Solid oxide fuel cells: A challenge for plasma deposition processes

Journal of Thermal Spray Technology

Volumn 16, Issue 3, 2007, Pages 381-403

  Henne, Rudolf ^a  

^a GERMAN AEROSPACE CENTER DLR   (Germany)

Author keywords

Applications; Designs; Function; Productionby plasma deposition methods; Requirements; Solid oxide fuel cells

Indexed keywords

CARNOT RELATIONSHIP; CHEMICAL ENERGY;

CERAMIC MATERIALS; HIGH TEMPERATURE PROPERTIES; PLASMA DEPOSITION; PLASMA SPRAYING; RELIABILITY;

SOLID OXIDE FUEL CELLS (SOFC);

EID: 34548314724     PISSN: 10599630     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11666-007-9053-4     Document Type: Review

References (108)

1. N.Q. Minh and T. Takahashi, Science and Technology of Ceramic Fuel Cells, Elsevier, 1995
2. J. Larminie and A. Dicks, Fuel Cell Systems Explained, 2nd Ed., Wiley, 2003, ISBN 0-470-84857-X
3. S.C. Singhal and K. Kendall (Eds.), High Temperature Solid Oxide Fuel Cells, Fundamentals, Design and Application, Elsevier, 2003, ISBN 1-85617-387-9
4. L.R. Pederson, P. Singh, X.-D. Zhou (2006) Application of Vacuum Deposition Methods to Solid Oxide Fuel Cells. Elsevier: Vacuum 80: 1066-1083
5. K. Kendall, Tubular Cells: A Novel SOFC Design, Final Year Project Report, Middlesex University, July 1993
6. K. Kendall, Solid Oxide Fuel Cells III, S.C. Singhal and H. Iwahara, Eds., The Electrochemical Society Proceedings, Pennington, NJ, PV93-4, 1993, p 813-821
7. A.V. Virkar, B. Butler, M. Gardiner, J. Rich, and M. Homel, Portable Solid Oxide Fuel Cell-Based Power Source Operating on Logistic Fuels, International Conference on Hydrogen and Fuel Cell Technologies, Oct. 26 2006 (Hamburg, Germany), 2006
8. M. Yokoyama, K. Nagai, K. Ukai, and Y. Mizutani, Microtube SOFC Module and its Electrochemical Evaluation, CD of the 7th European SOFC Forum, Lucerne, July 2006, B032
9. H. Tsukuda, A. Notomi, N. Hisatome 2000 Application of Plasma Spraying to Tubular-Type Solid Oxide Fuel Cells Production. J. Thermal Spray Technol. 9(3): 364-368
10. B. Gut and U. Bossel, Test of a Portable SOFC Generator with Methanol, CD of the 7th European SOFC Forum, Lucerne, July 2006, B 116
11. A. Schuler and V. Nerlich, The Rebirth of HEXIS, CD of the 7th European SOFC Forum, Lucerne, July 2006, A 061
12. www.seca 2004 and 2005
13. S.C. Farmer, B. Steinmetz, C. Steffen, L. Kohaut, and J. Walker, SOFC for Aerospace Applications at NASA (GRC), 2005 Fuel Cell Seminar, Nov. 14-18, 2005 (Palm Springs, Cal. USA), 2005
14. P. Lamp, J. Tachtler, O. Finkenwirth, S Mukerjee, and St. Shaffer, Development of an Auxiliary Power Unit with Oxide Fuel Cells for Automotive Applications, Fuel Cells, 2003, 3 (3), Wiley-VCH, 2003
15. F.-J. Wetzel and J. Schneider, Future Powertrain Technology Projects, 14th World Hydrogen Energy Conference, June 9-13, 2002 (Montreal, Canada)
16. G. Schiller, R. Henne, M. Lang, M. Müller 2003 Development of Solid Oxide Fuel Cells (SOFC) for Stationary and Mobile Applications by Applying Plasma Deposition Processes. Mater. Sci. Forum 426-432(3): 2539-2544
