Chapter 4 Methods for the characterisation of porous structure in membrane materials

Membrane Science and Technology

Volumn 4, Issue C, 1996, Pages 67-118

  Julbe, A ^a   Ramsay, J D F ^a  

^a INSTITUT CHARLES GERHARDT   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 34547777560     PISSN: 09275193     EISSN: None     Source Type: Book Series    
DOI: 10.1016/S0927-5193(96)80007-6     Document Type: Article

References (144)

1. Cuperus F.P., and Smolders C.A. Characterization of UF membranes Membrane characteristics and characterization techniques. Adv. Colloid Interface Sci. 34 (1991) 135
2. 14 Sept. Cuperus F.P. Characterization of ultrafiltration membranes. PhD report (1990), Twente University, The Netherlands
3. Mulder M. Characterization of membranes. In: Mulder M. (Ed). Basic Principles of Membrane Technology (1991), Kluwer Academic Publishers, The Netherlands 110-133
4. Hsieh H.P. General characteristics of inorganic membranes. In: Bhave R.R. (Ed). Inorganic Membranes, Synthesis, Characteristics and Applications (1991), Van Nostrand Reinhold, New York, NY 64-94
5. Nakao S.I. Determination of pore size and pore size distribution 3. Filtration mem-branes. J. Membr. Sci. 96 (1994) 131
6. Rouquerol J., Avnir D., Fairbridge C.W., Everett D.H., Haynes J.H., Pernicone N., Ramsay J.D.F., Sing K.S.W., and Unger K.K. Recommendations for the characterisation of porous solids. Pure Appl. Chem. 66 8 (1994) 1739
7. In: Unger K.K., Rouquerol J., Sing K.S.W., and Kral H. (Eds). Characterization of Porous Solids I, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS I) Vol. 39 (1988), Bad Soden, Germany Elsevier
8. In: Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids II, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS II) Vol. 62 (1990), Alicante, Spain Elsevier
9. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1993), Marseille, France Elsevier
10. Sing K.S.W., Everett D.H., Haul R.A.W., Moscou L., Pierotti R.A., Rouquerol J., and Siemieniewska T. Reporting physisorption data for gas/solid systems with special refer-ence to the determination of surface area and porosity. Pure Appl. Chem. 57 (1985) 603
11. Kaneko K. Determination of pore size and pore size distribution 1. Adsorbents and catalysts. J. Membr. Sci. 96 (1994) 59
12. 129Xe NMR Magnetic resonance studies of the porous structure of silica gels. J. Chem. Soc. Faraday Trans. 89 (23 (1993) 4239
13. Dullien F.A. Porous Media, Fluid Transport and Pore Structure (1979), Academic Press, London
14. Adler P.M. Porous Media. Series in Chemical Engineering (1992), Butterworth-Heineman, Boston, MA
15. Shelekin A.B., Dixon A.G., and Ma Y.H. Adsorption diffusion and permeation of gases in microporous membranes III. Application of percolation theory to interpretation of porosity tortuosity and surface area in microporous glass membranes. J. Membr. Sci. 83 (1993) 181
16. Satterfield C.N., and Sherwood T.K. The Role of Diffusion in Catalysis (1963), Addison-Wesley Publishing Company, Inc., Reading, MA
17. Seaton N.A. Determination of the connectivity of porous solids from nitrogen sorption measurements. Chem. Eng. Sci. 46 8 (1991) 1895
18. May. Liu H., Zhang L., and Seaton N.A. Characterisation of mesoporous solids using sorption hysteresis measurements. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1993), Marseille, France 129-140 Elsevier
19. Stauffer D. Introduction to Percolation Theory (1985), Taylor & Francis, London
20. Ser. C. Neimark A.V. New theoretical approaches to characterisation of mesoporous solids. In: Sequeira C.A.C., and Hudson M.J. (Eds). Multifunctional Mesoporous Inorganic Solids, NATO Asi Ser. Vol. 400 (1993), Kluwer, The Netherlands 27-35
21. Lim J.H.F., Jia X., Jafferali R., and Davies G.A. Statistical models to describe the structure of porous ceramic membranes. Sep. Sci. Technol. 28 1-3 (1993) 821
