-
1
-
-
34547896644
-
-
for a full synthetic report, see
-
for a full synthetic report, see: Belecki, K.; Berliner, M.; Bibart, R. T.: Meltz, C.; Ng, K.; Phillips, J.; Brown Ripin D. H. Org. Process Res. Dev. 2007, 11, 754-761.
-
(2007)
Org. Process Res. Dev
, vol.11
, pp. 754-761
-
-
Belecki, K.1
Berliner, M.2
Bibart, R.T.3
Meltz, C.4
Ng, K.5
Phillips, J.6
Brown Ripin, D.H.7
-
2
-
-
33947466935
-
-
Oxidation of thioacetates to sulfonic acids: Koenig, N. H.; Swern, D. J. Am. Chem. Soc. 1957, 79, 4235.
-
Oxidation of thioacetates to sulfonic acids: Koenig, N. H.; Swern, D. J. Am. Chem. Soc. 1957, 79, 4235.
-
-
-
-
3
-
-
34547877768
-
-
Residual metals in the activated carbon are postulated to be the active catalyst in this reaction, No lot-to-lot variability was observed in the effectiveness of the quench, either between different lots of the same grade of carbon, or other types of carbon KBB was also tried, Each lot was use-tested prior to use on scale
-
Residual metals in the activated carbon are postulated to be the active catalyst in this reaction, No lot-to-lot variability was observed in the effectiveness of the quench, either between different lots of the same grade of carbon, or other types of carbon (KBB was also tried). Each lot was use-tested prior to use on scale.
-
-
-
-
4
-
-
33947459206
-
-
For a review of organic peracids see
-
For a review of organic peracids see: Swern, D. Chem. Rev. 1949, 45, 1.
-
(1949)
Chem. Rev
, vol.45
, pp. 1
-
-
Swern, D.1
-
5
-
-
34547865879
-
-
Experiment was carried out using a titanium bomb and a φ-factor of 1.69. A corrected onset of -1 °C was observed when the experiment was repeated in a glass bomb with a metal stem and a φ-factor of 3.62.
-
Experiment was carried out using a titanium bomb and a φ-factor of 1.69. A corrected onset of -1 °C was observed when the experiment was repeated in a glass bomb with a metal stem and a φ-factor of 3.62.
-
-
-
-
6
-
-
34547907925
-
-
Experiment was carried out using a titanium bomb and a φ-factor of 2.42. A corrected onset of 41 °C was observed when the experiment was repeated in a glass bomb with a metal stem and a φ-factor of 4.43. The MSDS from FMC reports: SADT > 55 φC for a 55-gal drum (35 wt % peracetic acid solution in acetic acid).
-
Experiment was carried out using a titanium bomb and a φ-factor of 2.42. A corrected onset of 41 °C was observed when the experiment was repeated in a glass bomb with a metal stem and a φ-factor of 4.43. The MSDS from FMC reports: SADT > 55 φC for a 55-gal drum (35 wt % peracetic acid solution in acetic acid).
-
-
-
-
7
-
-
34547863293
-
-
This is not a direct comparison since we did not test a 32 wt, solution of performic acid
-
This is not a direct comparison since we did not test a 32 wt % solution of performic acid.
-
-
-
-
8
-
-
34547887417
-
-
When the process was repeated using acetic acid instead of formic acid, no product was observed at the end of the H2O2 addition. These relative rates of peracid formation have been noted in the literature, see ref 4
-
2 addition. These relative rates of peracid formation have been noted in the literature, see ref 4.
-
-
-
-
9
-
-
34547880172
-
Brethericks Handbook of Reactive Chemical Hazards
-
Urben, P.G, Ed, 6th ed, MA
-
Urben, P.G., Ed. Brethericks Handbook of Reactive Chemical Hazards, 6th ed.; Butterworth-Heinemann: Wobum, MA, 1999; p 1627.
-
(1999)
Butterworth-Heinemann: Wobum
, pp. 1627
-
-
-
10
-
-
34547872136
-
-
Integration was performed on a curve plotted as W versus seconds
-
Integration was performed on a curve plotted as W versus seconds.
-
-
-
-
11
-
-
34547876629
-
-
2 were added in the RC1 experiment.
-
2 were added in the RC1 experiment.
-
-
-
-
12
-
-
34547911931
-
-
The limiting oxygen concentration of 96 wt % formic acid was determined to be 7.26-7.72% by Chilworth Technology.
-
The limiting oxygen concentration of 96 wt % formic acid was determined to be 7.26-7.72% by Chilworth Technology.
-
-
-
-
13
-
-
34547924615
-
-
For details on formic acid, see
-
(a) For details on formic acid, see: http://www.basf.com.
-
-
-
-
14
-
-
34547865166
-
-
Reference 9, p 163
-
(b) Reference 9, p 163.
-
-
-
-
15
-
-
34547914274
-
-
The process as performed on scale used 7.2 of 96 wt % formic acid instead of 2.5 as in the RC1 run.
-
The process as performed on scale used 7.2 volumes of 96 wt % formic acid instead of 2.5 volumes as in the RC1 run.
-
-
-
|