17. J.J. Botti, M.J. Grieve, J.A. MacBain, and J.J. Ronning, Scenarios for Integration of SOFC APUs into Future Powertrain Systems, Proc. Aachener Motorenkolloquium, October 2005
18. Th. Flower, Bringing Siemens SOFC Products to Market-an Update, CD of the 7th European SOFC Forum, Lucerne, July 2006, A 081
19. R.P. Travis, C. Balestrino, R. Hill, and D. Bernardi, Development of a 1 MW SOFC System at Rolls-Royce Fuel Cell Systems, CD of the 7th European SOFC Forum, Lucerne, July 2006, B 096
20. H. Tannenberger and R. Schmitt, Swiss Patent No. 491 510,31
21. H. Gruner and H. Tannenberger, US Patent 5, 328,779
22. H. Gruner and H. Tannenberger, Plasma Sprayed Coatings for Fuel Cell Techniques (in German) DVS-Bericht, Vol. 130, 1990, p 194-196
23. H.R. Gruner and H. Tannenberger, SOFC Elements by Vacuum-Plasma-Spraying (VPS), Proceedings of 1st European Solid Oxide Fuel Cell Conference, Lucerne, Switzerland, Vol. 2, 1994, p 611-616
24. W. Mallener, K. Wippermann, H. Jansen, Z. Li, and D. Stöver, VPS Fabrication of Electroactive Solid Oxide Fuel Cell Membranes, Proc. Intern. Thermal Spray Conf. (Orlando, Fl., USA), 1992, p 835-838
25. R. Henne, E. Fendler, and M. Lang, Potential of Vacuum Plasma Spraying for the Production of SOFC Components, Proc. 1st European Solid Oxide Fuel Cell Conf. (Lucerne, Switzerland), 1994, p 612-627
26. R. Henne, W. Mayr, and A. Reusch, Einfluss der Düsenkontur beim Hochgeschwindigkeits-Vakuumplasmaspritzen auf Partikelverhalten und Schichtqualitä, (Influence of Torch Nozzle Contour with High Velocity Vacuum Plasma Spraying on Particle Behaviour and Layer Quality), Thermal Plasma 1993, Aachen, DVS, Vol. 152, 1993, p 7-11
27. R. Henne, G. Schiller, V. Borck, M. Müller, M. Lang, and R. Ruckdäschel, SOFC Components Production-an Interesting Challenge for DC- and RF- Plasma Spraying, Proc. 15th Internat. Thermal Spray Conf., May 1998 (Nice, France)
28. C. Zhang, H.L. Liao, W.Y. Li, G. Zhang, C. Coddet, C.J. Li, C.X. Li, X.J. Ning (2006), Characterisation of SOFC Electrolyte Deposition by Atmospheric Plasma Spraying and Low Pressure Plasma Spraying, J. Thermal Spray Technol., 15(4), 598-603
29. R. Rampon, G. Bertrand, and Chr. Coddet, Studies on Preparation of Yttria Stabilized Zirconia Thin Films by Suspension Plasma Spraying for SOFC Electrolytes, CD of 7th European SOFC Forum, Lucerne, 2006, P 0421
30. R. Rampon, G. Bertrand, F.-L. Toma, C. Coddet 2006 Liquid Plasma Sprayed Coatings of Yttria Stabilized Zirconia for SOFC Electrolytes. J. Thermal Spray Technol., 15(4): 682-688
31. R. Siegert, J.-E. Döring, R. Vaßen, J.-L. Marqués, D. Sebold, and D. Stöver, Denser Ceramic Coatings Obtained by the Optimization of the Suspension Plasma Spraying Technique, Proceedings of the ITSC 2004, Osaka, Japan
32. R. Henne, V. Borck, D. Siebold, W. Mayr, A. Reusch, M. Rahmane, G. Soucy, and M. Boulos, Converging-Diverging Nozzles for Improved Atmospheric Plasma Spraying, VDI-Berichte Nr. 1166, 1995, p 247-266, Proc. European Conference on Thermal Plasma Processes, (Aachen), 1994 (and JTST-paper) 247-266, Proc. European Conference on Thermal Plasma Processes, (Aachen), 1994 (and JTST-paper)