22. Tsetsekou A., and Androutsopoulos G. Mercury porosimetry hysteresis and entrap-ment predictions based on a corrugated random pore model. Chem. Eng. Comm. 110 (1991) 1
23. in press. Tsotsis T.T., Sahimi M., and Gavalas G. Membrane and Membrane Processes. Statistical Modeling of Fluid Solid Reaction Systems (1997), Oxford Press
24. Pennycook J.S. Powerful new analytical technique directly images a material's atomic structure and composition. Materials & Processing report 6 1 (1991) 1
25. Diff. CRAM-LPSES-CNRS. Humbert A. La microscopie par effet Tunnel. In: Ammou M. (Ed). Microcaractéri- sation des solides (1989), Sophia-Antipolis-Valbonne, France 253-289
26. Bessiere A., Meireles M., Aimar P., Sanchez V., Coratger R., and Beauvillain J. Surface analysis of ultrafiltration membranes by atomic force microscopy. In: Aimar P., and Aptel P. (Eds). Proc. Euromembrane 92 Vol. 6 (1992), Récents Progrès en Génie des Procédés, Paris 111-116 22
27. Fitzche A.K., Arevalo A.R., Moore M.D., and O'Hara C. The surface structure and morphology of polyacrylonitrile membranes by atomic force microscopy. J. Membr. Sci. 81 (1993) 109
28. Bottino A., Capannelli G., Grosso A., Monticelli O., Cavalleri O., Rolandi R., and Soria R. Surface characterization of ceramic membranes by atomic force microscopy. J. Membr. Sci. 95 (1994) 289
29. Fonseca R.J.M.D., Saurel J.M., Foucaran A., Massone E., Taliercio T., and Camassel J. Acoustic microscopy investigation of porous silicon. Thin Solid Films 255 (1995) 155
30. Microscopies. J. CNRS (Meudon-France) 65 (1995) 11
31. Scott E.R., and White H.S. Scanning electrochemical microscopy of a porous membrane. J. Membr. Sci. 58 (1991) 71
32. Kim K.J., Stevens P.V., and Fane A.G. Porosity dependence of pore entry shape in track-etched membranes by image analysis. J. Membrane Sci. 93 (1994) 79
33. Zeman L., and Denault L. Characterization of microfiltration membranes by image analysis of electron micrographs Part I. Method develoment. J. Membr. Sci. 71 (1992) 221
34. Zeman L. Characterization of microfiltration membranes by image analysis of electron micrographs Part II. Functional and morphological parameters. J. Membr. Sci. 71 (1992) 233
35. Vivier H., Pons M.N., and Portala J.F. Study of microporous membrane structure by image analysis. J. Membr. Sci. 46 (1989) 81
36. 2-91 (1991), Key Engineering Materials 61 & 62, Trans Tech Pub. Zurich 83-88
37. May. McEnaney B., and Mays T.J. Characterization of macropores using quantitative micros- copy. 1994. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1993), Marseille, France 327-338 Elsevier
38. May. Ewing B., Davis P.J., Majors P.D., Drobny G., Smith M., and Earl W.L. Determination of spatially resolved pore size information. 1991. In: Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids II, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS II) Vol. 62 (1990), Alicante, Spain 709-715 Elsevier
39. Guillot G., Kassab G., Hulin J.P., and Rigord P. Monitoring of tracer dispersion in porous media by NMR imaging. J. Phys. D: Appl. Phys. 24 (1991) 763
40. Rocek J., and Uchytil P. Evaluation of selected methods for the characterisation of ceramic membranes. J. Membr. Sci. 89 (1994) 119
41. Lowell S., and Shields J.E. Powder Surface Area and Porosity. 2nd edn. (1984), Powder Technology Series, Chapman & Hall, London
42. Gregg S.J., and Sing K.S.W. Adsorption, Surface Area and Porosity (1982), Academic Press, London
43. Frye G.C., Ricco A.J., Martin S.J., and Brinker C.J. Characterization of the surface area and porosity of sol-gel films using SAW devices. Mater. Res. Soc Symp. Proc. 121 (1988) 349
44. Hietala S.L., Smith D.M., Hietala V.M., Frye G.C., and Martin S.J. Pore structure characterization of thin films using a surface acoustic wave/volumetric adsorption technique. Langmuir 9 (1993) 249
