Temperature dependant micellization of AOT in aqueous medium: Effect of the nature of counterions

Journal of Dispersion Science and Technology

Volumn 28, Issue 6, 2007, Pages 984-989

  Chakraborty, Amitabha ^a   Chakraborty, Subrata ^a   Saha, Swapan K ^a  

^a UNIVERSITY OF NORTH BENGAL   (India)

Author keywords

Aerosol OT; Counter ion; Critical micelle concentration; Thermodynamic parameters

Indexed keywords

ELECTRIC CONDUCTIVITY MEASUREMENT; FREE ENERGY; ION EXCHANGE; IONIZATION; LITHIUM; MICELLIZATION; POTASSIUM; SURFACE TENSION; THERMODYNAMIC PROPERTIES;

COUNTER ION; SULPHOSUCCINIC ACID;

CRITICAL MICELLE CONCENTRATION;

CRITICAL MICELLE CONCENTRATION; ELECTRIC CONDUCTIVITY MEASUREMENT; FREE ENERGY; ION EXCHANGE; IONIZATION; LITHIUM; MICELLIZATION; POTASSIUM; SURFACE TENSION; THERMODYNAMIC PROPERTIES;

EID: 34548435500     PISSN: 01932691     EISSN: 15322351     Source Type: Journal    
DOI: 10.1080/01932690701463175     Document Type: Article

References (40)