33. T. Kavka, R. Henne, and J. Arnold, Improvement of Plasma Spraying Conditions for SOFC Applications: Effect of Nozzle Geometry and Gas Shrouds, Proc. 2006 Intern. Thermal Spray Conf, May (Seattle, Wash., USA), 2006
34. G. Schiller, T. Franco, R. Henne, M. Lang, R. Ruckdäschel, P. Otschick, and K. Eichler, Solid Oxide Fuel Cells VII, H. Yokogawa and S.C. Singhal, Eds., The Electrochemical Soc. Proc. (Pennington, N.J.), PV 2001-16, 2001, p 895
35. G. Schiller, R. Henne, M. Lang, and M. Müller, DC and RF Plasma Processing for Fabrication of Solid Oxide Fuel Cells, Internat. Thermal Spray Conf., May 2004 (Osaka, Japan)
36. M. Lang, Th. Franco, M. Johnson, G. Schiller, and P. Szabo, Characterisation of Vacuum Plasma Sprayed Planar Solid Oxide Fuel Cells During Reduction-Oxidation Cycling, Proc. 6th European Solid Oxide Fuel Cell Forum, May 28-June 2nd (Lucerne, Switzerland), 2005
37. G. Renouard-Vallet, L. Bianchi, A.L. Sauvet Monts, P. Fauchais, M. Vardelle, M. Boulos, and F. Gitzhofer, Elaboration of SOFCs' Electrolytes by Air Plasma Spraying (APS) and Vacuum Plasma Spraying (VPS)-Comparison of Electrolytes' Properties, Proc. Internat. Thermal Spray Conf., May 2004 (Osaka, Japan)
38. A.A. Syed, Z. Ilhan, J. Arnold, G. Schiller, H. Weckmann 2006 Improved Plasma Sprayed YSZ Coatings for SOFC Electrolytes. J. Thermal Spray Technol. 15(4): 617-622
39. 1.95 Powder on the Sinterability and other Properties for an SOFC Electrolyte, CD of the 7th European SOFC Forum, Lucerne, 2006, B 053
40. C.-J. Li, X.-J. Ning, C.-X. Li (2005) Effect of Densification Processes on the Properties of Plasma-Sprayed YSZ Electrolyte Coatings for Solid Oxide Fuel Cells, Surf. Coat. Technol. 190: 60-64
41. K.A. Khor, X.J. Chen, and S.H. Chan, Spray Treatment of Plasma Sprayed Yttria Stabilized Zirconia (YSZ) Electrolyte with Spark Plasma Sintering (SPS) Technique, Proc. ITSC 2004, (Osaka, Japan), 2004
42. I. Fagoaga, M. Parco, G. Barykin, C. Vaquero, and J. de Juan, Development of Zirconia Coatings by HFPD, Proc. 2006 Internat. Thermal Spray Conf., May 2006 (Seattle, Wash., USA)
43. A. Refke, G. Barbezat, D. Hawley, and R.K. Schmid, Low Pressure Plasma Spraying (LPPS) as a Tool for the Deposition of Functional SOFC Components, Proc. 2004 Internat. Thermal Spray Conf., May 2004 (Osaka, Japan)
44. K. Mailhot, F. Gitzhofer, and M.I. Boulos, Supersonic Induction Plasma Spraying of Yttria Stabilised Zirconia Films, Proc. 15th Internat. Thermal Spray Conf., May 1998 (Nice, France), p 1419-1424
45. G. Renouard-Vallet, F. Gitzhofer, M. Boulos, P. Fauchais, M. Vardelle, and L. Bianchi, Optimization of Axial Injection Conditions in a Supersonic Induction Plasma Torch: Application to SOFCs, Thermal Spray 2003: Advancing the Science & Applying the Technology, C. Moreau and B. Marple, Eds., ASM International, Mat. Park, Ohio, USA, 2003, p 195-202
46. L. Jia, Chr. Dossou-Yovo, C. Gahlehrt, and F. Gitzhofer, Induction Plasma Spraying of Samarium Doped Ceria as Electrolyte for Solid Oxide Fuel Cells, Proc. 2004 Intern. Thermal Spray Conf., May 2004 (Osaka, Japan)
