Synthesis of chain-end functionalized polyolefins with a bis(phenoxy imine) titanium catalyst

Macromolecular Rapid Communications

Volumn 28, Issue 6, 2007, Pages 698-703

  Makio, Haruyuki ^a   Fujita, Terunori ^a  

^a MITSUI CHEMICALS INC   (Japan)

Author keywords

FI catalysts; Functionalization of polymers; Phenoxyimine ligand; Polyolefins; Telechelics

Indexed keywords

CATALYSTS; ETHYLENE; INITIATORS (CHEMICAL); LIVING POLYMERIZATION; PROPYLENE; SYNTHESIS (CHEMICAL); TITANIUM;

CATIONIC SPECIES; HYDROXYL GROUPS; PHENOXYIMINE LIGANDS; TELECHELICS;

POLYOLEFINS;

EID: 34547867779     PISSN: 10221336     EISSN: 15213927     Source Type: Journal    
DOI: 10.1002/marc.200600853     Document Type: Article

References (27)

1. E. J. Goethals, "Telechelic Polymers: Synthesis and Applications", CRC Press, Boca Raton 1989, and references therein.
2. For radical polymerisation, see: [2a] M. Kamigaito, T. Ando, M. Sawamoto, Chem. Rev. 2001, 101, 3689;
3. [2b] C. J. Hawker, A. W. Bosman, E. Harth, Chem. Rev. 2001, 101, 3661;
4. [2c] A. A. Gridnev, S. D. Ittel, Chem. Rev. 2001, 101, 3611;
5. [2d] For ionic polymerisation R. N. Young, R. P. Quirk, L. Fetters, J. Adv. Polym. Sci. 1984, 56, 1.
6. [2e] K. Matyjaszewski, "Cationic Polymerizations: Mechanisms, Synthesis, and Applications (Plastics Engineering 35)", Marcel Dekker, New York 1996;
7. [2f] M. Szwarc, "Ionic Polymerization Fundamentals", Hanser Gardner, New York 1996.
8. [3a] T. Sawaguchi, Y. Suzuki, A. Sakaki, H. Saito, S. Yano, M. Seno, Polym. Int. 2000, 49, 921;
9. [3b] T. Sawaguchi, T. Ikemura, M. Seno, Macromolecules 1995, 28, 7973;
10. [3c] T. Shiono, N. Naga, K. Soga, Macromol. Chem. Rapid Commun. 993, 14, 323;
11. [3d] T. Ishihara, T. Shiono, Macromolecules 2003, 36, 9675;
12. [3e] T. Shiono, H. Kurosawa, K. Soga, Macromolecules 1995, 28, 437.
13. [4a] A. C. Gottfried, M. Brookhart, Macromolecules 2003, 36, 3085;
14. [4b] M. Murata, Y. Fukui, K. Soga, Macromol. Rapid Commun. 1998, 19, 267.
15. [5a] For reviews: H. Makio, N. Kashiwa, T. Fujita, Adv. Synth. Catal. 2002, 344, 477;
16. [5b] M. Mitani, T. Nakano, T. Fujita, Chem. Eur. J. 2003, 9, 2396;
17. [5c] M. Mitani, J. Saito, S. Ishii, Y. Nakayama, H. Makio, N. Matsukawa, S. Matsui, J. Mohri, R. Furuyama, H. Terao, H. Bando, H. Tanaka, T. Fujita, Chem. Rec. 2004, 4, 137;
18. [5d] H. Makio, T. Fujita, Bull. Chem. Soc. Jpn. 2005, 78, 52;
19. [5e] R. Furuyama, J. Saito, S. Ishii, H. Makio, M. Mitani, H. Tanaka, T. Fujita, J. Organomet. Chem. 2005, 690, 4398.
20. M. Mitani, J. Mohri, Y. Yoshida, J. Saito, S. Ishii, K. Tsuru, S. Matsui, R. Furuyama, T. Nakano, H. Tanaka, S. Kojoh, T. Matsugi, N. Kashiwa, T. Fujita, J. Am. Chem. Soc. 2002, 124, 3327.
21. H. Makio, T. Oshiki, K. Takai, T. Fujita, Chem. Lett. 2005, 34, 1382.
22. H. Makio, T. Fujita, Macromol. Symp. 2004, 213, 221.
23. [9a] J. Saito, M. Mitani, M. Onda, J. Mohri, S. Ishii, Y. Yoshida, T. Nakano, H. Tanaka, T. Matsugi, S. Kojoh, N. Kashiwa, T. Fujita, Macromol. Rapid Commun. 2001, 22, 1072;
24. [9b] M. Lamberti, D. Pappalardo, A. Zambelli, C. Pellecchia, Macromolecules 2002, 35, 658;
25. [9c] P. D. Hustad, J. Tian, G. W. Coates, J. Am. Chem. Soc. 2002, 124, 3614;
26. [9d] G. Talarico, V. Busico, L. Cavallo, L. Am. Chem. Soc. 2003, 125, 7172.
27. Under the conditions (Tp: 0 °C), peak melting temperatures of the syndiotactic poly (propylene) s prepared by this catalyst are in the range of 143-146 °C. M. Mitani, R. Furuyama, J. Mohri, J. Saito, S. Ishii, H. Terao, T. Nakano, H. Tanaka, T. Fujita, J. Am. Chem. Soc. 2003, 125, 4293.