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34548527919
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This is to be compared with the additions of vinyl-Rh1 species to γ-OH-substituted cyclic enones, which may take place under chelation or nonchelation control, and similar additions of Ar-Rh1 species, which take place under nonchelation control. See ref 6
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1 species, which take place under nonchelation control. See ref 6.
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For OH-directed stereoselectivity in Rh-catalyzed hydrogenation reactions, see:, and references cited therein
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Similar models have been used to interpret the addition reactions of other nucleophiles to γ-hydroxy-substituted α,β-unsaturated esters. See: Kireev, A. S, Manpadi, M, Kornienko, A. J. Org. Chem. 2006, 71, 2630 and references cited therein
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Similar models have been used to interpret the addition reactions of other nucleophiles to γ-hydroxy-substituted α,β-unsaturated esters. See: Kireev, A. S.; Manpadi, M.; Kornienko, A. J. Org. Chem. 2006, 71, 2630 and references cited therein.
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