47. F. Hudon, H. Mënard, and J. Jurewicz, RF Plasma Deposition of Controlled Porosity Deposits. Application to Solid Oxide Fuel Cells, 17th Internat. Symposium on Plasma Chemistry, Aug. 2005 (Toronto, Canada), Topic 12: Plasma Spray and Thermal Plasma Materials Processing
48. H.Y. Jung, H. Kim, H.-R. Kim, J.-W. Son, J. Kim, H.-W. Lee, H. Song, and J.-H. Lee, Fabrication and Characterisation of Solid Oxide Fuel Cell Based on Sc-Doped Zirconia, CD of the 7th European SOFC Forum, Lucerne 2006, P 0429
49. T. Yoshida, M. Boulos, F. Gitzhofer, J. Heberlein, R. Henne, and T. Ishigaki, Development of Integrated Fabrication Process for Solid Oxide Fuel Cells using Advanced Plasma Technology, 1998, Final Report for a NEDO International Research Grant
50. H.C. Chen, J. Heberlein, R. Henne 2000 Integrated Fabrication Process for Solid Oxide Fuel Cells in a Triple Torch Plasma Reactor. J. Thermal Spray Technol. 9(3): 348-353
51. E. Theophile, F. Gitzhofer, and M.I. Boulos, Supersonic Induction Plasma Spraying of Yttria Stabilized Zirconia for Solid Oxide Fuel Cells, 14th Internat. Symposium on Plasma Chemistry, August 1999 (Prague)
52. F. Gitzhofer, M. Boulos, J. Heberlein, R. Henne, T. Ishigaki, and T. Yoshida, Integrated Fabrication Processes for Solid Oxide Fuel Cells Using Thermal Spray Technology, MRS Bulletin, July 2000, p 38-42
53. F.L. Toma, G. Bertrand, R. Rampon, D. Klein, and C. Coddet, Relationship between the Suspension Properties and Liquid Plasma Sprayed Coating Characteristics, Proc. 2006 Internat. Thermal Spray Conf., May 2006 (Seattle, Wash., USA)
54. C.-J. Li, X.-J. Ning, C.-X. Li 2005 Effect of Densification Processes on the Properties of Plasma Sprayed YSZ Electrolyte Coatings for Solid Oxide Fuel Cells. Surf. Coat. Technol. 190(1): 60-64
55. 3-δ ITSOFC Fabricated by Atmospheric Plasma Spraying. J. Power Sour. 140(2): 217-225
56. R. Vaßen and D. Stöver, Development of Thin and Gastight Ceramic Coatings by Atmospheric Plasma-Spraying, Proc. 2006 Internat. Thermal Spray Conf., May, 2006 (Seattle, Wash., USA)
57. M. Müller, E. Bouyer, M. v. Bradke, D.W. Branston, R.B. Heimann, R. Henne, G. Lins, and G. Schiller, Thermal Induction Plasma Processes for the Synthesis of SOFC Materials, Beitrag für Materialwissenschaft und Werkstofftechnik, Wiley VCH, No 3/4, 2002
58. A. Rolle and J.T.S. Irvine; Electrical, Microstructural Properties and Sulphur Tolerance of Anodes for SOFCs, 7th European SOFC Forum, July 2006, Lucerne, Switzerland
59. 2/Ni-anodes for Solid Oxide Fuel Cells. Ph.D. thesis, University of Stuttgart, 1999 (in German)
60. D. Hathiramani, R. Vaßn, D. Stöver, R.J. Damani 2006 Comparison of Atmospheric Plasma Sprayed Anode Layers for SOFCs Using Different Feedstock. J. Thermal Spray Technol. 15(4): 593-597
61. H. Weckmann, O. Finkenwirth, R. Henne, and A. Refke, Microstructure of Ni-graphite/YSZ Composite Coatings on Porous Metallic Substrates Obtained by Atmospheric Plasma Spraying (APS), Proc. Internat. Thermal Spray Conference (ITSC) 2005 (Basel, Switzerland)
