Modelling of the kinetics of the supercritical CO2 assisted grafting of maleic anhydride onto isotactic polypropylene in the solid state

Chemical Engineering Science

Volumn 62, Issue 18-20, 2007, Pages 5290-5294

  Tong, Gang Sheng ^a   Liu, Tao ^a   Hu, Guo Hua ^b,c   Hoppe, Sandrine ^b   Zhao, Ling ^a   Yuan, Wei Kang ^a  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b UNIVERSITÉ DE LORRAINE   (France)

^c INSTITUT UNIVERSITAIRE DE FRANCE   (France)

Author keywords

Kinetics; Maleic anhydride; Mathematical modelling; Polypropylene; Supercritical fluids

Indexed keywords

GRAFTING REACTION; ISOTACTIC POLYPROPYLENE; KINETIC MODEL;

CARBON DIOXIDE; DECOMPOSITION; DIFFUSION; GRAFTING (CHEMICAL); MALEIC ANHYDRIDE; MATHEMATICAL MODELS; POLYPROPYLENES; REACTION KINETICS;

SUPERCRITICAL FLUIDS;

CARBON DIOXIDE; DECOMPOSITION; DIFFUSION; GRAFTING (CHEMICAL); MALEIC ANHYDRIDE; MATHEMATICAL MODELS; POLYPROPYLENES; REACTION KINETICS; SUPERCRITICAL FLUIDS;

EID: 34547940449     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2006.12.037     Document Type: Article

References (11)

1. Brandrup J., and Immergut E.H. Polymer Handbook. third ed. (1989), Wiley, New York pp. II-29, II-80
2. Guan, Zh.B., DeSimone, J.M., 1992. Kinetic investigation of the thermal decomposition of AIBN in supercritical carbon dioxide. Polymer preprints, vol. 33(2). Division of Polymer Chemistry American Chemical Society, pp. 172-173.
3. ′-azobis (isobutyronitrile). Macromolecules 26 (1993) 2663-2669
4. Hu G.H., Flat J.J., and Lambla M. Exchange and free radical grafting reactions in reactive extrusion. Makromolekulare Chemie. Macromolecular Symposia 75 (1993) 137-157
5. Liu T., Hu G.H., Tong G.Sh., Zhao L., Cao G.P., and Yuan W.K. Supercritical carbon dioxide assisted solid-state grafting process of maleic anhydride onto polypropylene. Industrial and Engineering Chemistry Research 44 (2005) 4292-4299
6. Moad G. Synthesis of polyolefin graft copolymers by reactive extrusion. Progress in Polymer Science 24 (1999) 81-142
7. Rätzsch M., Arnold M., Borsig E., Bucka H., and Reichelt N. Radical reaction on polypropylene in the solid state. Progress in Polymer Science 27 (2002) 1195-1282
8. Roover B.De., Sclavons M., Carlier V., Devaux J., Legras R., and Momtaz A. Molecular characterization of maleic anhydride-functionalized polypropylene. Journal of Polymer Science Part A: Polymer Chemistry 33 5 (1995) 829-842
9. Severini F., Pegoraro M., Yuana L., Riccab G., and Fantic N. Free radical grafting of maleic anhydride in vapour phase on polypropylene film. Polymer 40 (1999) 7059-7064
10. Shi D., Yang J., Yao Zh., Wang Y., Huang H., Jing W., Yin J., and Costa G. Functionalisation of isotactic polypropylene with maleic anhydride by reactive extrusion: mechanism of melt grafting. Polymer 42 (2001) 5549-5557
11. 2. Studies in Surface Science and Catalysis 159 (2006) 673-676