45. Avery R.G., and Ramsay J.D.F. The sorption of nitrogen in porous compacts of silica and zirconia powders. J. Colloid Interface Sci. 42 (1973) 597
46. 1994. Lastoskie C., Gubbins K.E., and Quirke N. Pore size distribution analysis and network- ing: studies of microporous sorbents. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Marseille, France, May. Proc. of the IUPAC Symposium (COPS III), Vol. 87 (1993), Elsevier, Amsterdam 51-60
47. Marseille, France, May. Kaneko K., Ishii C., and Rybolt T. Superhigh surface area determination of microporous carbons. 1994. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1993), Elsevier, Amster- dam 583-592
48. Ramsay J.D.F. Nitrogen adsorption in microporous silica compacts. J. Collloid Interface Sci. 51 (1975) 205
49. Sing K.S.W. Utilization of adsorption data in the BET region. In: Everett D.H., and Ottewill R.H. (Eds). Surface Area Determination (1970), Butterworths, London 25-42
50. Gregg S.J., and Langford J.F. Evaluation of microporosity with special reference to a carbon black. Trans. Faraday Soc 65 (1969) 1394
51. Dubinin M.M. The potential theory of adsortion of gases and vapors for adsorbents with energitically nonuniform surfaces. Chem. Rev. 60 (1960) 235
52. Dubinin M.M. Physical adsorption of gases and vapors in micropores. In: Cahen- head D.A. (Ed). Progress in Surface and Membrane Sience Vol. 9 (1975), Academic Press, New York, NY 1-70
53. Mikhail R.S., Brunauer S., and Bodor E.E. Investigations of a complete pore structure analysis. I. Analysis of micropores. J. Colloid Interface Sci. 26 1 (1968) 45
54. Horvath G., and Kawazoe K. Method for calculation of effective pore size distribution in molecular sieve carbon. J. Chem. Eng. Jpn. 16 (1983) 470
55. Saito A., and Foley H.C. Curvature^and parametric sensitivity in models for adsorption in micropores. AIChE J 37 (1991) 429
56. 1994. Olivier J.P., Conklin W.B., and Szombathely M.V. Determination of pore size distribu- tion from density functional theory: a comparison of nitrogen and argon results. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Marseille, France, May. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1993), Elsevier, Amsterdam 81-90
57. Bojan M.J., and Steele W. Simulation of sorption in pores with constrictions. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Marseille, France, May 1993. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1994), Elsevier, Amsterdam 11-20
58. Marseille, France, May 1993. Molina-Sabio M., Rodriguez-Reinoso F., Valladares D., and Zgrablich G. A lattice-gas model for adsorption in microporous solids. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1994), Elsevier, Amsterdam 573-582
59. Do D.D., and Do H.D. Characterisation of microporous carbon using sorption data of multiple sorbates at vaious temperature. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Marseille, France, May 1993. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1994), Elsevier, Amsterdam 641-650
60. Spencer D.H.T. The use of molecular probes in the characterization of carbonaceous materials. In: Bond R.L. (Ed). Porous Carbon Solids (1967), Academic Press, New York, NY 87-154
61. Grosgogeat E., Fried J.R., Jenkins R.G., and Hwang S.T. A method for the determination of the pore size distribution of molecular sieve materials and its application to the characterization of partially pyrolyzed polysilastyrene/porous glass composite mem-branes. J. Membr. Sci. 57 (1991) 237
62. Ramsay J.D.F., and Avery R.G. Adsorption in silica compacts containing pores of molecular size. Pore Structure and Properties of Materials, Part I, Proc. Int. Symp. (1973), IUPAC, Academia Prague B37-B45