62. H. Weckmann, A. Syed, Z. Ilhan, J. Arnold, Development of Porous Anode Layers for the Solid Oxide Fuel Cell by Plasma Spraying, J. Thermal Spray Technol., 15(4) 2006: 604-609
63. K. Barthel and S. Rambert, Thermal Spraying and Performance of Graded Composite Cathodes as SOFC-Component, Mater. Sci. Forum, 1999, p 308-311
64. K. Barthel, S. Rambert, St. Siegmann 2000 Microstructure and Polarization Resistance of Thermally Sprayed Composite Cathodes for Solid Oxide Fuel Cell Use. J. Thermal Spray Technol. 9(3): 343-347
65. H. Nie, W. Huang, T.-L. Wen, H. Tu, Z. Zhan 2002 LSM Cathodes for SOFC Prepared by Plasma Spraying. J. Mater. Sci. Lett. 21(24): 1951-1953
66. 3 Produced by a Reactive DC Thermal Plasma Spray System, Plasma Chemistry and Plasma Processing, Vol. 23, No. 2, June 2003, p 223 ff
67. C. Monterrubio-Badillo, T. Chartier, H. Ageorges, J.F. Coudert, and P. Fauchais, Preparation of Stable Suspensions of Perovskites for Plasma Spraying, Materials Science Forum (Conf. Proc.) Aug. 2002
68. C. Monterrubio-Badillo, H. Ageorges, T. Chartier, J.F. Coudert, and P. Fauchais, Plasma Spraying of a Perovskite Suspension for SOFC Cathodes, Thermal Spray 2003: Advancing the Science & Applying the Technology, C. Moreau and B. Marple, Eds., ASM International, Mat. Park, Ohio, USA, 2003
69. C. Monterubbio-Badillo, H. Ageorges, T. Chartier, J.F. Coudert, and P. Fauchais, Chemical Composition Optimisation of Perovskite Coatings by Suspension Plasma Spraying for SOFC Cathodes, Internat. Thermal Spray Conf., May 2004 (Osaka, Japan)
70. B.D. White, O. Kesler, N. Ben-Oved, and A. Burgess, Preparation of an SOFC LSM/YSZ Composite Cathode by Air Plasma Spraying, Proc. 2006 Internat. Thermal Spray Conf., May 2006 (Seattle, Wash., USA)
71. G. Schiller, M. Müller, F. Gitzhofer, Preparation of Perovskite Powders and Coatings by Radio Frequency Suspension Plasma Spraying, J. Thermal Spray Technol., 8(3) 1999, 389-392
72. 3-δ (M = Mn, Fe or Co Cathode Materials by Induction Plasma Technology, J. Thermal Spray Technol. Vol. 15(1), 2006, 37-45
73. G. Schiller, M. Müller, E. Bouyer, and M. v. Bradke, RF Plasma Synthesis and Deposition of SOFC Materials, 16th Internat. Symposium on Plasma Chemistry, June 22-27, 2003, (Taormina, Italy)
74. E. Garcia and T.W. Coyle, Thermal Spray Deposition of Fuel Cell Interconnect Material, Proc. 2006 Internat. Thermal Spray Conf, May 2006 (Seattle, Wash., USA)
75. W. Köck, H.P. Martinz, H. Greiner, and M. Janousek, Development and Processing of Metallic Cr-Based Materials for SOFC Parts, Proc. 4th Internat. Symp. On Solid Oxide Fuel Cells, M. Dokiya, O. Yamamoto, H. Tagawa, and S.C. Singhal, Eds., Electrochemical Society (ECS), 1995, p 841-849
76. T. Franco, M. Lang, G. Schiller, P. Szabo, W. Glatz, and G. Kunschert, Powder Metallurgical High Performance Materials for Substrates-Supported IT-SOFCs, 6th European Fuel Cell Forum, 2004, p 209-217
77. T. Malkow, W.J. Quaddakers, L. Singheiser, and H. Nickel, Untersuchung zum Langzeitverhalten von metallischen Interkonnektwerkstoffen der Hochtemperaturbrennstoffzelle (SOFC) im Hinblick auf die Kompatibilität mit kathodenseitigen Kontaktschichten, Bericht des Forschungszentrums Jülich, 1998, No. Jül-3589