1. Delbene, J. E. (1979) An ab initio molecular orbital study of 2- and 4-monosubstituted pyridines. J. Am. Chem. Soc., 107, pp. 6184-6189.
2. Shah, D. O. (1991) Surface Phenomena in Enhanced Oil Recovery, Plenum Press, New York
3. Jha, B. K., Patist, A. and Shah, D. O. (1999) Effect of antifoaming agents on the micellar stability and foamability of sodium dodecyl sulfate solutions. Langmuir, 15, pp. 3042-3044.
4. Rehag, H. and Hoffmann, H. (1991) Viscoelastic surfactant solutions: Model systems for rheological research. Mol. Phys., 74, p. 933.
5. Hoffmann, S., Rauscher, A. and Hoffmann, H. (1991) Shear induced micellar structures. Ber. Bunsen-Ges. Phys. Chem., 95, pp. 153-164.
6. Mukerjee, P. (1961) The nature of the association equilibria and hydrophobic bonding in aqueous solutions of association colloids. Adv. Colloid Interface Sci., 1, pp. 242-275.
7. Baumuller, W., Hoffmann, H., Ulbricht, W., Tondre, C. and Zana, R. (1978) Chemical relaxation and equilibrium studies of aqueous solutions of laurylsulfate micelles in the presence of divalent metal ions. J. Colloid Interface Sci., 64, pp. 418-437.
8. Satake, I., Iwamatsu, I., Hosokawa, S. and Matuura, R. (1963) The surface activities of bivalent metal alkyl sulfates. I. On the micelles of some metal alkyl sulfates. Bull. Chem. Soc. Jpn., 36, pp. 204-209.
9. Benrraou, M., Bales, B. L. and Zana, R. (2003) Effect of the nature of the counterion on the properties of anionic surfactants. 1. cmc, ionization degree at the cmc and aggregation number of micelles of sodium, cesium, tetramethylammonium, tetraethylammonium, tetrapropylammonium, and tetrabutylammonium dodecyl sulfates. J. Phys. Chem. B, 107, pp. 13432-13440.
10. Nusselder, J. J.H. and Engberts, J. B.F.N. (1992) Toward a better understanding of the driving force for micelle formation and micellar growth. J. Colloid Interface Sci., 148, pp. 353-361.
11. Paredes, S., Tribout, M., Ferreira, J. and Leonis, J. (1976) A microcalorimetric method of determination of critical miceller concentration and enthalpy of micellization. Colloid Polym. Sci., 254, pp. 637-642.
12. Shanks, P. C. and Franses, E. I. (1992) Estimation of micellization parameters of aqueous sodium dodecyl sulfate from conductivity data. J. Phys. Chem., 96, pp. 1794-1805.
13. Goddard, E. D. and Benson, G. C. (1957) Conductivity of aqueous solutions of some paraffin chain salts. Can. J. Chem., 35, pp. 986-991.
14. Kameyama, K. and Toshio, T. (1990) Micellar properties of octylglucoside in aqueous solutions. J. Colloid Interface Sci., 137, pp. 1-10.
15. Tanford, C. (1980) The Hydrophobic Effect: Formation of Micelles and Biological Membranes, Wiley, New York
16. Paula, S., Süs, W., Tuchtenhagen, J. and Blume, A. (1995) Thermodynamics of micelle formation as a function of temperature: A High sensitivity titration calorimetry study. J. Phys. Chem., 99, pp. 11742-11751.
17. Onori, G. and Santucci, A. (1997) Calorimetric study of the micellization of n-butoxyethanol in water. J. Phys. Chem. B., 101, pp. 4662-4666.
18. Birdi, K. S. (1983) Calorimetric determination of the enthalpy of micelle formation in aqueous media. Colloid Polym. Sci., 261, pp. 45-48.
19. von Os, N. M., Daane, G. J. and Haandrekman, G. (1991) The effect of chemical structure upon the thermodynamics of micellization of model alkylarenesulfonates: III. Determination of the critical micelle concentration and the enthalpy of demicellization by means of microcalorimetry and a comparison with the phase separation model. J. Colloid Interface Sci., 141, pp. 199-217.
20. Barry, B. W. and Russel, G. F.J. (1972) Prediction of micellar molecular weights and thermodynamics of micellization of mixtures of alkyltrimethylammonium salts. J. Colloid Interface Sci., 40, pp. 174-194.
21. Emerson, M. F. and Holtzer, A. (1967) Hydrophobic bond in micellar systems. Effects of various additives on the stability of micelles of sodium dodecyl sulfate and of n-dodecyltrimethylammonium bromide. J. Phys. Chem., 71, pp. 3320-3330.
22. Eastoe, J., Robenson, B. H. and Heenan, R. K. (1993) Water-in-oil microemulsions formed by ammonium and tetrapropylammonium salts of Aerosol OT. Langmuir, 9, pp. 2820-2822.
23. Temsamani, M. B., Maeck, M., Hassani, I. E. and Hurwitz, H. D. (1998) Fourier transform infrared investigation of water states in aerosol-ot reverse micelles as a function of counterionic nature. J. Phys. Chem. B., 102, pp. 3335-3340.
24. xOH, in aqueous solution. J. Phys. Chem., 86, pp. 541-545.
25. Oh, S. G. and Shah, D. O. (1993) Effect of counterions on the interfacial tension and emulsion droplet size in the oil/water/dodecyl sulfate system. J. Phys. Chem., 97, pp. 284-286.
26. Morori, A. (1992) Micelles: Theoretical and Applied Aspects, Planum Press, New York
27. Weckström, K., Hanu, K. and Rosenholm, J. B. (1994) Enthalpies of mixing a non-ionic surfactant with water at 303.15 K studied by calorimetry. J. Chem. Soc., Faraday Trans, 90, pp. 733-738.
28. Evans, D. F. and Ninham, B. W. (1986) Molecular forces in the self-organization of amphiphiles. J. Phys. Chem., 90, pp. 226-234.
29. Evans, D. F. and Ninham, B. W. (1983) Ion binding and the hydrophobic effect. J. Phys. Chem., 87, pp. 5025-5032.
30. Lumry, R. and Rajender, S. (1970) Enthalpy-entropy compensation phenomena in water solutions of proteins and small molecules: A ubiquitous properly of water. Biopolymers., 9, pp. 1125-1227.
31. Privalov, P. L. and Gill, S. J. (1989) The hydrophobic effect: A reappraisal. Pure Appl. Chem., 61, pp. 1097-1104.
32. Jolicoeur, C. and Philip, P. R. (1974) Enthalpy-entropy compensation for micellization and other hydrophobic interactions in aqueous solutions. Can. J. Chem., 52, pp. 1834-1839.
33. Lee, B. (1991) Solvent reorganization contribution to the transfer thermodynamics of small nonpolar molecules. Biopolymers, 31, pp. 993-1008.
34. Lee, B. (1994) Enthalpy-entropy compensation in the thermodynamics of hydrophobicity. Biophys. Chem., 51, pp. 271-278.
35. Madau, B. and Lee, B. (1994) Role of hydrogen bonds in hydrophobicity: the free energy of cavity formation in water models with and without the hydrogen bonds. Biophys. Chem., 51, pp. 279-289.
36. Myers, D. (1992) Surfactant Science and Technology, VCH, New York
37. La Mesa, C. (1990) Dependence of critical micelle concentration of intensive variables: A reduced variables analysis. J. Phys. Chem., 94, pp. 323-326.
38. Majhi, P. R. and Blume, A. (2001) Thermodynamic characterization of temperature-induced micellization and demicellization of detergents studied by differential scanning calorimetry. Langmuir, 17, pp. 3844-3851.
39. Marcus, Y. (1985) Ion Solvation, Wiley-Interscience, New York
40. Nakagaki, M. and Handa, T. (1984) Effect of structure on activity at the critical micelle concentration and on the free energy of micelle formation. ACS Symposium Series, 253, p. 73.