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A similar reaction was conducted with rubidium metal. Only a small amount (ca. 10% yield) of a product whose NMR spectra were consistent with the formula Rb[A'](thf) could be isolated, however. The product could not be obtained in a form suitable for single-crystal X-ray diffraction and was not further studied.
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A similar reaction was conducted with rubidium metal. Only a small amount (ca. 10% yield) of a product whose NMR spectra were consistent with the formula Rb[A'](thf) could be isolated, however. The product could not be obtained in a form suitable for single-crystal X-ray diffraction and was not further studied.
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34548169245
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Crystals of K[A′](thf)3/2 are orthorhombic, space group Pna21, with a, 23.151(2) Å, b, 11.0862(9) Å c, 16.9491(14) Å, V, 4350.1(6) Å3, Z, 4, and ρcalc, 1.016 g cm-3 for fw, 665.39. Refinement of 7483 reflections collected at 173 K with Mo Kα radiation led to residuals of R(F2, 0.0559 and Rw(F2, 0.1054 all data
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2) = 0.1054 (all data).
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34548147389
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2) = 0.1198 (all data).
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