78. St. Megel, M. Kusnezoff, V. Sachuk, and A. Reinert, Long-Term Stability of Ferritic Alloys for APU Application, CD of 7th European SOFC Forum, Lucerne, July 2006, B 105
79. R. Henne, M. Müller, E. Proß, G. Schiller, F. Gitzhofer, M. Boulos, Near-Net-Shape Forming of Metallic Bipolar Plates for Planar Solid Oxide Fuel Cells by Induction Plasma Spraying, J. Thermal Spray Technology, Vol. 8(1), 1999, 110-116
80. A. Venskutonis and G. Kunschert, Powder-Metallurgical Processing of Interconnect Materials and Components for Stationary and Mobile SOFC Applications, 7th European SOFC Forum, July 2006, Lucerne, Switzerland
81. H. Schmidt, B. Brückner, and K. Fischer, Solid Oxide Fuel Cells IV, M. Dokiya, O. Yamamoto, H. Tagawa, and S.C. Singhal, Eds., The Electrochemical Soc. Proc., Pennington, N.J. PV 95, 1995, p 869
82. R. Ruckdäschel, R. Henne, G. Schiller, and H. Greiner, Solid Oxide Fuel Cells V, U. Stimming, S.C. Singhal, H. Tagawa and W. Lehnert, Eds., The Electrochemical Soc: Proc., Pennington, N.J., PV 97-40, 1997, p 1273
83. G. Schiller, R. Henne, R. Ruckdäschel, and H. Greiner, Vacuum Plasma Sprayed Protective Layers for Flat-Plate Solid Oxide Fuel Cells, 14th Internat. Plansee Seminar '97, Vol. 1, Metallic High Temperature Materials, Conf. Proc. of Plansee AG (Reutte, Austria), 1997, p 671-684
84. Th. Franco, R. Ruckdäschel, M. Lang, G. Schiller, and P. Szabo, Diffusion and Protecting Barrier Layers in a Substrate-Supported SOFC Concept, CD of the 7th European SOFC Forum, Lucerne, July 2006, P 0802
85. R. Henne, T. Franco, R. Ruckdäschel 2006 High-Velocity DC-VPS for Diffusion and Protecting Barrier Layers in Solid Oxide Fuel Cells, J. Thermal Spray Technol. 15(4): 695-700
86. H.W. Nie, T.-L. Wen, H.Y. Tu (2003) Protection Coatings for Planar Oxide Fuel Cell Interconnect Prepared by Plasma Spraying. Mater. Res. Bull. 38: 1531-1536
87. M.-J. Garcia-Vargas, M. Zahid, F. Tietz, Th. Kiefer, Ph. Stevens, and R. Vaßen, Protection of SOFC Interconnects against Cr-Evaporation using Atmospheric Plasma-Sprayed Spinel Layers, CD of the 7th European SOFC Forum, Lucerne, July 2006, B 081
88. S.Y. Hwang, J.H. Kim, B.G. Seong, and H. Yang, SOFC Interconnector Coating Using HVOF Process, Proc. Internat. Thermal Spray Conf., May 2006 (Seattle, Wash., USA)
89. M. Lang, R. Henne, S. Schaper, G. Schiller 2001 Development and Characterization of Vacuum Plasma Sprayed Thin Film Solid Oxide Fuel Cells. J. Thermal Spray Technol. 10(4): 618-625
90. X. Huang, K. Ridgeway, S. Narasimhan, K. Reifsnider, and X. Ma, Application of Plasma Sprayed Coatings in a Novel Integrated Composite Seal for SOFCs, Proc. 2006 Internat. Thermal Spray Conf., May 2006 (Seattle, Wash., USA)
91. R. Henne, H.R. Zerfass, and J. Arnold, Verfahren zum Herstellen einer Dichtungsanordnung für einen Brennstoffzellenstapel und Dichtungsanordnung fü einen Brennstoffzellenstapel, Patent Application DEA 102005045053, 21.09.05
