (k) Irwin, L. J.; Reibenspies, J. H.; Miller, S. A. J. Am. Chem. Soc. 2004, 126, 16716.
12. (l) Guo, N.; Li, L.; Marks, T. J. J. Am. Chem. Soc. 2004, 126, 6542.
13. (m) Wang, H.; Chan, H.-S.; Okuda, J.; Xie, Z. Organometallics 2005, 24, 3118.
14. (a) Fokken, S.; Spaniol, T. P.; Kang, H.-C.; Massa, W.; Okuda, J. Organometallics 1996, 15, 5069.
15. (b) Mack, H.; Eisen, M. S. J. Chem. Soc. Dalton Trans. 1998, 17.
16. (c) van der Linden, A.; Schaverien, C. J.; Meijboom, N.; Ganter, C.; Orpen, G. A. J. Am. Chem. Soc. 1995, 117, 3008.
17. (d) Zhang, Y.; Mu, Y. Organometallics 2006, 25, 631.
18. (a) Scollard, J. D.; McConville, D. H.; Vittal, J. J. Organometallics 1997, 16, 4415.
19. (b) Baumann, R.; Davis, W. M.; Schrock, R. R. J. Am. Chem. Soc. 1997, 119, 3830.
20. (c) Warren, T. H.; Schrock, R. R.; Davis, W. M. Organometallics 1996, 15, 562.
21. (d) Scollard, J. D.; McConville, D. H.; Payne, N. C.; Vittal, J. J. Macromolecules 1996, 29, 5241.
22. (e) Tsuie, B.; Swenson, D. C.; Jordan, R. F. Organometallics 1997, 16, 1392.
23. (f) Scollard, J. D.; McConville, D. H. J. Am. Chem. Soc. 1996, 118, 10008.
24. (g) Baumann, R.; Davis, W. M.; Schrock, R. R. J. Am. Chem. Soc. 1997, 119, 3830.
25. (h) Cho, D. J.; Wu, C. J.; Sujith, S.; Han, W.-S.; Kang, S. O.; Lee, B. Y. Organometallics 2006, 25, 2133.
26. (a) Atwood, D. A. Coord. Chem. Rev. 1998, 176, 407.
27. (b) Coles, M. P.; Jordan, R. F. J. Am. Chem. Soc. 1997, 119, 8125.
28. (c) Ihara, E.; Young, V. G., Jr.; Jordan, R. F. J. Am. Chem. Soc. 1998, 120, 8277.
29. (d) Radzewich, C. E.; Guzei, I. A.; Jordan, R. F. J. Am. Chem. Soc. 1999, 121, 8673.
30. (e) Pietryga, J. M.; Gorden, J. P.; Macdonald, C. L. B.; Voigt, A.; Wiacek, R. J.; Cowley, A. H. J. Am. Chem. Soc. 2001, 123, 7713.
31. Non porphyrin pyrrolyl ligands: (a) Arunachalampillai, A.; Crewdson, P.; Korobkov, I.; Gamgarotta, S. Organometallics 2006, 25, 3856.
32. (b) Harris, S. A.; Ciszewski, J. T.; Odom, A. L. Inorg. Chem. 2001, 40, 1987.
33. (c) Ciszewski, J. T.; Harrison, J. F.; Odom, A. L. Inorg. Chem. 2004, 43, 3605.
34. (d) Reid, S. D.; Blade, A. J.; Wilson, C.; Love, J. B. Inorg. Chem. 2006, 45, 636.
35. (e) Yu, J. O.; Lam, E.; Sereda, J. L.; Rampersad, N. C.; Lough, A. J.; Browning, C. S.; Farrar, D. H. Organometallics 2005, 24, 37.
36. Raines, S.; Kovacs, C. A. J. Heterocycl. Chem. 1970, 7, 223.
37. Intramolecular methane elimination, for example: Emig, N.; Nguyen, H.; Krautscheid, H.; Réau, R.; Cazaux, J.-B.; Bertrand, G. Organometallics 1998, 17, 3599.
38. Similar phenomena have been seen, for example: Coles, M. P.; Swenson, D. C.; Jordan, R. F. Organometallics 1997, 16, 5183.