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For review of the leuco dyes, see: Chemistry and Applications of Leuco Dyes, ed. by R. Muthyala, Plenum Press, New York and London, 1997.
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For review of the leuco dyes, see: Chemistry and Applications of Leuco Dyes, ed. by R. Muthyala, Plenum Press, New York and London, 1997.
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2
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34548335008
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a) S. Machida, S. Takayama, N. Ikeda, T. Urano, K. Sano, Proceedings of 218th ACS National Meeting, New Orleans, LA, U.S.A., August, 1999, Abstr., No. ENVR-135.
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N. Ikeda, S. Takayama, S. Machida, T. Urano, A. Tanaka, M. Oguchi, T. Nomaki, K. Sano, Proceedings of 220th ACS National Meeting, Washington, DC, U.S.A., August, 2000, Abstr., No. IEC-181.
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b) N. Ikeda, S. Takayama, S. Machida, T. Urano, A. Tanaka, M. Oguchi, T. Nomaki, K. Sano, Proceedings of 220th ACS National Meeting, Washington, DC, U.S.A., August, 2000, Abstr., No. IEC-181.
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34548333929
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Synthesis and isolation of 2: Rhodamine B base was purchased from Sigma-Aldrich Corp. and purified by recrystallization from toluene. Ethyl-3,4,5-trihydroxybenzoate was purchased from Tokyo Chemical Industry Co, Ltd. and used as received. Rhodamine B base (45.7 mg, 0.10 mmol) and ethyl-3,4,5-trihydroxybenzoate (20.0 mg, 0.10 mmol) were placed in a screw vial (20 cm3) and acetonitrile (1 cm3) was added. The mixture was shaken for a few minutes, and dark red solution was immediately obtained. The solution was kept for an hour with the solvent removed under ambient temperature and red blocks were precipitated. The precipitates were separated by decantation and the solvent was removed completely in vacuo, giving red crystals of 2 22.0 mg, 0.034 mmol, 34% yield, For syntheses and isolation of 3 and 4, see Supporting Information which is available electronically on the CSJ-Journal web site
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3) was added. The mixture was shaken for a few minutes, and dark red solution was immediately obtained. The solution was kept for an hour with the solvent removed under ambient temperature and red blocks were precipitated. The precipitates were separated by decantation and the solvent was removed completely in vacuo, giving red crystals of 2 (22.0 mg, 0.034 mmol, 34% yield). For syntheses and isolation of 3 and 4, see Supporting Information which is available electronically on the CSJ-Journal web site, http://www.csj.jp/journals/chem-lett/index.html.
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