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This notation refers to a molecule-He dimer, where b-type transitions correspond to molecular rotations, and a-type transitions to end-over-end motion of the He relative to the molecule. In clusters, for a given total angular momentum J, the molecular rotations can be accessed by the molecular correlation function SJ(τ) and the end-over-end motion by a correlation function of collective helium coordinates, FJ(τ, ∑m ∑i,j〈Y *Jm(Ωi(τ))YJm(Ω j(τ))〉 where Qi is the orientation of atom i relative to the molecule.23
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