메뉴 건너뛰기




Volumn 26, Issue 17, 2007, Pages 4354-4356

Trimethylsilylated allyl complexes of the heavy alkali metals, M[1,3-(SiMe3)2C3H3](thf) n (M = K, Cs)

Author keywords

[No Author keywords available]

Indexed keywords

CESIUM COMPOUNDS; DERIVATIVES; METAL COMPLEXES; POLYMERIZATION; SOLID STATE REACTIONS; SUBSTITUTION REACTIONS;

EID: 34548164154     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700410a     Document Type: Article
Times cited : (27)

References (29)
  • 16
    • 34548150350 scopus 로고    scopus 로고
    • A similar reaction was conducted with rubidium metal. Only a small amount (ca. 10% yield) of a product whose NMR spectra were consistent with the formula Rb[A'](thf) could be isolated, however. The product could not be obtained in a form suitable for single-crystal X-ray diffraction and was not further studied.
    • A similar reaction was conducted with rubidium metal. Only a small amount (ca. 10% yield) of a product whose NMR spectra were consistent with the formula Rb[A'](thf) could be isolated, however. The product could not be obtained in a form suitable for single-crystal X-ray diffraction and was not further studied.
  • 22
    • 34548169245 scopus 로고    scopus 로고
    • Crystals of K[A′](thf)3/2 are orthorhombic, space group Pna21, with a, 23.151(2) Å, b, 11.0862(9) Å c, 16.9491(14) Å, V, 4350.1(6) Å3, Z, 4, and ρcalc, 1.016 g cm-3 for fw, 665.39. Refinement of 7483 reflections collected at 173 K with Mo Kα radiation led to residuals of R(F2, 0.0559 and Rw(F2, 0.1054 all data
    • 2) = 0.1054 (all data).
  • 24
    • 34548147389 scopus 로고    scopus 로고
    • 2) = 0.1198 (all data).
    • 2) = 0.1198 (all data).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.