63. Kresge C.T., Leonowicz M.E., Roth W.J., Vartuli J.C., and Beck J.S. Ordered mesoporous molecular sieve synthesized by a liquid-crystal template mechanism. Nature 359 (1992) 710
64. Dabadie T., Ayral A., Guizard C., Cot L., Robert J.C., and Poncelet O. Liquid crystal templating effects on silica gels synthesized using quaternary ammonium surfactants. Mater. Res. Soc. Symp. Proc. 346 (1994) 849
65. Stoekli H.F., and Kraehenbuel F. The external surface of microporous carbons, derived from adsorption and immersion studies. Carbon 22 (1984) 297
66. Brun M., Lallemand A., Quinson J.F., and Eyraud C. A new method for the simultane-ous determination of the size and shape of pores: the thermoporometry. Thermochim. Acta 21 (1977) 59
67. Brun M., Lallemand A., Lorette G., Quinson J.F., Richard M., Eyraud L., and Eyraud C. Changement d'état liquide-solide dans les milieux poreux I. J. Chimie Phys. 6 (1973) 973
68. Brun M., Lallemand A., Quinson J.F., and Eyraud C. Changement d'état liquide-solide dans les milieux poreux II. J. Chimie Phys. (1973) 979
69. Quinson J.F., and Brun M. Progress in thermoporometry. In: Unger K.K., Rouquerol J., Sing K.S.W., and Kral H. (Eds). Characterization of Porous Solids I, Studies in Surface Science and Catalysis. Bad Soden, Germany, April. Proc. of the IUPAC Symposium (COPS I) Vol. 39 (1988), Elsevier, Amsterdam 307-315
70. Jallut C., Lenoir J., Bardot C., and Eyraud C. Thermoporometry. Modelling and simula-tion of a mesoporous solid. J. Membr. Sci. 68 (1992) 271
71. Zeman L., Tkacik G., and le Parlouer P. Characterisation of porous sublayers in UF membranes by thermoporometry. J. Membr. Sci. 32 (1987) 329
72. Kobayashi T., Todoki M., Fujii M., Takeyama T., and Tanzawa H. Permeability and structure of PMMA stereocomplex hollow fiber membrane for hemodialysis. In: Drioli E., and Nakagaki M. (Eds). Proc. Eur.-Jpn Cong. Membr. Membr. Processes (1986), Plenum, New York, NY 507-513
73. Quinson J.F., Mameri N., Guihard L., and Bariou B. The study of the swelling of an ultrafiltration membrane under the influence of solvents by thermoporometry and measurement of permeability. J. Membr. Sci. 58 (1991) 191
74. Bad Soden, Germany, April. Eyraud C., Quinson J.F., and Brun M. The role of thermoporometry in the study of porous solids. In: Unger K.K., Rouquerol J., Sing K.S.W., and Kral H. (Eds). Characterization of Porous Solids I, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS I) Vol. 39 (1988), Elsevier, Amsterdam 295-305
75. Bargeman C.D., and Smolders C.A. Critical points in the analysis of membrane pore structures by thermoporometry. J. Membr. Sci. 66 (1992) 45
76. Marseille, France, May 1993. Earl W.L., Kim Y.W., and Smith D.M. NMR measurement of pore structure. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1994), Elsevier, Amsterdam 301-309
77. Glaves C.L., Davis P.J., Moore K.A., Smith D.M., and Hsieh H.P. Pore structure charac-terization of composite membranes. J. Colloid Interface Sci 133 (2 (1989) 377
78. Glaves C.L., and Smith D.M. Membrane pore structure analysis via NMR-spin-lattice relaxation experiments. J. Membr. Sci. 46 (1989) 167
79. Gallegos D.P., Smith D.M., and Brinker C.J. A NMR technique for the analysis of pore structure: application to mesopores and micropores. J. Colloid Interface Sci. 124 1 (1988) 186
80. Alicante, Spain, May 1990. Smith D.M., and Davis P.J. Pore analysis of wet materials via low-field NMR. In: Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids II, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS II) Vol. 62 (1991), Elsevier, Amsterdam 301-310
81. August 25-30. Smith D.M., Deshpande R., Brinker C.J., Earl W.L., Ewing B., and Davis P.J. In-situ pore structure characterisation during sol-gel synthesis of controlled porosity materials. Proc. Symp. on Catalyst Supports: Chemistry, Forming and Characterization (1991), American Chemical Soc, New York City meeting 489-495
