A single-event microkinetic analysis of the catalytic cracking of (cyclo)alkanes on an equilibrium catalyst in the absence of coke formation

Chemical Engineering Science

Volumn 62, Issue 18-20, 2007, Pages 5033-5038

  Quintana Solorzano R ^a   Thybaut, J W ^a   Marin, G B ^a  

^a GHENT UNIVERSITY   (Belgium)

Author keywords

(Cyclo)alkanes; Alkenes; Carbenium ions; Catalytic cracking; Microkinetics; Single events

Indexed keywords

COKE FORMATION; EQUILIBRIUM CATALYST; HYDRIDE TRANSFER; MICROKINETIC ANALYSIS; MICROKINETICS;

CATALYSTS; COMPUTER SIMULATION; KINETIC PARAMETERS; OLEFINS; THERMAL EFFECTS;

CATALYTIC CRACKING;

CATALYSTS; CATALYTIC CRACKING; COMPUTER SIMULATION; KINETIC PARAMETERS; OLEFINS; THERMAL EFFECTS;

EID: 34547945234     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2007.01.008     Document Type: Article

References (13)

1. Baltanás M.A., Van Raemdonck K.K., Froment G.F., and Mohedas S.R. Fundamental kinetic modeling of hydroisomerization and hydrocracking of noble-metal-loaded faujasites. 1. Rate parameters for hydroisomerization. Industrial and Engineering Chemistry Research 28 (1989) 899
2. Christensen G., Apelian M.R., Hickey K.J., and Jaffe S.B. Future directions in modeling the FCC process: an emphasis on product quality. Chemical Engineering Science 54 (1999) 2753
3. Dewachtere N.V., Santaella F., and Froment G.F. Application of a single-event kinetic model in the simulation of an industrial riser reactor for the catalytic cracking of a vacuum gas oil. Chemical Engineering Science 54 (1999) 3653
4. Froment G.F. Single event kinetic modeling of complex catalytic processes. Catalysis Reviews 47 (2005) 83
5. Leuenberg, E., Wilbert, L.L., 1987. Octane Catalyst Effects on the FCCU: heat balance. NPRA Annual Meeting, San Antonio, TX, USA.
6. Marquardt D.W. An algorithm for least-squares estimation of non-linear parameters. Industrial Applied Mathematics 11 (1963) 431
7. Martens G.G., Thybaut J.W., and Marin G.B. Single-event rate parameters for the hydrocracking of cycloalkanes on Pt/US-Y Zeolites. Industrial and Engineering Chemistry Research 40 (2001) 1832
8. Petzold, L.R., Hindmarsh, C., 1997. LSODA solver for ODE equations. 〈http://www.netlib.com〉.
9. Quintana-Solórzano R., Thybaut J.W., and Marin G.B. Catalytic cracking and coking of (cyclo)alkane/1-octene mixtures on an equilibrium catalyst. Applied Catalysis A: General 314 (2006) 184
10. Thybaut J.W., Marin G.B., Baron G.V., Jacobs P.A., and Martens J.A. Alkene protonation enthalpy determination from fundamental kinetic modeling of alkane hydroconversion on Pt/H-(US)Y-Zeolite. Journal of Catalysis 202 (2001) 324-339
11. Thybaut J.W., Laxminarasimahn C.S., Marin G.B., Denayer J.F.M., Baron G.V., Jacobs P.A., and Martens J.A. Alkylcarbenium ion concentrations in zeolite pores during octane hydrocracking on Pt/HUSY zeolite. Catalysis Letters 94 1-2 (2004) 81
12. Watson B.A., Klein M., and Harding R.H. Mechanistic modeling of n-heptane cracking on HZSM-5. Industrial and Engineering Chemistry Research 35 (1996) 1506
13. Yaluris G., Madon R.J., Rudd D.F., and Dumesic J.A. Catalytic cycles and selectivity of hydrocarbon cracking on Y-zeolite based catalyst. Industrial and Engineering Chemistry Research 33 (1994) 2903