92. H.S. Spacil, C.S. Tedmo 1969 Electrochemical Dissociation of Water Vapor in Solid Oxide Electrolyte Cells, J. Electrochem. Soc. 116: 1618-1633
93. D. Stöver, R. Hecker, H. Jansen, and W. Malléner, Shaping of SOFC Components by Use of Plasma Spraying, Proc. 2nd Internat. Symposium on SOFC, Athens, Greece, July, 1991
94. K. Okumura, Y. Aihara, S. Ito, S. Kawasaki 2000 Development of Thermal Spraying-Sintering Technology for Solid Oxide Fuel Cells. J. Thermal Spray Technol. 9(3):354-359
95. A. Notomi, N. Hisatome (1996) Application of Plasma Spraying to Solid Oxide Fuel Cell Production. Pure Appl. Chem. 68: 1101-1106
96. K. Huang, Cell Power Enhancement via Materials Selection, CD of 7th European SOFC Forum, Lucerne, 2006
97. G. Schiller, M. Müller, and F. Gitzhofer, Preparation of Perovskite Powders and Coatings by RF-Suspension Plasma Spraying, Proc. 15th Internat. Thermal Spray Conf., May 1998 (Nice, France)
98. G. Schiller, R.H. Henne, M. Lang, R. Ruckdäschel, S. Schaper (2000) Development of Vacuum Plasma Sprayed Thin-Film SOFC for Reduced Operating Temperature. Fuel Cells Bull. 3: 7-12
99. M. Lang, T. Franco, R. Henne, S. Schaper, and G. Schiller, Proc. 4th European SOFC Forum, A.J. McEvoy, Ed., Oberrohrdorf, Switzerland, 2000, p 231
100. M. Lang, T. Franco, G. Schiller, N. Wagner 2002 Electrochemical Characterisation of Vacuum Plasma Sprayed Thin-Film Solid Oxide Fuel Cells (SOFC) for Reduced Operating Temperatures. J. Appl. Electrochem. 32(8): 871-874
101. G. Schiller, T. Franco, M. Lang, P. Metzger, and A. Störmer, Recent Results on the SOFC APU Development at DLR, Proc. Electrochemical Society, Vol. 2005-07, p 66-75, Internat. Symp. On Solid Oxide Fuel Cells (SOFC-IX), May 2005 (Quebec City, Canada)
102. M. Lang, C. Auer, A. Eismann, Th. Franco, Chr. Lachenmann, G. Schiller, and P. Szabo, Characterisation of SOFC Short Stacks and Stacks for Mobile Application, CD of 7th European SOFC Forum, Lucerne, 2006, B 034
103. M. Lang, P. Szabo, Z. Ilhan, S. Cinque, T. Franco, and G. Schiller, Development of Solid Oxide Fuel Cells and Short Stacks for Mobile Application, Proc. of the 1st European Fuel Cell Technology and Application Conference Dec. 14-16 (Rome, Italy), 2005
104. S. Takenoriri, N. Kadokawa, K. Koseki 2000 Development of Metallic Substrate Supported Planar Solid Oxide Fuel Cells Fabricated by Atmospheric Plasma Spraying. J. Thermal Spray Technol. 9(3): 360-368
105. X. Ma, J. Dai, H. Zhang, J. Roth, T.D. Xiao, D.E. Reisner 2005 Solid Oxide Fuel Cell Development by Using Novel Plasma Spray Techniques. J. Fuel Cell Sci. Technol. 2(3): 190-196
106. X.Q. Ma, H. Zhang, J. Dai, J. Roth, R. Hui, T.D. Xiao, D.E. Reisner 2005 Intermediate Temperature Solid Oxide Fuel Cell Based on Fully Integrated Plasma-Sprayed Components. J. Thermal Spray Technol. 14(1): 61-66
107. D. Hathiramani, R. Vaßen, D. Stöver, R.J. Damani 2006 Comparison of Atmospheric Plasma Sprayed Anode Layers for SOFCs Using Different Feedstock. J. Thermal Spray Technol. 5(4): 593-597
108. St. Renon (GE), Fabrication of SOFCs by Plasma Spray, 30th Anniversary Fuel Cell Seminar, Nov. 13th-17th, 2006, Honolulu, Hawaii, USA