82. 129Xe in the molecu-lar sieve ALPO-11: a dynamic averaging model. J. Phys. Chem. 99 (1995) 619
83. Berlin. Fraissard J., Ito T., and De Ménorval L.C. Nuclear Magnetic Resonance study of Xenon adsorbed on zeolites and metal-zeolites, Application to catalyst research. Proceedings 8th International Conference on Catalysis (1984) 25-35
84. 129Xe NMR spectroscopy. J. Phys. Chem. 93 (1989) 4138
85. Ripmeester J.A., and Davidson D.W. Xe-129 NMR in the clathrate hydrate of xenon. J.Mol. Struct. 75 (1981) 67
86. 2. Microporous and Macroporous Materials. MRS Symp. Proc. Ser. Vol. 431 (1996)
87. Julbe A., Balzer C., Barthez J.M., Guizard C., Larbot A., and Cot L. Effect of non-ionic surface active agents on TEOS derived sols gels and materials. J. Sol-Gel Sci. Technol. 4 (1995) 89
88. Demarquay J., and Fraissard J. Xe-129 NMR of xenon adsorbed on zeolites. Relationship between the chemical shift and the void space. J. Chem. Phys. Lett. 136 (1987) 314
89. Guinier A., and Fournet G. Small Angle Scattering of X-rays (1955), Wiley, New York
90. 2 adsorption isotherms measurements. In: Haynes M.J., and Doria P.R. (Eds). Proc. of RILEM/CNR International Symp. on Principles and Applications of Pore Structural Charac- terisation (1985), J.W. Arrowsmith, Bristol 97-116
91. Ramsay J.D.F. Applications of neutron scattering in investigations of adsorption proc-esses in porous materials. Pure Appl. Chem. 65 (1993) 2164
92. Ramsay J.D.F. Recent developments in the characterization of oxide sols using small angle neutron scattering techniques. Chem. Soc. Rev. 15 (1986) 335
93. Chap. 2. Porod G. General theory. In: Glatter O., and Kratky O. (Eds). Small Angle X-ray Scattering (1982), Academic Press, London 17-51
94. Marseille, France, May 1993. Hua D.W., D'Souza J.V., Schmidt P.W., and Smith D.M. Pore structure analysis via small angle X-ray scattering. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1994), Elsevier, Amsterdam 255-262
95. Marseille, France, May 1993. Ramsay J.D.F. Neutron scattering investigations of adsorption in microporous adsor- bents having controlled pore geometry. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1994), Elsevier, Amsterdam 235-245
96. 6 within the accessible pores. J. Colloid Interface Sci. 142 (1991) 540
97. Alicante, Spain, May 1990. Ramsay J.D.F., and Avery R.G. Neutron scattering investigation of adsorption proc- esses in model porous systems. In: Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids II, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS II) Vol. 62 (1991), Elsevier, Amsterdam 235-244
98. Alicante, Spain, May 1990. Ramsay J.D.F., Russell P.J., and Swanton S.W. Gel precipitated oxide gels with control- led porosity-Determination of structure by small angle neutron scattering and adsorp- tion isotherms measurements. In: Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids II, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS II) Vol. 62 (1991), Elsevier, Amsterdam 257-265
99. Alicante, Spain, May 1990. Dore J.C., and North A.N. Small angle and ultrasmall angle scattering techniques for characterization of porous materials. In: Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids II, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS II) Vol. 62 (1991), Elsevier, Amsterdam 245-255
100. Ramsay J.D.F., and Wing G. Small angle neutron scattering investigations of water sorption in porous silica and ceria gels. J. Colloid Interface Sci. 141 (1991) 475
101. Alicante, Spain, May 1990. Stacey M.H. Evolution of porosity during conversion of η-alumina to a novel porous α-alumina fibre. In: Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids II, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS II) Vol. 62 (1991), Elsevier, Amsterdam 615-624
