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Volumn 11, Issue 4, 2007, Pages 762-765

Execution of a performic acid oxidation on multikilogram scale

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EID: 34547856209     PISSN: 10836160     EISSN: None     Source Type: Journal    
DOI: 10.1021/op700039r     Document Type: Article
Times cited : (11)

References (15)
  • 2
    • 33947466935 scopus 로고    scopus 로고
    • Oxidation of thioacetates to sulfonic acids: Koenig, N. H.; Swern, D. J. Am. Chem. Soc. 1957, 79, 4235.
    • Oxidation of thioacetates to sulfonic acids: Koenig, N. H.; Swern, D. J. Am. Chem. Soc. 1957, 79, 4235.
  • 3
    • 34547877768 scopus 로고    scopus 로고
    • Residual metals in the activated carbon are postulated to be the active catalyst in this reaction, No lot-to-lot variability was observed in the effectiveness of the quench, either between different lots of the same grade of carbon, or other types of carbon KBB was also tried, Each lot was use-tested prior to use on scale
    • Residual metals in the activated carbon are postulated to be the active catalyst in this reaction, No lot-to-lot variability was observed in the effectiveness of the quench, either between different lots of the same grade of carbon, or other types of carbon (KBB was also tried). Each lot was use-tested prior to use on scale.
  • 4
    • 33947459206 scopus 로고
    • For a review of organic peracids see
    • For a review of organic peracids see: Swern, D. Chem. Rev. 1949, 45, 1.
    • (1949) Chem. Rev , vol.45 , pp. 1
    • Swern, D.1
  • 5
    • 34547865879 scopus 로고    scopus 로고
    • Experiment was carried out using a titanium bomb and a φ-factor of 1.69. A corrected onset of -1 °C was observed when the experiment was repeated in a glass bomb with a metal stem and a φ-factor of 3.62.
    • Experiment was carried out using a titanium bomb and a φ-factor of 1.69. A corrected onset of -1 °C was observed when the experiment was repeated in a glass bomb with a metal stem and a φ-factor of 3.62.
  • 6
    • 34547907925 scopus 로고    scopus 로고
    • Experiment was carried out using a titanium bomb and a φ-factor of 2.42. A corrected onset of 41 °C was observed when the experiment was repeated in a glass bomb with a metal stem and a φ-factor of 4.43. The MSDS from FMC reports: SADT > 55 φC for a 55-gal drum (35 wt % peracetic acid solution in acetic acid).
    • Experiment was carried out using a titanium bomb and a φ-factor of 2.42. A corrected onset of 41 °C was observed when the experiment was repeated in a glass bomb with a metal stem and a φ-factor of 4.43. The MSDS from FMC reports: SADT > 55 φC for a 55-gal drum (35 wt % peracetic acid solution in acetic acid).
  • 7
    • 34547863293 scopus 로고    scopus 로고
    • This is not a direct comparison since we did not test a 32 wt, solution of performic acid
    • This is not a direct comparison since we did not test a 32 wt % solution of performic acid.
  • 8
    • 34547887417 scopus 로고    scopus 로고
    • When the process was repeated using acetic acid instead of formic acid, no product was observed at the end of the H2O2 addition. These relative rates of peracid formation have been noted in the literature, see ref 4
    • 2 addition. These relative rates of peracid formation have been noted in the literature, see ref 4.
  • 9
    • 34547880172 scopus 로고    scopus 로고
    • Brethericks Handbook of Reactive Chemical Hazards
    • Urben, P.G, Ed, 6th ed, MA
    • Urben, P.G., Ed. Brethericks Handbook of Reactive Chemical Hazards, 6th ed.; Butterworth-Heinemann: Wobum, MA, 1999; p 1627.
    • (1999) Butterworth-Heinemann: Wobum , pp. 1627
  • 10
    • 34547872136 scopus 로고    scopus 로고
    • Integration was performed on a curve plotted as W versus seconds
    • Integration was performed on a curve plotted as W versus seconds.
  • 11
    • 34547876629 scopus 로고    scopus 로고
    • 2 were added in the RC1 experiment.
    • 2 were added in the RC1 experiment.
  • 12
    • 34547911931 scopus 로고    scopus 로고
    • The limiting oxygen concentration of 96 wt % formic acid was determined to be 7.26-7.72% by Chilworth Technology.
    • The limiting oxygen concentration of 96 wt % formic acid was determined to be 7.26-7.72% by Chilworth Technology.
  • 13
    • 34547924615 scopus 로고    scopus 로고
    • For details on formic acid, see
    • (a) For details on formic acid, see: http://www.basf.com.
  • 14
    • 34547865166 scopus 로고    scopus 로고
    • Reference 9, p 163
    • (b) Reference 9, p 163.
  • 15
    • 34547914274 scopus 로고    scopus 로고
    • The process as performed on scale used 7.2 of 96 wt % formic acid instead of 2.5 as in the RC1 run.
    • The process as performed on scale used 7.2 volumes of 96 wt % formic acid instead of 2.5 volumes as in the RC1 run.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.