One-electron reduction of methanesulfonyl chloride. The fate of MeSO 2CI•- and MeSO2• intermediates in oxygenated solutions and their role in the cis-trans isomerization of mono-unsaturated fatty acids

Journal of the American Chemical Society

Volumn 129, Issue 28, 2007, Pages 8716-8723

  Tamba, Maurizio ^a   Dajka, Katalin ^a   Ferreri, Carla ^a   Asmus, Klaus Dieter ^b   Chatgilialoglu, Chryssostomos ^a  

^a CNR   (Italy)

^b ADAM MICKIEWICZ UNIVERSITY   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

METHANESULFONYL CHLORIDE; SULFONYL RADICALS; SUPEROXIDES;

ABSORPTION; CATALYST ACTIVITY; FREE RADICALS; ISOMERIZATION; REDUCTION; STEREOCHEMISTRY;

FATTY ACIDS;

4 NITROACETOPHENONE; MESYLIC ACID; METHANE; METHANESULFONYL CHLORIDE; MONOUNSATURATED FATTY ACID; OXYGEN; RADICAL; SULFONE DERIVATIVE; SUPEROXIDE; UNCLASSIFIED DRUG; FREE RADICAL; MESYLIC ACID DERIVATIVE; UNSATURATED FATTY ACID;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CIS ISOMER; ELECTRON TRANSPORT; EQUILIBRIUM CONSTANT; ISOMERIZATION; LIGHT ABSORPTION; ONE ELECTRON REDUCTION; OXYGENATION; REACTION ANALYSIS; REACTION TIME; REDUCTION; STRUCTURE ANALYSIS; TRANS ISOMER; BIOLOGICAL MODEL; CHEMISTRY; OXIDATION REDUCTION REACTION; SOLUTION AND SOLUBILITY; STEREOISOMERISM;

FATTY ACIDS, UNSATURATED; FREE RADICALS; MESYLATES; MODELS, BIOLOGICAL; OXIDATION-REDUCTION; OXYGEN; SOLUTIONS; STEREOISOMERISM;

EID: 34548379572     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja070626q     Document Type: Article

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