102. Matsumoto A., Kaneko K., and Ramsay J.D.F. Neutron scattering investigations of the structure and adsorption properties of activated carbon fibers. In: Suzuki M. (Ed). Fundamentals of Adsorption, Studies in Surface Science and Catalysis Vol. 80 (1993), Elsevier, Amsterdam 405-412
103. Rigden J.S., Dore J.C., and North A.N. Determination of anisotropic features in porous materials by small angle X-ray Scattering. In: Rouquerol J., Rodriguez-Reinoso F., Sing K.S.W., and Unger K.K. (Eds). Characterization of Porous Solids III, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS III) Vol. 87 (1994), Elsevier 263-272 Marseille, France, May 1993
104. Auvray L., Ayral A., Dabadie T., Cot L., Guizard C., and Ramsay J.D.F. Sol-gel systems with controlled structure formed in surfactant media. Faraday Discuss. Chem. Soc. 101 (1995) 235
105. Azzam R.M.A., and Bashara N.M. Ellipsometry and Polarized Light (1977), North Holland, Amsterdam
106. Chap. 8. Bohren C.F., and Huffman D.R. Absorption and Scattering of Light by Small Particles (1983), Wiley-Interscience, New York, NY
107. Daugy E., Pointu B., and Villela G. Dépôt par pulvérisation et assistance ionique d'oxydes et d'argent pour réalisation de miroirs métalliques protégés. Le Vide, les Couches Minces 245 (1989) 59
108. July. Sehgal R., Huling J.C., and Brinker C.J. Use of silica sols in inorganic sieving mem- branes. In: Ma Y.H. (Ed). Proc. 3rd International Conference on Inorganic Membranes (1994), Worcester, MA, USA 85-94
109. Gladstone J.H., and Dale T.P. Trans. Roy. Soc. (Lond.) 153 (1964) 317
110. Plinski W.A. Comparison of properties of dielectric films deposited by various meth-ods. J. Vac. Sci. Technol. 14 5 (1977) 1064
111. Amin K.E. Radiograph and ultrasound detect defects early. Am. Ceram. Soc. Bull. 74 1 (1995) 7
112. Kunerth D.C., Telschow K.L., and Walter J.B. Characterization of porosity distributions in advanced ceramics: a comparison of ultrasonic methods. Materials Eval. 47 (1989) 571
113. Huang W., and Rokhlin S.I. Low-frequency normal incidence ultrasonic method for thin layer characterization. Materials Eval. 11 (1993) 1279
114. Fonseca R.J.M.D., Saurel J.M., Foucaran A., Massone E., Taliercio T., and Camassel J. Acoustic microscopy investigation of porous silicon. Thin Solid Films 255 (1995) 155
115. Armitage B.H., Bradey F.P., and Ramsay J.D.F. The measurement of pore size in porous and microporous materials using resonant ion beam backscattering. Nucl. Instrum. Meth. 149 (1978) 329
116. Keddie J.L., and Giannelis E.P. Ion-beam analysis of sol-gel films: structural and com-positional evolution. J. Am. Ceram. Soc. 73 10 (1990) 3106
117. Shaefer H.E., Wurschum R., Birringer R., and Gleiter H. Structure of nanometer-sized polycrystalline iron investigated by positron lifetime spectroscopy. Phys. Rev. B 38 14 (1988) 9545
118. Dolveck J.Y., Dai G.H., Moser P., Pineri M., and Escoubes M. Free volume measurements in polymides by positronium anihilation. Materials Sci. Forum 105-110 (1992) 1549
119. Zerda T.W., Hoang G., Miller B., Quarles C.A., and Orcel G. Positronium decay study of pore sizes in silica sol-gels. Mater. Res. Symp. Proc. 121 (1988) 653
120. Meireles M., Beissieres A., Rogissart I., Aimar P., and Sanchez V. An appropriate molecular size parameter for porous membrane calibration. J. Membr. Sci. 103 1/2 (1995) 105
121. ASTM F 316-86, Standard test method for pore size characterisation of membrane filters by bubble point and mean flow pore test. Annual Book of ASTM Standards Vol. 10.05 (1990)
122. ASTM E1294-89, Standard test method for pore size characteristics of membrane filters using automated liquid porosimeter.
123. ASTM F316 Test method for pore size characteristics of membrane filter for use in aerospace fluids, Annual Book of ASTM Standards, Vol. 11.01.
