Kinetic aspects of styrene minisuspension polymerization using a mixture PVA-SDS as stabilizer: Effect of the time of addition of SDS

European Polymer Journal

Volumn 43, Issue 9, 2007, Pages 3819-3825

  Ramirez, Jorge C ^a   Herrera Ordonez, Jorge ^a  

^a CENTRO DE INVESTIGACIÓN EN QUÍMICA APLICADA   (Mexico)

Author keywords

Minisuspension polymerization; Polystyrene; Suspension polymerization

Indexed keywords

COLLOIDS; MOLECULAR WEIGHT; PARTICLE SIZE ANALYSIS; POLYMERIZATION; POLYVINYL ALCOHOLS; STABILITY CRITERIA;

MINISUSPENSION POLYMERIZATION; SODIUM DODECIL SULFATE (SDS); SUSPENSION POLYMERIZATION;

STYRENE;

EID: 34548282518     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2007.07.001     Document Type: Article

References (21)

1. Schork F.J., Deshpande P.B., and Leffew K.W. Control of polymerization reactors. Heterogeneous polymerization (1993), Mercel Dekker Inc., New York 85-100
2. Kaminski Lenzi M., Machado Silva F., Lima E.L., and Pinto J.C. Semibatch styrene suspension polimerization proceses. J Appl Polym Sci 89 (2003) 3021-3038
3. Yuan H.G., Kalfas G., and Ray W.H. Suspension polymerization. JMS-Rev Macromol Chem Phys C31 2&3 (1991) 215-299
4. Vivaldo-Lima E., Wood P.E., and Hamielec A.E. An updated review on suspension polymerization. Ind Eng Chem 36 (1997) 939-965
5. Dotson N.A., Galván R., Laurence R.L., and Tirrellz M. Polymerization process modeling. Heterogeneous polymerization (1996), VCH, New York 305-312
6. Ramirez J.C., Herrera-Ordonez J., and Gonzalez V.A. Kinetics of styrene minisuspension polymerization using a mixture PVA-SDS as stabilizer. Polymer 47 (2006) 3336-3343
7. Philip J., Gnanaprakash G., Jayakumar T., Kalyanasundaram P., and Raj B. Three distinct scenarios under polymer, surfactant, and colloidal interaction. Macromolecules 36 (2003) 9230-9236
8. Almog Y., and Levy M. Dispersion polymerization of styrene: effect of surfactant. J Polym Sci Polym Chem 19 (1981) 115-126
9. Almog Y., and Levy M. Free radical polymerization of styrene and methyl methacrylate in dispersed systems and the effect of carbon black. Ind Eng Prod Res Dev 21 (1982) 163-170
10. Nomura M., Ikoma J., and Fujita K. Kinetics and mechanisms of particle formation and growth in the emulsion polymerization initiated by the oil-soluble initiator, 2,2′-azobisisobutyronitrile. ACS Symp Ser 492 (1992) 55-71
11. Nomura M., Ikoma J., and Fujita K. Kinetics and mechanisms of emulsion polymerization initiated by oil-soluble initiators. Kinetic modeling of unseeded emulsion polymerization of styrene initiated by 2,2′-azobisisobutyronitrile. J Polym Sci Part A: Polym Chem 31 (1993) 2103-2113
12. Luo Y., and Schork F.J. Emulsion and miniemulsion polymerizations with and oil-soluble initiator in the presence and absence of an aqueous-phase radical scavenger. J Polym Sci Polym Chem 40 (2002) 3200-3211
13. Herrera-Ordonez J., Olayo R., and Carro S. The kinetics of emulsion polymerization: some controversial aspects. J Macromol Sci Part C - Polym Revs C44 3 (2004) 207-229
14. Dunn A.S. Rate of emulsifier adsorption as a factor in the nucleation of polymer latex particles. ACS Symp Ser 492 (1992) 45-54
15. Varela de la Rosa L., Sudol E.D., El-Aasser M.S., and Klein A. Emulsion polymerization of styrene using reaction calorimeter. I. Above and below critical micelle concentration. J Polym Sci Part A: Polym Chem 37 (1999) 4054-4055
16. Miller C.M., Clay P.A., Gilbert R.G., and El-Aasser M.S. An Experimental Investigation on the Evolution of the molecular weight distribution in styrene emulsion polymerization. J Polym Sci A: Polym Chem 35 (1997) 989-1006
17. Nomura M., Harada M., and Eguchi W. Effect of stirring on the emulsion polymerization of styrene. J Appl Polym Sci 16 (1972) 835-847
18. Leemans L., Jerome R., and Teyssie P. Diffusive radical entry as the rate-determining step in amphiphilic block polyelectrolyte mediated emulsion polymerization. Macromolecules 31 (1998) 5565-5571
19. Capek I. Sterically and electrosterically stabilized emulsion polymerization. Kinetics and preparation. Adv Colloid Int Sci 99 (2002) 77-162
20. Thickett S.C., and Gilbert R.G. Mechanism of radical entry in electrosterically stabilized emulsion polymerization systems. Macromolecules 39 (2006) 6495-6504
21. Herrera-Ordonez J., Rivera O., Maldonado-Textle H., and Ramirez J.C. Kinetics of styrene emulsion polimerization above the critical Michelle concentration: effect of the initial monomer concentration on the molecular weight. J Polym Sci Polym Chem 43 (2005) 1963-1972