124. Sneider P., and Uchytil P. Liquid expulsion permporometry for characterization of porous membranes. J. Membr. Sci. 95 (1994) 29
125. Bottino A., Capannelli G., Petit-Bon P., Cao N., Pegoraro M., and Zoia G. Pore size and pore size distribution in microfiltration membranes. Sep. Sci. Technol 26 10/11 (1991) 1315
126. Liu M.G., Ben Aim R., and Peuchot M.M. Characterization of inorganic mem- branes by permporometry method: importance of non equilibrium phenomena. In: Burggraaf A.J., Charpin J., and Cot L. (Eds). Inorganic Membranes (1991), Key Engineering Materials 61 & 62, Trans Tech Publications, Zurich 603-605
127. Bad Soden, Germany, April. Capannelli G., Becchi I., Bottino A., Moretti P., and Munari S. Computer driven poro- simeter for ultrafiltration membranes. In: Unger K.K., Rouquerol J., Sing K.S.W., and Kral H. (Eds). Characterization of Porous Solids I, Studies in Surface Science and Catalysis. Proc. of the IUPAC Symposium (COPS I) Vol. 39 (1988), Elsevier, Amsterdam 283-294
128. Munari S., Bottino A., Moretti P., Capannelli G., and Becchi I. Permporometric study on ultrafiltration membranes. J. Membr. Sci. 41 (1989) 69
129. Munari S., Bottino A., Capannelli G., and Moretti P. Membrane morphology and transport properties. Desalination 53 (1985) 11
130. Petropoulos J.H., and Petrou J.K. Structural characterization of porous solids. Sep. Technol. 2 10 (1992) 162
131. Leenaars A.F.M., and Burggraaf A.J. The preparation and characterization of alumina membranes with ultra-fine pores: Part 3. The permeability for pure liquids. J. Membr. Sci. 24 (1985) 245
132. Paris, p-1050-1. Charpin J., and Rasneur B. Caracterisation de la texture poreuse des matériaux. In: de lTngénieur T. (Ed). Caractérisation (1987)
133. Schofield R.W., Fane A.G., and Fell C.J.D. Gas and vapour transport through micropor-ous membranes. I. Knudsen-Poiseuille transition. J. Membr. Sci. 53 (1990) 159
134. Altena F.W., Knoef H.A.M., Heskamp H., Bargeman D., and Smolders C.A. Some comments on the applicability of gas permeation methods to characterise porous membranes based on improved experimental accuracy and data handling. J. Membr. Sci. 12 (1983) 313
135. Uchytil P. Gas permeation in ceramic membranes. Part I. Theory and testing of ceramic membranes. J. Membr. Sci. 97 (1994) 139
136. Uchytil P., and Broz Z. Gas permeation in ceramic membranes. Part II. Modeling of gas permeation through ceramic membranes with one separation layer. J. Membr. Sci. 97 (1994) 145
137. Uchytil P., Wagner Z., Rocek J., and Broz Z. Possibility of pore size determination in separation layer of ceramic membrane using permeation method. J. Membr. Sci. 103 (1995) 151
138. Lange R.S.A.d., Keiser K., and Burggraaf A.J. Analysis and theory of gas transport in microporous sol-gel derived ceramic membranes. J. Membr. Sci. 104 (1995) 81
139. de Lange R.S.A., Hekkink J.H.A., Keiser K., and Burggraaf A.J. Permeation and separa-tion studies on microporous sol-gel modified ceramic membranes. Microporous Materi-als 4 (1995) 169
140. Shelekhin A.B., Dixon A.G., and Ma Y.H. Adsorption, permeation and diffusion of gases in microporous membranes. II.Permeation of gases in microporous glass mem-branes. J. Membr. Sci. 75 (1992) 232
141. Eyraud C. Application of gas-liquid permporometry to characterization of inorganic ultrafilters. In: Dridi E., and Nakagaki M. (Eds). Proc. Eur.-JPN Cong. Memb. Processes (1984) 629-634
142. Cuperus F.P., Bargeman D., and Smolders C.A. Permporometry. The determination of the size distribution of active pores in UF membranes. J. Membr. Sci. 71 (1992) 57
143. Cao G.Z., Meijerink J., Brinkman H.W., and Burggraaf A.J. Permporomerty study on the size distribution of active pores in porous ceramic membranes. J. Membr. Sci. 83 (1993) 221
144. Katz M., and Barush G. New insights into the structure of microporous membranes obtained using a new pore size evaluation method. Desalination 58 (1986) 199